Interaction of metallic zirconium and its alloys Zry-2 and E110 with molten eutectic salt of LiF–NaF–KF containing zirconium fluoride components

2016 ◽  
Vol 70 (2) ◽  
Author(s):  
Viliam Pavlík ◽  
Peter Barborík ◽  
Miroslav Boča Miroslav ◽  
Zuzana Vasková
Keyword(s):  
Construction Materials ◽  
Zirconium Alloys ◽  
Eutectic Salt ◽  
Zirconium Fluoride ◽  
Special Construction

The interactions of selected zirconium alloys used as special construction materials (Zr-pure, Zry-2, E-110) with the molten system of (LiF–NaF–KF)

scholarly journals Effect of Corrosion of the Fuel Rod Construction Materials on the Radiation Safety of Nuclear Power Plants with PWR

2020 ◽  
Vol 63 (1) ◽  
pp. 89-98
Author(s):  
V. V. Kravchenko ◽  
S. D. Tsygankova
Keyword(s):  
Nuclear Power ◽  
Power Plants ◽  
Construction Materials ◽  
Zirconium Alloys ◽  
General Concept ◽  
Corrosion Process ◽  
Operating Conditions ◽  
Metal Corrosion ◽  
Fuel Rods ◽  
The Core

The article considers the general concept of corrosion in accordance with GOST 5272–68 “Metal Corrosion”, the classification of the corrosion process, the stages of corrosion as energy function of the flow path of the corrosion process, the main indicators of the corrosion process. According to the forecasts of the International Monetary Fund and Focus Economics, the amount of funds that will be spent on counteracting corrosion and its consequences in selected industrialized countries has been estimated. The growth of funds invested in the counteracting the effects of metal corrosion in the Russian Federation for 2016–2019 is presented in the form of a diagram. The substantiation of the use of zirconium as a structural material for the shell of fuel rods has been fulfilled. The values of the thermal neutron absorption cross sections for various elements serving as structural elements for the core of a nuclear reactor are presented. Factors influencing the choice of alloying elements and their percentage in various alloys (Zr-2, Zr-4, ZIRLO™, M5®), which are the special development that reduce the corrosion rate, are also considered. The composition and mechanical properties of E110 and E635 alloys, which were used as materials for the fuel rods shell in the core of WWER-1200 reactors at the Belarusian NPP, are considered as well. The behavior of zirconium alloys E110 and E635 in the core is analyzed. The main factors that make a significant contribution to the corrosion process in actual operating conditions of zirconium alloys as fuel rods shell have been identified. The existing methods of preliminary special processing of fuel rods shells stored in the air for a long time before their receipt for assembly are presented. The structure of the oxide on the shells of alloys E110 and E635 oxidized in an autoclave is demonstrated.

Corrosion monitoring and root cause identification in high solids concentrators

TAPPI Journal ◽  
2016 ◽  
Vol 15 (7) ◽  
pp. 467-477
Author(s):  
PASI NIEMELAINEN ◽  
MARTTI PULLIAINEN ◽  
JARMO KAHALA ◽  
SAMPO LUUKKAINEN
Keyword(s):  
Paper Industry ◽  
Black Liquor ◽  
Construction Materials ◽  
Open Circuit ◽  
Process Conditions ◽  
Potential Range ◽  
Corrosion Monitoring ◽  
General Corrosion ◽  
High Solids ◽  
Passive Area

Black liquor high solids (about 80%) concentrators have often been found to suffer from aggressive corrosion. In particular, the first and second effect bodies are susceptible to corrosion attacks resulting in tube leaks and wall thinning, which limit the availability and lifetime of evaporator lines. Corrosion dynamics and construction materials have been studied extensively within the pulp and paper industry to understand the corrosion process. However, it has been challenging to identify root causes for corrosion, which has limited proactive measures to minimize corrosion damage. Corrosion of the first phase concentrator was studied by defining the potential regions for passive area, stress corrosion cracking, pitting corrosion, and general corrosion. This was achieved by using a technique called polarization scan that reveals ranges for the passive area in which the equipment is naturally protected against corrosion. The open circuit potential, also known as corrosion potential, and linear polarization resistance of the metal were monitored online, which allowed for definition of corrosion risks for stainless steel 304L and duplex stainless steels 2205 and SAF 2906. An online temperature measurement added insight to the analysis. A process diagnostics tool was used to identify root causes of the corrosion attacks. Many of the root causes were related to process conditions triggering corrosion. Once the metal surface was activated, it was difficult to repassivate the metal naturally unless a sufficient potential range was reached.

