Alternative Representation for the Stability Diagram of Quadrupole Ion Traps upon Additional Quadrupolar Excitation

2013 ◽  
Vol 19 (3) ◽  
pp. 141-149 ◽  
Author(s):  
Arnaud Vernier ◽  
Fabien Chirot ◽  
Rodolphe Antoine ◽  
Arnaud Salvador ◽  
Jean-Philippe Charrier ◽  
...  
Keyword(s):  
Ion Traps ◽  
Stability Diagram ◽  
Quadrupolar Excitation ◽  
Alternative Representation ◽  
The Stability ◽  
Quadrupole Ion Traps

Waveboard Artifacts Generate Ghost Resonances Consistent with Equations for Predicting Ion Motion in Commercial Quadrupole Ion Traps

2005 ◽  
Vol 11 (1) ◽  
pp. 15-21 ◽  
Author(s):  
Kwenga F. Sichilongo ◽  
Bert C. Lynn
Keyword(s):  
Ion Trap ◽  
Ion Traps ◽  
Quadrupole Ion Trap ◽  
Stability Diagram ◽  
Two Dimensional ◽  
Quadrupole Field ◽  
Non Linear ◽  
Contour Plots ◽  
The Stability ◽  
Contour Surface

Real-time experiments involving fragmentation of the precursor molecular ion of n-butylbenzene ( m/z 134) to produce product ions C7H+7 ( m/z 91) and C7H+8 ( m/z 92), were used to observe the motion of ions in a commercial quadrupole ion trap. Initially, ghost resonance peaks were observed for excitation of the precursor ion at qz values of 0.4 and 0.5 on the qz axis of the stability diagram. Further experiments involving the generation of two-dimensional contour plots confirmed that these ghost peaks, which were in agreement with mathematical equations describing the motion of ions in a quadrupole field, arose due to waveboard artifacts. Two-dimensional contour surface plots showed non-linear secular frequency canyons from a qz value of 0.5 to higher values corresponding with higher drive radio frequency (rf) voltages on the stability diagram. This observation confirmed that ions are subjected to non-linear effects in this mass scan range. The octapole and hexapole field lines were observed at qz values of 0.65 and 0.78, respectively.

CHARGE STABILITY AND CONDUCTANCE ANALYSIS OF ANTHRACENE-BASED SINGLE ELECTRON TRANSISTOR

2013 ◽  
Vol 12 (06) ◽  
pp. 1350045 ◽  
Author(s):  
ANURAG SRIVASTAVA ◽  
BODDEPALLI SANTHIBHUSHAN ◽  
PANKAJ DOBWAL
Keyword(s):  
Coulomb Blockade ◽  
Density Functional ◽  
Stability Diagram ◽  
Single Electron ◽  
Single Electron Transistor ◽  
Functional Theory ◽  
Charge Stability ◽  
Anthracene Molecule ◽  
The Stability ◽  
Experimental Values

The present paper discusses the investigation of electronic properties of anthracene-based single electron transistor (SET) operating in coulomb blockade region using Density Functional Theory (DFT) based Atomistix toolkit-Virtual nanolab. The charging energies of anthracene molecule in isolated as well as electrostatic SET environments have been calculated for analyzing the stability of the molecule for different charge states. Study also includes the analysis of SET conductance dependence on source/drain and gate potentials in reference to the charge stability diagram. Our computed charging energies for anthracene in isolated environment are in good agreement with the experimental values and the proposed anthracene SET shows good switching properties in comparison to other acene series SETs.

Evaluation of Non-Vibrating Utility Burner/Furnace Systems for Resistance to Thermoacoustic Oscillations

2006 ◽  
Author(s):  
Frantisek L. Eisinger ◽  
Robert E. Sullivan
Keyword(s):  
Design Process ◽  
Axial Direction ◽  
Stability Diagram ◽  
Stable Range ◽  
Design Engineers ◽  
Secondary Role ◽  
The Stability ◽  
Thermoacoustic Oscillations

Six burner/furnace systems which operated successfully without vibration are evaluated for resistance to thermoacoustic oscillations. The evaluation is based on the Rijke and Sondhauss models representing the combined burner/furnace (cold/hot) thermoacoustic systems. Frequency differences between the lowest vulnerable furnace acoustic frequencies in the burner axial direction and those of the systems’ Rijke and Sondhauss frequencies are evaluated to check for resonances. Most importantly, the stability of the Rijke and Sondhauss models is checked against the published design stability diagram of Eisinger [1] and Eisinger and Sullivan [2]. It is shown that the resistance to thermoacoustic oscillations is adequately defined by the published design stability diagram to which the evaluated cases generally adhere. Once the system falls into the stable range, the frequency differences or resonances appear to play only a secondary role. It is concluded, however, that in conjunction with stability, the primary criterion, sufficient frequency separations shall also be maintained in the design process to preclude resonances. The paper provides sufficient details to aid the design engineers.

