scholarly journals Quantitative Modeling of Physical Properties of Crude Oil Hydrocarbons Using Volsurf+ Molecular Descriptors

2016 ◽  
Vol 22 (3) ◽  
pp. 133-141
Author(s):  
Saadi Saaidpour ◽  
Faraidon Ghaderi
2017 ◽  
Vol 733 ◽  
pp. 42-46
Author(s):  
Habiba Shehu ◽  
Edidiong Okon ◽  
Edward Gobina

Shuttle tankers are becoming more widely used in deep water installations as a means of transporting crude oil to storage plants and refineries. The emissions of hydrocarbon vapours arise mainly during loading and offloading operations. Experiments have been carried out on the use of polyurethane/zeolite membrane on an alumina support for the separation of methane from carbon dioxide and oxygen. The physical properties of the membrane were investigated by FTIR. Single gas permeation tests with methane, propane, oxygen and carbon dioxide at a temperature of 293 K and pressure ranging from 0.1 to 1.0 x 10-5 Pa were carried out. The molar flux of the gases through the membrane was in the range of 3 x 10-2 to 1 x 10-1 molm-2s-1. The highest separation factor of CH4/CO2 and CH4/O2 and CH4/C3H8 was determined to be 1.7, 1.7 and 1.6 respectively.


2019 ◽  
Vol 17 (1) ◽  
pp. 663-670 ◽  
Author(s):  
Maqsood Ahmad ◽  
Muhammad Javaid ◽  
Muhammad Saeed ◽  
Chahn Yong Jung

AbstractBakelite network $BN_{m}^{n}$is a molecular graph of bakelite, a pioneering and revolutionary synthetic polymer (Thermosetting Plastic) and regarded as the material of a thousand uses. In this paper, we aim to compute various degree-based topological indices of a molecular graph of bakelite network $BN_{m}^{n}$. These molecular descriptors play a fundamental role in QSPR/QSAR studies in describing the chemical and physical properties of Bakelite network $BN_{m}^{n}$. We computed atom-bond connectivity ABC its fourth version ABC4 geometric arithmetic GA its fifth version GA5 Narumi-Katayama, sum-connectivity and Sanskruti indices, first, second, modified and augmented Zagreb indices, inverse and general Randic’ indices, symmetric division, harmonic and inverse sum indices of $BN_{m}^{n}$.


2019 ◽  
pp. 56-60
Author(s):  
L. Dj. Abdullayeva

The questions on determination level of contamination of soil with crude oil hydrocarbons using vegetations reflection spectrum are considered. The close link between concentration of pigments in vegetation and its reflection properties make it possible to use the reflection spectroscopy as an indicator to predict the vegetation stress occur due to spill of different types of crude oil. The reason is that light types of oil have a more effect on vegetation in comparison with heavy ones. The heavy types of oil have a predominant high molecular heavy components which are hardly transported and distributed within vegetation. The light oil is less viscose’s and well filtered through soil and roots of vegetation. The stressed condition occurred due to effect of oil is mainly reasoned by its such toxic components as aromatic compounds. The carried out analysis of reflection spectrums reveals the double polarity of differences of spectral signals formed by subtraction of reflection spectrums of oil of light and heavy types from controlled reflection spectrum. It causes uncertainty in estimation of contamination of oil using single wavelength method. The question on utilization in practices the inverse type interrelations for diminishing errors of measurements inherent for single wavelength method by transition to two wavelength regime of measurements. It is shown that presence of above said inverse interrelations allows to reach following prevalence’s upon use of two wavelength measurements. 1. Incrtease of dynamic range of measurements; 2. Decrease of random errors. Two variants of two wavelengths methods allowing to determine the level of contamination of soil with crude oil hydrocarbons are developed. The general methodic for determination of level of soil pollution with oil is suggested.


2014 ◽  
Vol 88 ◽  
pp. 185-191 ◽  
Author(s):  
Uzochukwu C. Ugochukwu ◽  
Martin D. Jones ◽  
Ian M. Head ◽  
David. A.C. Manning ◽  
Claire I. Fialips

Author(s):  
Travis Mecham ◽  
Galen Stanley ◽  
Michael Pelletier ◽  
Jim C. P. Liou

Recent advances in SCADA and leak detection system technologies lead to higher scan rates and faster model speeds. As these model speeds increase and the inherent mathematical uncertainties in implicit method solutions are reduced, errors and uncertainties in measurement of the physical properties of the fluids transported by pipeline come to dominate the confidence calculations for computer generated leak alerts in the control center. The ability to collect more data must be supported by the need for better model data in order to achieve optimal leak detection system performance. This is particularly true when the products transported are non-homogeneous and have strong viscosity-vs-temperature relationships. These are characteristics of crude oils in California’s San Joaquin Valley where significant heating is required to pump these oils in an efficient manner. Proper characterization and correct mathematical expression of these physical properties in leak models has become critical. This paper presents these new developments in the context of an implementation of this new technology for the Pacific Pipeline System (PPS). PPS is a recently constructed and commissioned 209 km (130-mile), 50.8 cm (20″) diameter, insulated, hot crude oil pipeline between the southern portion of California’s San Joaquin Valley and refineries in the Los Angeles basin. Operational temperatures in this line vary from ambient to 82.2°C (180°F) with pressures ranging from 345 kPa (50 psi) to 11,720 kPa (1700 psi). Due to the unique geometry of the line, facilities along the route include pumping stations, metering stations and numerous “throttle-type” pressure reduction facilities. On PPS, a high-speed leak detection model is supported by a fiber optic (OC-1) communication backbone with data rate capacities in excess of 50 Megabits Per Second (MPS). Total scan times for the distributed communication system have been reduced to 1/4 second — each facility reports data to the SCADA host four times each second. A corresponding 1/4 second leak detection model cycle leads to selection of Methods of Characteristics segments on the order of 260 meters (850 feet). This resolution, in conjunction with the advanced instrumentation package of PPS, makes detection of very small leaks realizable. This paper starts with an overview of the system and combines a mix of the theoretical requirements imposed by the mathematical solutions with a practical description of the laboratory procedures and propagated experimental errors. The paper reviews temperature-related errors and uncertainties and their influence on leak detection performance.


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