From vinylsilanes to organic/inorganic hybrid materials
2005 ◽
Vol 77
(12)
◽
pp. 2083-2090
◽
Keyword(s):
Alternating regioregular silylene-spaced divinylarene copolymers [(donor-SiMe2-)n=1-3-(acceptor-SiMe2)] are synthesized by rhodium-catalyzed hydrosilylation of bis-alkynes with bisvinylic silyl hydrides. Efficient intrachain energy transfer has been observed in these copolymers. The intensities of emission profiles depend on the relative ratio of donor-to-acceptor chromophores. The corresponding inorganic/organic hybrid materials are synthesized, and their photophysical properties are described.
2008 ◽
Vol 194
(2-3)
◽
pp. 238-246
◽
2008 ◽
Vol 200
(2-3)
◽
pp. 318-324
◽
Keyword(s):
2015 ◽
Vol 16
(12)
◽
pp. 1070-1077
Keyword(s):