Cellulose recycling as a source of raw chirality
2013 ◽
Vol 85
(8)
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pp. 1683-1692
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Keyword(s):
Modern organic chemistry requires easily obtainable chiral building blocks that show high chemical versatility for their application in the synthesis of enantiopure compounds. Biomass has been demonstrated to be a widely available raw material that represents the only abundant source of renewable organic carbon. Through the pyrolitic conversion of cellulose or cellulose-containing materials it is possible to produce levoglucosenone, a highly functionalized chiral structure. This compound has been innovatively used as a template for the synthesis of key intermediates of biologically active products and for the preparation of chiral auxiliaries, catalysts, and organocatalysts for their application in asymmetric synthesis.
Keyword(s):
2003 ◽
Vol 75
(9)
◽
pp. 1263-1275
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2008 ◽
Vol 47
(11)
◽
pp. 1982-1982
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1998 ◽
Vol 30
(2)
◽
pp. 145-176
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