scholarly journals POTENSI KATALIS PADAT ASAM GAMMA ALUMINA TERSULFATASI PADA REAKSI ESTERIFIKASI MINYAK BIJI KARET

REAKTOR ◽  
2016 ◽  
Vol 16 (3) ◽  
pp. 109 ◽  
Author(s):  
Maria Ulfah ◽  
S Subagjo
Keyword(s):  
Fatty Acid ◽  
Free Fatty Acid ◽  
Optimum Condition ◽  
Seed Oil ◽  
Catalyst Concentration ◽  
Volume Ratio ◽  
Esterification Reaction ◽  
Rubber Seed Oil ◽  
Rubber Seed ◽  
Time Of Reaction

POTENTIAL OF SULFATET ALUMINA-HETEROGENEOUS ACID CATALYST IN ESTERIFICATION RUBBER SEED OIL.  Two tipe of  catalysts have been synthesed and evaluated ( free fatty acid conversion) in esterification of rubber seed oil. The first and the second catalyst have content SO3 8,821 % and 40,715 %, respectly. The optimum condition of reaction studied : volume ratio methanol/oil  0,9-1,8 v/v;  catalyst concentration 1,67-10 % wt/v; time of reaction 1-7 hours and temperature of reaction 50-70 oC. This study  showed, the second catalyst  more active than the first catalyst. Maximum conversion from esterification reaction of rubber seed oil of the first and the second catalyst are 75 % and  97 %, respectly. The optimum condition of reaction achieved at volume ratio methanol/oil  1,8 v/v;  catalyst concentration 1,67 % wt/v; time of reaction 7 hours and temperature of reaction 70 oC.   Keywords: sulfated alumina, free fatty acid, eterification, rubber seed oil.AbstrakDua tipe katalis alumina tersulfatasi telah disintesis dan dievaluasi kinerjanya (berupa konversi Asam Lemak Bebas, ALB) pada reaksi esterifikasi asam lemak bebas minyak biji karet. Katalis tipe 1 dan tipe 2 berturut-turut memiliki kandungan SO3 8,821 % dan 40,715 %.  Kondisi optimasi reaksi yang dipelajari: rasio volume metanol/minyak 0,9-1,8 v/v; konsentrasi katalis 1,67-10 % b/v; waktu reaksi 1-7 jam dan temperatur reaksi 50-70 oC.  Hasil penelitian menunjukkan katalis tipe 2 lebih aktif dari tipe 1. Konversi ALB maksimum  dari reaksi esterifikasi minyak biji karet  dengan katalis tipe 1 dan tipe 2  berturut-turut 75 % dan 97 %.  Kondisi  optimum reaksi tersebut dicapai pada rasio volume metanol/minyak 1,8; konsentrasi katalis/minyak 1,67 % b/v; lama reaksi 7 jam dan temperatur reaksi 70 oC. Kata kunci: alumina tersulfatasi, asam lemak bebas, esterifikasi, minyak biji karet

Synthesis and characterization of CuO/C catalyst for the esterification of free fatty acid in rubber seed oil

Fuel ◽  
2014 ◽  
Vol 120 ◽  
pp. 195-201 ◽  
Author(s):  
Huei Ruey Ong ◽  
Maksudur R. Khan ◽  
M.N.K. Chowdhury ◽  
Abu Yousuf ◽  
Chin Kui Cheng
Keyword(s):  
Fatty Acid ◽  
Free Fatty Acid ◽  
Seed Oil ◽  
Synthesis And Characterization ◽  
Rubber Seed Oil ◽  
Rubber Seed

Biodiesel Production from the High Free Fatty Acid “Hevea brasiliensis” and Fuel Properties Characterization

2014 ◽  
Vol 625 ◽  
pp. 897-900 ◽  
Author(s):  
Junaid Ahmad ◽  
Suzana Yusup ◽  
Awais Bokhari ◽  
Ruzaimah Nik Mohammad Kamil
Keyword(s):  
Fatty Acid ◽  
Free Fatty Acid ◽  
Seed Oil ◽  
Standard Procedure ◽  
Fuel Properties ◽  
Biodiesel Production ◽  
Modern World ◽  
High Free Fatty Acid ◽  
Rubber Seed Oil ◽  
Rubber Seed

Energy crises, depletion of fossil fuel reservoirs, environmental pollution, global warming, green house effect and starvation are becoming very serious problems in the modern world. Biodiesel is a liquid fuel which can be the best alternative for the fossil fuels. In this study, non-edible rubber seed oil (RSO) with high free fatty acid (FFA) content (45%) was used for the production of biodiesel. The process comprises of two steps, in the first step acid esterification was used to reduce the FFA and in the second step base transesterification was employed to convert the treated oil into rubber seed oil methyl esters (RSOMEs). The conversion yield of biodiesel was analyzed using gas chromatography. The fuel properties were tested using the standard procedure of ASTM D6751 and EN14214. All the properties were within the ranges of the biodiesel standards. The result shows that rubber seed oil is a potential non-edible source for biodiesel production.