Fine structure of the stability diagram and the amplitude of ion oscillation within hyperboloidal mass spectrometers

2002 ◽  
Vol 16 (4) ◽  
pp. 261-263 ◽  
Author(s):  
Ernst P. Sheretov ◽  
Igor V. Philippov ◽  
Tatiana B. Karnav ◽  
Edgar V. Fedosov ◽  
Vladimir W. Ivanov
Keyword(s):  
Fine Structure ◽  
Stability Diagram ◽  
Mass Spectrometers ◽  
The Stability

scholarly journals The linear instability of the stratified plane Couette flow

2018 ◽  
Vol 853 ◽  
pp. 205-234 ◽  
Author(s):  
Giulio Facchini ◽  
Benjamin Favier ◽  
Patrice Le Gal ◽  
Meng Wang ◽  
Michael Le Bars
Keyword(s):  
Reynolds Number ◽  
Stability Analysis ◽  
Numerical Simulations ◽  
Couette Flow ◽  
Vertical Direction ◽  
Stability Diagram ◽  
Linear Instability ◽  
Plane Couette Flow ◽  
Horizontal Shear ◽  
The Stability

We present the stability analysis of a plane Couette flow which is stably stratified in the vertical direction orthogonal to the horizontal shear. Interest in such a flow comes from geophysical and astrophysical applications where background shear and vertical stable stratification commonly coexist. We perform the linear stability analysis of the flow in a domain which is periodic in the streamwise and vertical directions and confined in the cross-stream direction. The stability diagram is constructed as a function of the Reynolds number $Re$ and the Froude number $Fr$, which compares the importance of shear and stratification. We find that the flow becomes unstable when shear and stratification are of the same order (i.e. $Fr\sim 1$) and above a moderate value of the Reynolds number $Re\gtrsim 700$. The instability results from a wave resonance mechanism already known in the context of channel flows – for instance, unstratified plane Couette flow in the shallow-water approximation. The result is confirmed by fully nonlinear direct numerical simulations and, to the best of our knowledge, constitutes the first evidence of linear instability in a vertically stratified plane Couette flow. We also report the study of a laboratory flow generated by a transparent belt entrained by two vertical cylinders and immersed in a tank filled with salty water, linearly stratified in density. We observe the emergence of a robust spatio-temporal pattern close to the threshold values of $Fr$ and $Re$ indicated by linear analysis, and explore the accessible part of the stability diagram. With the support of numerical simulations we conclude that the observed pattern is a signature of the same instability predicted by the linear theory, although slightly modified due to streamwise confinement.

The chemical stability of mendipite, diaboleïte, chloroxiphite, and cumengéite, and their relationships to other secondary lead(II) minerals

1980 ◽  
Vol 43 (331) ◽  
pp. 901-904 ◽  
Author(s):  
D. Alun Humphreys ◽  
John H. Thomas ◽  
Peter A. Williams ◽  
Robert F. Symes
Keyword(s):  
Chloride Ion ◽  
Stability Diagram ◽  
Chloride Ions ◽  
Ion Concentration ◽  
Stability Field ◽  
Cupric Ion ◽  
Free Energy Of Formation ◽  
High Concentrations ◽  
The Stability ◽  
Ph Range

SummaryThe chemical stabilities of mendipite, Pb3O2Cl2, diaboleïte, Pb2CuCl2(OH)4, chloroxiphite, Pb3CuCl2O2(OH)2, and cumengéite, Pb19Cu24Cl42 (OH)44, have been determined in aqueous solution at 298.2 K. Values of standard Gibbs free energy of formation, ΔGf°, for the four minerals are −740, −1160, −1129, and −15163±20 kJ mol−1 respectively. These values have been used to construct the stability diagram shown in fig. I which illustrates their relationships to each other and to the minerals cotunnite, PbCl2, paralaurionite, PbOHCl, and litharge, PbO. This diagram shows that mendipite occupies a large stability field and should readily form from cold, aqueous, mineralizing solutions containing variable amounts of lead and chloride ions, and over a broad pH range. The formation of paralaurionite and of cotunnite requires a considerable increase in chloride ion concentration, although paralaurionite can crystallize under much less extreme conditions than cotunnite. The encroachment of the copper minerals on to the stability fields of those mineral phases containing lead(II) only is significant even at very low relative activities of cupric ion. Chloroxiphite has a large stability field, and at given concentrations of cupric ion, diaboleïte is stable at relatively high aCl−. Cumengéite will only form at high concentrations of chloride ion.

Sign in / Sign up

Export Citation Format

Share Document