Abstract. Air toxics, also known as hazardous air pollutants (HAPs), have gained
increased public awareness in recent years. Air toxics may be released from
various sources, such as mobile sources, stationary sources, and fugitive
emissions. This study investigated profiles of air toxics from mobile
sources, stationary sources, and the operations in a port in an industrial
metropolitan area in Taiwan. Six carcinogens, including benzene,
formaldehyde, 1,3-butadiene, arsenic, 2,3,7,8-TCDD, and diesel particulate
matter (DPM), were chosen as the target pollutants. The AERMOD model was
applied to simulate the concentrations of the ambient air toxic species, and
the concentrations were used to evaluate cancer risk. Cancer risk for each
air toxic was also investigated to evaluate the potential impact on
residents. The results of the emission estimation for the base year (2014)
showed that the emissions of benzene, 1,3-butadiene, and formaldehyde could
be mainly attributed to mobile sources in the study areas. The
contributions, in order, were 86 %, 77 %, and 69 %. DPM emissions from
port operations accounted for 76 %, and most of the arsenic (70 %) and
2,3,7,8-TCDD (99 %) were emitted from stationary sources, especially from
the steel industry. Approximately 66 % and 32 % of the cancer risk of
air toxics were contributed to the emissions from port operations and
on-road vehicles, respectively, in this area, and approximately 1.4 % of
the risk was contributed to stationary sources. DPM was the pollutant that
posed the highest cancer risk among all six air toxics. It accounted for
more than 80 % of the overall cancer risk, followed by 1,3-butadiene
(10 %), benzene (4.7 %), formaldehyde (1.2 %), arsenic (0.7 %), and
2,3,7,8-TCDD (0.2 %). The dominant sources of DPM were ocean-going vessels
and diesel trucks.