Equilibrium Thermodynamic State of the Polaron System

2000 ◽  
pp. 77-148
2008 ◽  
Vol 59 (5) ◽  
Author(s):  
Viorel Feroiu ◽  
Dan Geana ◽  
Catinca Secuianu

Vapour � liquid equilibrium, thermodynamic and volumetric properties were predicted for three pure hydrofluorocarbons: difluoromethane (R32), pentafluoroethane (R125) and 1,1,1,2 � tetrafluoroethane (R134a) as well as for binary and ternary mixtures of these refrigerants. Three cubic equations of state GEOS3C, SRK (Soave � Redlich � Kwong) and PR (Peng � Robinson) were used. A wide comparison with literature experimental data was made. For the refrigerant mixtures, classical van der Waals mixing rules without interaction parameters were used. The GEOS3C equation, with three parameters estimated by matching several points on the saturation curve (vapor pressure and corresponding liquid volumes), compares favorably to other equations in literature, being simple enough for applications.


2021 ◽  
Vol 11 (14) ◽  
pp. 6301
Author(s):  
Giulia Grisolia ◽  
Mariarosa Astori ◽  
Antonio Ponzetto ◽  
Antonio Vercesi ◽  
Umberto Lucia

Recently, a non-equilibrium thermodynamic approach has been developed in order to model the fundamental role of the membrane electric potential in the cell behaviour. A related new viewpoint is introduced, with a design of a photobiomodulation treatment in order to restore part of the visual field. Here, a first step in experimental evidence of the validity of the thermodynamic approach is developed. This result represents the starting point for future experimental improvements for light stimulation in order to improve the quality of life of the patients. The future possible therapy will be in addition to the pharmacological treatments.


Soft Matter ◽  
2020 ◽  
Author(s):  
Ulices Que-Salinas ◽  
Pedro Ezequiel Ramirez-Gonzalez ◽  
Alexis Torres-Carbajal

In this work we implement a machine learning method to predict the thermodynamic state of a liquid using only its microscopic structure provided by the radial distribution function (RDF). The...


2012 ◽  
Vol 48 (3) ◽  
pp. 461-469 ◽  
Author(s):  
L. Falat ◽  
V. Homolová ◽  
J. Kepic ◽  
M. Svoboda ◽  
A. Výrostková

The studies were performed on dissimilar ferritic/austenitic weldments between 9Cr tempered martensitic steels of the grades either P/T 91 or 92 and unstabilised AISI316H austenitic steel. The welded joints were fabricated using the fusion welding by tungsten inert gas (TIG) method with Ni-based filler metal. Microstructural analyses were performed using light and electron microscopy. Microstructural gradient in heat-affected zone (HAZ) of 9Cr steels remained preserved during creep exposure. All weldments fractured by the type IV failure within their intercritical HAZ (ICHAZ) regions. The most remarkable microstructural change during creep was the precipitation of intermetallic Laves phase. Experimentally determined phases of the samples after creep exposure are in good agreement with equilibrium thermodynamic calculations.


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