Reactions of MoOCl4 and MoO2Cl2 with Heterocyclic Thioamides

MoOCl4/MoO2Cl2 were reacted with 2-mercaptopyridine (IUPAC: pyridine-2-thiol)/4-phenylimidazole-2-thiol (IUPAC: 4-phenyl-1, 3-dihydroimidazole-2-thione)/6-mercaptopurine (IUPAC: 1, 7-dihydro-purine-6-thione) in acetonitrile medium using equal/twice molar concentrations at normal temperature. The reactions yielded products: MoOCl3(C5H4NS-SNH4C5).2HCl, [1]; Mo3O3Cl12(C5H4NS-SNH4C5)(CH3CN)2, [2]; Mo2OCl6(C9H7N2S)4, [3] and Mo2O2Cl8(C5H4N4S)(CH3CN), [4]. The various techniques used for characterization of compounds are: Fourier transform infrared, proton nuclear magnetic resonance, 13C nuclear magnetic resonance, liquid/gas chromatography mass spectrometry and C, H, N, S, Mo, Cl analysis. The products are prone to oxidation/hydrolysis by air/moisture, so all procedures were executed in vacuum line using dry nitrogen atmosphere. Elemental analysis and fragments recorded in mass spectrometry are in tune with the formulae proposed.

Download Full-text

13C nuclear magnetic resonance and gas chromatography-mass spectrometry studies of carbon metabolism in the actinomycin D producer Streptomyces parvulus by use of 13C-labeled precursors.

Journal of Bacteriology ◽

10.1128/jb.173.24.7790-7801.1991 ◽

1991 ◽

Vol 173 (24) ◽

pp. 7790-7801 ◽

Cited By ~ 15

Author(s):

L Inbar ◽

A Lapidot

Keyword(s):

Mass Spectrometry ◽

Nuclear Magnetic Resonance ◽

Gas Chromatography ◽

Magnetic Resonance ◽

Carbon Metabolism ◽

Actinomycin D ◽

Gas Chromatography Mass Spectrometry ◽

Chromatography Mass Spectrometry ◽

13C Nuclear Magnetic Resonance ◽

Nuclear Magnetic

Download Full-text

Characterization of reference lipids and their degradation products by Raman spectroscopy, nuclear magnetic resonance and gas chromatography-mass spectrometry

ARKIVOC ◽

10.3998/ark.5550190.0006.c24 ◽

2006 ◽

Vol 2005 (12) ◽

pp. 311-318 ◽

Cited By ~ 1

Author(s):

Marta S. Maier ◽

Dalva L. A. de Faria ◽

María T. Boschín ◽

Sara D. Parera

Keyword(s):

Mass Spectrometry ◽

Nuclear Magnetic Resonance ◽

Gas Chromatography ◽

Raman Spectroscopy ◽

Magnetic Resonance ◽

Degradation Products ◽

Gas Chromatography Mass Spectrometry ◽

Chromatography Mass Spectrometry ◽

Nuclear Magnetic

Download Full-text

Qualitative and quantitative characterization of a complex mixture of hexylbenzenes by 13C nuclear magnetic resonance and gas chromatography-mass spectrometry

Fresenius Zeitschrift für Analytische Chemie ◽

10.1007/bf00521006 ◽

1989 ◽

Vol 335 (5) ◽

pp. 469-474 ◽

Cited By ~ 1

Author(s):

M. de Pooter ◽

J. Klok

Keyword(s):

Mass Spectrometry ◽

Nuclear Magnetic Resonance ◽

Gas Chromatography ◽

Magnetic Resonance ◽

Complex Mixture ◽

Gas Chromatography Mass Spectrometry ◽

Quantitative Characterization ◽

Qualitative And Quantitative ◽

13C Nuclear Magnetic Resonance

Download Full-text

Nuclear magnetic resonance- and gas chromatography/mass spectrometry-based metabolomic characterization of water-soluble and volatile compound profiles in cabbage vinegar

Journal of Bioscience and Bioengineering ◽

10.1016/j.jbiosc.2018.02.003 ◽

2018 ◽

Vol 126 (1) ◽

pp. 53-62 ◽

Cited By ~ 4

Author(s):

Satoru Ishihara ◽

Takashi Inaoka ◽

Toshihide Nakamura ◽

Keitarou Kimura ◽

Yasuyo Sekiyama ◽

...

Keyword(s):

Mass Spectrometry ◽

Nuclear Magnetic Resonance ◽

Gas Chromatography ◽

Magnetic Resonance ◽

Volatile Compound ◽

Water Soluble ◽

Gas Chromatography Mass Spectrometry ◽

Chromatography Mass Spectrometry ◽

Nuclear Magnetic

Download Full-text

Synthesis and Characterization of a Trifunctional Photoinitiator Based on Two Commercial Photoinitiators with α-Hydroxyl Ketone Structure

Materials ◽

10.3390/ma14185272 ◽

2021 ◽

Vol 14 (18) ◽

pp. 5272

Author(s):

Rong Zhong ◽

Hui Hu ◽

Yanfang Zhou

Keyword(s):

Mass Spectrometry ◽

Nuclear Magnetic Resonance ◽

Magnetic Resonance ◽

Proton Nuclear Magnetic Resonance ◽

Synthesis And Characterization ◽

The Novel ◽

Nuclear Magnetic Resonance Spectra ◽

Magnetic Resonance Spectra ◽

Nuclear Magnetic

A trifunctional photoinitiator based on commercial photoinitiators 2-hydroxy-2-methylpropiophenone (Irgacure1173) and 2-hydroxy-4′-(2-hydroxyethoxy)-2-methylpropiophenone (Irgacure2959) was synthesized by an esterization reaction. Its structure was characterized by UV-Vis spectrometry, Infrared Transformed Fourier, Proton Nuclear Magnetic Resonance Spectra, 13 Carbon Nuclear Magnetic Resonance Spectra, Mass Spectrometry, and Thermogravimetry. In addition, its photoinitiating activity was investigated. The results showed that the novel photoinitiator had good photoinitiating activity and thermal stability compared to commercial photoinitiators. The migration of the residual photoinitiator in the cured film was lower than that of 1173 and 2959.

Download Full-text