The hydration of metal cations in hydrothermal solutions: Recent EXAFS results

2021 ◽  
pp. 43-46
Author(s):  
T.M. Seward ◽  
C.M.B. Henderson ◽  
J.M. Charnock ◽  
B.R. Dobson
Keyword(s):  
Metal Cations ◽  
Hydrothermal Solutions

Adsorption of metal cations on wool carbonising waste. Part 1. Adsorption isotherms

1981 ◽  
Vol 31 (1) ◽  
pp. 597-601 ◽  
Author(s):  
Karim Farag ◽  
Francis Perineau ◽  
Antoine Gaset ◽  
Jacques Molinier
Keyword(s):  
Adsorption Isotherms ◽  
Metal Cations

Experimental study of influence of oil-cracking processes in hydrothermal solutions on formation of various types of oil-and-gas deposits

2011 ◽  
Vol 3 (Special Issue) ◽  
pp. 1-7
Author(s):  
V. S. Balitsky ◽  
M. A. Novikova ◽  
S. V. Penteley ◽  
L. V. Balitskaya ◽  
T. M. Bublikova
Keyword(s):  
Experimental Study ◽  
Oil And Gas ◽  
Hydrothermal Solutions ◽  
Oil Cracking

A Contribution to the Structure Characteristics and Phase Composition of Vanadium-Phosphorus Catalysts Prepared from the VOPO4.xH2O.yH3PO4 Precursor

1992 ◽  
Vol 57 (12) ◽  
pp. 2475-2480 ◽  
Author(s):  
Milan Brutovský ◽  
Štefan Gerej ◽  
Ján Novák ◽  
Lucia Ferdinandyová
Keyword(s):  
Heat Treatment ◽  
Phase Composition ◽  
Ir Spectra ◽  
Metal Cations ◽  
Preparation Procedure ◽  
Final Temperature ◽  
Structure Characteristics ◽  
Heat Treatment Regime ◽  
Condensed Phosphates ◽  
Defective Crystals

Catalysts were prepared from VOPO4.xH2O.yH3PO4 (x = 0.3-2, y = 0.2-0.85) by reduction with SO2 up to a final temperature of 750-800 °C, and activated in a reaction mixture of 1.0-1.4% butane in air up to 500 °C. The structure characteristics and phase composition of the catalysts were found to be affected by the preparation procedure and heat treatment regime. Their diffraction lines and IR spectra revealed that the catalysts from larger and less defective crystals than catalysts which were obtained from the VOHPO4.xH2O.yH3PO4 precursor and activated in the reaction mixture at temperatures up to 500 °C. In the catalysts prepared by the above procedure, the tendency to the formation of phases of higher-condensed phosphates, in particular VO(PO3)2 or even V(PO3)3, increases with increasing n(P):n(V) ratio and is then more pronounced than with vanadium-phosphorus catalysts prepared by other procedures. The tendency to the formation of the catalytically less active condensed phosphates is partly suppressed by the embedding of modifying metal cations (Fe or Cu in this case).

ChemInform Abstract: Siting and Stability of Metal Cations in Zeolites

ChemInform ◽  
2010 ◽  
Vol 32 (28) ◽  
pp. no-no
Author(s):  
Alexis T. Bell
Keyword(s):  
Metal Cations

scholarly journals The phenoxyl group-modulated interplay of cation–π and σ-type interactions in the alkali metal series

2020 ◽  
Vol 22 (46) ◽  
pp. 27105-27120
Author(s):  
Giacomo Prampolini ◽  
Marco d'Ischia ◽  
Alessandro Ferretti
Keyword(s):  
Alkali Metal ◽  
Noncovalent Interactions ◽  
Metal Cations ◽  
Alkali Metal Cations ◽  
Striking Effect

An extensive exploration of the interaction PESs of phenol and catechol complexes with alkali metal cations reveals a striking effect of –OH substitution on the balance between cation-π and σ-type noncovalent interactions.

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