Outer Product Analysis Applied to near Infrared and Mid Infrared Spectra to Study a Spanish Protected Denomination of Origin Cheese

2009 ◽  
Vol 17 (3) ◽  
pp. 135-140 ◽  
Author(s):  
Tiziana M.P. Cattaneo ◽  
Stephania Barzaghi
2020 ◽  
Vol 12 (9) ◽  
pp. 1512
Author(s):  
Hanyi Xu ◽  
Dongyun Xu ◽  
Songchao Chen ◽  
Wanzhu Ma ◽  
Zhou Shi

Wise soil management requires detailed soil information, but conventional soil class mapping in a rather coarse spatial resolution cannot meet the demand for precision agriculture. With the advantages of non-destructiveness, rapid cost-efficiency, and labor savings, the spectroscopic technique has proved its high potential for success in soil classification. Previous studies mainly focused on predicting soil classes using a single sensor. In this study, we attempted to compare the predictive ability of visible near infrared (vis-NIR) spectra, mid-infrared (MIR) spectra, and their fused spectra for soil classification. A total of 146 soil profiles were collected from Zhejiang, China, and the soil properties and spectra were measured by their genetic horizons. Along with easy-to-measure auxiliary soil information (soil organic matter, soil texture, color and pH), four spectral data, including vis-NIR, MIR, their simple combination (vis-NIR-MIR), and outer product analysis (OPA) fused spectra, were used for soil classification using a multiple objectives mixed support vector machine model. The independent validation results showed that the classification model using MIR (accuracy of 64.5%) was slightly better than that using vis-NIR (accuracy of 64.2%). The predictive model built on vis-NIR-MIR did not improve the classification accuracy, having the lowest accuracy of 61.1%, which likely resulted from an over-fitting problem. The model based on OPA fused spectra performed best with an accuracy of 68.4%. Our results prove the potential of fusing vis-NIR and MIR using OPA for improving prediction ability for soil classification.


1993 ◽  
Vol 1 (2) ◽  
pp. 99-108 ◽  
Author(s):  
P. Robert ◽  
M.F. Devaux ◽  
A. Qannari ◽  
M. Safar

Multivariate data treatments were applied to mid and near infrared spectra of glucose, fructose and sucrose solutions in order to specify near infrared frequencies that characterise each carbohydrate. As a first step, the mid and near infrared regions were separately studied by performing Principal Component Analyses. While glucose, fructose and sucrose could be clearly identified on the similarity maps derived from the mid infrared spectra, only the total sugar content of the solutions was observed when using the near infrared region. Characteristic wavelengths of the total sugar content were found at 2118, 2270 and 2324 nm. In a second step, the mid and near infrared regions were jointly studied by a Canonical Correlation Analysis. As the assignments of frequencies are generally well known in the mid infrared region, it should be useful to study the relationships between the two infrared regions. Thus, the canonical patterns obtained from the near infrared spectra revealed wavelengths that characterised each carbohydrate. The OH and CH combination bands were observed at: 2088 and 2332 nm for glucose, 2134 and 2252 nm for fructose, 2058 and 2278 nm for sucrose. Although a precise assignment of the near infrared bands to chemical groups within the molecules was not possible, the present work showed that near infrared spectra of carbohydrates presented specific features.


1995 ◽  
Vol 78 (6) ◽  
pp. 1537-1541 ◽  
Author(s):  
Angela Fehrmann ◽  
Monika Franz ◽  
Andreas Hoffmann ◽  
Lutz Rudzik ◽  
Eberhard Wüst

Abstract Identification of microorganisms by traditional microbiological methods is time consuming. The German Federal Health Office has developed a method using mid-infrared spectroscopy to identify microorganisms rapidly. This method has been modified for application to microorganisms important in the dairy industry. Mid- and near-infrared spectroscopies are well-established methods for quantitative measurements of fat, protein, lactose, and solid content in a variety of products. A disadvantage of both methods is the huge absorption due to water; extraction of other components is complicated and can be achived only statistically. With Raman spectroscopy, water causes less absorption. We investigated the use of Raman spectroscopy as a quantitative method for milk powder.


1997 ◽  
Vol 51 (8) ◽  
pp. 1200-1204 ◽  
Author(s):  
James B. Reeves ◽  
Stephen R. Delwiche

The objective of this study was to determine whether mid-infrared diffuse reflectance spectroscopy could be used in the same manner as near-infrared diffuse reflectance spectroscopy to quantitatively determine the protein content of ground wheat samples. One hundred and thirty hard red winter wheat samples were assayed for protein by combustion and scanned in the near- and mid-infrared. Samples (UDY ground) were scanned neat in the near-infrared from 1100 nm (9091 cm−1) to 2498 nm (4003 cm−1) on a scanning monochromator and in the mid-infrared from 4000 cm−1 (2500 nm) to 400 cm−1 (25,000 nm) on a Fourier transform spectrometer at 4-and 16-cm−1 resolutions. Protein content varied from a low of 8.98% to a high of 18.70% (average of 12.86% with a standard deviation of 1.66%). Calibrations developed with the use of partial least-squares gave an R2 and bias-corrected standard error of performance of 0.999 and 0.054 for the near-infrared and 0.997 and 0.085 for the mid-infrared (4 cm−1 resolution). Calibration results based on mid-infrared spectra, while not as good as those for near-infrared spectra, were nevertheless quite good. These results demonstrate that it is possible to develop satisfactory calibrations for protein in ground wheat with the use of mid-infrared spectra without the need for sample dilution with KBr.


Icarus ◽  
2020 ◽  
Vol 352 ◽  
pp. 113978
Author(s):  
Molly C. McCanta ◽  
M. Darby Dyar

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