Rheological behavior of asphalt binder based on time-temperature superposition principle: A molecular dynamics simulation study

2021 ◽  
pp. 74-81
Author(s):  
Xingyi Zhu ◽  
Wenrong Zhang ◽  
Pei Wu ◽  
Lu Zhou ◽  
Chuanqi Yan ◽  
...  
Author(s):  
Arindam Basu ◽  
Mihai O. Marasteanu ◽  
Simon A. M. Hesp

During the development of the Strategic Highway Research Program low-temperature binder specifications, in an effort to propose practical laboratory tests that require less time to perform, the time–temperature superposition principle was used to show that the stiffness after 2 h of loading at the performance-graded (PG) low temperature can be approximated by the stiffness after 60 s of loading at 10°C above the PG low temperature. This equivalence principle was developed on the basis of test results from the eight core asphalts and is widely accepted today. However, actual 2-h tests were not performed to experimentally validate this equivalence. Furthermore, the effect of physical hardening on time–temperature superposition was not considered. The validity of the time–temperature equivalence factor used in the low-temperature specification criterion and the ways in which the deviations could affect the current specification are evaluated.


Soft Matter ◽  
2021 ◽  
Author(s):  
Adegbola Balogun ◽  
Daria Lazarenko ◽  
Fardin Khabaz ◽  
Rajesh Khare

Molecular dynamics simulations are used to determine the temperature dependence of dynamic and rheological properties of a model imidazolium-based ionic liquid (IL). Simulation results for the volumetric properties of the...


2019 ◽  
Author(s):  
Ketan Khare ◽  
Frederick R. Phelan Jr.

<a></a><a>Quantitative comparison of atomistic simulations with experiment for glass-forming materials is made difficult by the vast mismatch between computationally and experimentally accessible timescales. Recently, we presented results for an epoxy network showing that the computation of specific volume vs. temperature as a function of cooling rate in conjunction with the time–temperature superposition principle (TTSP) enables direct quantitative comparison of simulation with experiment. Here, we follow-up and present results for the translational dynamics of the same material over a temperature range from the rubbery to the glassy state. Using TTSP, we obtain results for translational dynamics out to 10<sup>9</sup> s in TTSP reduced time – a macroscopic timescale. Further, we show that the mean squared displacement (MSD) trends of the network atoms can be collapsed onto a master curve at a reference temperature. The computational master curve is compared with the experimental master curve of the creep compliance for the same network using literature data. We find that the temporal features of the two data sets can be quantitatively compared providing an integrated view relating molecular level dynamics to the macroscopic thermophysical measurement. The time-shift factors needed for the superposition also show excellent agreement with experiment further establishing the veracity of the approach</a>.


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