Optimisation and Kinetic Studies of Acid Esterification of High Free Fatty Acid Rubber Seed Oil

2015 ◽  
Vol 41 (7) ◽  
pp. 2515-2526 ◽  
Author(s):  
Lai Fatt Chuah ◽  
Awais Bokhari ◽  
Suzana Yusup ◽  
Jiří Jaromír Klemeš ◽  
Bawadi Abdullah ◽  
...  
Keyword(s):  
Fatty Acid ◽  
Free Fatty Acid ◽  
Seed Oil ◽  
Kinetic Studies ◽  
High Free Fatty Acid ◽  
Rubber Seed Oil ◽  
Rubber Seed ◽  
Acid Esterification

Enzyme catalyzed biodiesel production from rubber seed oil containing high free fatty acid

2017 ◽  
Vol 14 (8) ◽  
pp. 687-693 ◽  
Author(s):  
Jilse Sebastian ◽  
Chandrasekharan Muraleedharan ◽  
Arockiasamy Santhiagu
Keyword(s):  
Fatty Acid ◽  
Free Fatty Acid ◽  
Seed Oil ◽  
Biodiesel Production ◽  
High Free Fatty Acid ◽  
Rubber Seed Oil ◽  
Rubber Seed

scholarly journals Optimisation of Free Fatty Acid Removal in Nyamplung Seed Oil (Callophyllum inophylum L.) using Response Surface Methodology Analysis

2021 ◽  
Vol 29 (4) ◽  
Author(s):  
Ratna Dewi Kusumaningtyas ◽  
Haniif Prasetiawan ◽  
Radenrara Dewi Artanti Putri ◽  
Bayu Triwibowo ◽  
Siti Choirunisa Furi Kurnita ◽  
...  
Keyword(s):  
Response Surface Methodology ◽  
Fatty Acid ◽  
Reaction Time ◽  
Free Fatty Acid ◽  
Response Surface ◽  
Reaction Temperature ◽  
Seed Oil ◽  
Catalyst Concentration ◽  
Molar Ratio ◽  
Esterification Reaction

Nyamplung seed (Calophyllum inophyllum L.) oil is a prospective non-edible vegetable oil as biodiesel feedstock. However, it cannot be directly used in the alkaline catalysed transesterification reaction since it contains high free fatty acid (FFA) of 19.17%. The FFA content above 2% will cause saponification reaction, reducing the biodiesel yield. In this work, FFA removal was performed using sulfuric acid catalysed esterification to meet the maximum FFA amount of 2%. Experimental work and response surface methodology (RSM) analysis were conducted. The reaction was conducted at the fixed molar ratio of nyamplung seed oil and methanol of 1:30 and the reaction times of 120 minutes. The catalyst concentration and the reaction temperature were varied. The highest reaction conversion was 78.18%, and the FFA concentration was decreased to 4.01% at the temperature of 60℃ and reaction time of 120 minutes. The polynomial model analysis on RSM demonstrated that the quadratic model was the most suitable FFA conversion optimisation. The RSM analysis exhibited the optimum FFA conversion of 78.27% and the FFA content of 4%, attained at the reaction temperature, catalyst concentration, and reaction time of 59.09℃, 1.98% g/g nyamplung seed oil, and 119.95 minutes, respectively. Extrapolation using RSM predicted that the targeted FFA content of 2% could be obtained at the temperature, catalyst concentration, and reaction time of 58.97℃, 3%, and 194.9 minutes, respectively, with a fixed molar ratio of oil to methanol of 1:30. The results disclosed that RSM is an appropriate statistical method for optimising the process variable in the esterification reaction to obtain the targeted value of FFA.

Optimization of esterification of fatty acid rubber seed oil for methyl ester synthesis in a plug flow reactor

2016 ◽  
Vol 13 (7) ◽  
pp. 720-729 ◽  
Author(s):  
Tho Dinh Son Van ◽  
Nghia Phan Trung ◽  
Vu Nguyen Anh ◽  
Huong Nguyen Lan ◽  
Anh To Kim
Keyword(s):  
Fatty Acid ◽  
Methyl Ester ◽  
Seed Oil ◽  
Flow Reactor ◽  
Plug Flow ◽  
Plug Flow Reactor ◽  
Ester Synthesis ◽  
Rubber Seed Oil ◽  
Rubber Seed
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