Comprehensive two-dimensional gas chromatographic analysis of volatile organic compounds in distillate of fermented Sorbus domestica fruit

AbstractThe Slovak-Czech spirit distilled from Sorbus domestica was analyzed by GCxGC with headspace solid phase microextraction and liquid-liquid extraction. Two column combinations, nonpolar × medium-polar and polar × medium-polar were tested. The second column setup provided more exploited 2D separation space with better distribution of peaks in chromatogram. Effects of the first column on the elution order of γ-lactones, benzyl esters, and unsaturated aldehydes in the second separation were observed. More than 500 compounds were detected; nearly 100 were confirmed with standards.

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Application of a static solid-phase microextraction procedure combined with liquid–liquid extraction to determine poly(dimethyl)siloxane–water partition coefficients for selected polychlorinated biphenyls

Journal of Chromatography A ◽

10.1016/j.chroma.2006.03.029 ◽

2006 ◽

Vol 1116 (1-2) ◽

pp. 240-247 ◽

Cited By ~ 26

Author(s):

Ze-Yu Yang ◽

Eddy Y. Zeng ◽

Huan Xia ◽

Ji-Zhong Wang ◽

Bi-Xian Mai ◽

...

Keyword(s):

Polychlorinated Biphenyls ◽

Partition Coefficients ◽

Solid Phase Microextraction ◽

Solid Phase ◽

Liquid Extraction ◽

Dimethyl Siloxane ◽

Liquid Liquid Extraction

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Comparison of Liquid-Liquid Extraction (LLE), Solid-Phase Extraction (SPE), and Solid-Phase Microextraction (SPME) for Pyrethroid Pesticides Analysis from Enriched River Water

Bulletin of Environmental Contamination and Toxicology ◽

10.1007/s00128-002-0018-5 ◽

2002 ◽

Vol 69 (1) ◽

pp. 123-128 ◽

Cited By ~ 45

Author(s):

W. R. Barrionuevo ◽

F. M. Lanças

Keyword(s):

Solid Phase Extraction ◽

River Water ◽

Solid Phase Microextraction ◽

Solid Phase ◽

Liquid Extraction ◽

Phase Extraction ◽

Liquid Liquid Extraction ◽

Pyrethroid Pesticides

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Comparison of solid-phase microextraction and liquid–liquid extraction in 96-well format for the determination of a drug compound in human plasma by liquid chromatography with tandem mass spectrometric detection

Journal of Pharmaceutical and Biomedical Analysis ◽

10.1016/j.jpba.2007.08.029 ◽

2007 ◽

Vol 45 (4) ◽

pp. 599-608 ◽

Cited By ~ 33

Author(s):

W. Xie ◽

J. Pawliszyn ◽

W.M. Mullett ◽

B.K. Matuszewski

Keyword(s):

Liquid Chromatography ◽

Solid Phase Microextraction ◽

Solid Phase ◽

Liquid Extraction ◽

Mass Spectrometric ◽

Tandem Mass ◽

Liquid Liquid Extraction ◽

Tandem Mass Spectrometric ◽

Drug Compound

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Comparative analysis of volatile compounds of ‘fino’ sherry wine by rotatory and continuous liquid–liquid extraction and solid-phase microextraction in conjunction with gas chromatography-mass spectrometry

Analytica Chimica Acta ◽

10.1016/j.aca.2004.02.002 ◽

2004 ◽

Vol 513 (1) ◽

pp. 141-150 ◽

Cited By ~ 43

Author(s):

R Castro ◽

R Natera ◽

P Benitez ◽

C.G Barroso

Keyword(s):

Mass Spectrometry ◽

Gas Chromatography ◽

Comparative Analysis ◽

Volatile Compounds ◽

Solid Phase Microextraction ◽

Solid Phase ◽

Liquid Extraction ◽

Gas Chromatography Mass Spectrometry ◽

Liquid Liquid Extraction ◽

Sherry Wine

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Volatiles from the Mandibular Gland Reservoir Content of Colobopsis explodens Laciny and Zettel, 2018, Worker Ants (Hymenoptera: Formicidae)

Molecules ◽

10.3390/molecules24193468 ◽

2019 ◽

Vol 24 (19) ◽

pp. 3468 ◽

Cited By ~ 1

Author(s):

Michaela Hoenigsberger ◽

Alexey Kopchinskiy ◽

Christoph Bueschl ◽

Alexandra Parich ◽

Alice Laciny ◽

...

Keyword(s):

Mass Spectrometry ◽

Solid Phase Microextraction ◽

Solid Phase ◽

Mandibular Gland ◽

Liquid Extraction ◽

Microbial Pathogens ◽

Gas Chromatography Mass Spectrometry ◽

Phenolic Constituents ◽

Volatile Organic ◽

Distinct Field

Forty-five volatile organic compounds (VOCs) were identified or annotated in the mandibular gland reservoir content (MGRC) of the Southeast Asian ant Colobopsis explodens Laciny and Zettel, 2018 (Hymenoptera: Formicidae), using headspace solid-phase microextraction (HS-SPME) coupled to gas chromatography mass spectrometry (GC-MS) and liquid extraction combined with GC-MS. In extension of previous reports on VOCs of C. explodens, members of different compound classes, such as alkanes, aliphatic and aromatic carboxylic acids, and phenolics, were detected. The ketone 2-heptanone and the biochemically related phenolics benzene-1,3,5-triol (phloroglucinol, PG), 1-(2,4,6-trihydroxyphenyl)ethanone (monoacetylphloroglucinol, MAPG), 5,7-dihydroxy-2-methylchromen-4-one (noreugenin), and 1-(3-Acetyl-2,4,6-trihydroxyphenyl)ethanone (2,4-diacetylphloroglucinol, DAPG) dominated the GC-MS chromatograms. The identities of the main phenolics MAPG and noreugenin were further verified by liquid chromatography-high resolution-tandem mass spectrometry (LC-HRMS/MS). A comparative study of MGRC samples originating from three distinct field expeditions revealed differences in the VOC profiles, but the presence and relative abundances of the dominating constituents were largely consistent in all samples. Our study considerably extends the knowledge about the number and type of VOCs occurring in the MGRC of C. explodens. Based on the type of the detected compounds, we propose that the likely irritant and antibiotic phenolic constituents play a role in defense against arthropod opponents or in protection against microbial pathogens.

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