Housing Inflation: Policy Guidelines from Shariah Perspective

2019 ◽  
Vol 16 (1) ◽  
pp. 70-81
Author(s):  
Azrul Azlan Iskandar Mirza ◽  
Asmaddy Haris ◽  
Ainulashikin Marzuki ◽  
Ummi Salwa Ahmad Bustamam ◽  
Hamdi Hakiem Mudasir ◽  
...  
Keyword(s):  
Content Analysis ◽  
Housing Prices ◽  
Construction Materials ◽  
Housing Price ◽  
Developed Countries ◽  
Control Element ◽  
Recent Issue ◽  
Analysis Methodology ◽  
The Government ◽  
Developing And Developed Countries

The soaring housing prices in Malaysia is not a recent issue. It is a global phenomenon especially in developing and developed countries, driven by factors including land price, location, construction materials cost, demand, and speculation. This issue demands immediate attention as it affects the younger generation, most of whom could not afford to buy their own house. The government has taken many initiatives and introduced regulations to ensure that housing prices are within the affordable range. This article aims to introduce a housing price control element from the Shariah perspective, as an alternative solution for all parties involved in this issue. It adopts content analysis methodology on policy from Shariah approved sources.

CREDO RADON UA – INFORMATION MODEL FOR CALCULATION OF ROAD CONSTRACTION

2019 ◽  
pp. 34-42
Author(s):  
Volodymyr Karedin ◽  
Nadiya Pavlenko
Keyword(s):  
Design Process ◽  
Static Loading ◽  
Computer Aided Design ◽  
Experimental Studies ◽  
Construction Materials ◽  
Residual Deformation ◽  
Road Construction ◽  
Information Support ◽  
Existing Structures ◽  
Road Pavement

CREDO RADON UA software provides an automated calculation of the strength of the pavement structures of non-rigid and rigid types, as well as the calculation of the strengthening of existing structures. In the article, one can see the main features and functionality of the CREDO RADON UA software, the main points in the calculations according to the new regulations. Information support of the design process includes necessary databases, informational and helping materials that make up the full support of the pavement design process. The concept of CREDO RADON UA 1.0 software is made on the use of elasticity theory methods in calculations of initial information models of pavements. Performing optimization calculations, the roadwear in CREDO RADON UA is designed in such a way that no unacceptable residual deformation occurs under the influence of short-term dynamic or static loading in the working layer of the earth bed and in the structural layers during the lifetime of the structure. The calculation algorithms were made in accordance with the current regulatory documents of Ukraine. CREDO RADON UA software allows user to create information bases on road construction materials and vehicles as part of the traffic flow for calculations. The presented system of automated modeling makes it easier for the customer to control the quality of design solutions, to reasonably assign designs to layers of reinforcement, to quickly make comparisons of calculations of different designs for the optimal use of allocated funds. Prospects for further improvement of the program should be the results of theoretical and experimental studies on filling the databases, which are used as information support for automated design of road structures. Keywords: CREDO RADON UA, road, computer-aided design, repair project, road pavement, strengthening, construction, rigid pavement, elasticity module, a transport stream, calculation method, information support, dynamic or static loading.

Control of hydrogen absorption by nickel films obtained upon magnetic spraying of zirconium alloy using the thermoEMF method

2020 ◽  
Vol 86 (8) ◽  
pp. 32-37
Author(s):  
V. V. Larionov ◽  
Xu Shupeng ◽  
V. N. Kudiyarov
Keyword(s):  
Magnetron Sputtering ◽  
Hydrogen Concentration ◽  
Hydrogen Absorption ◽  
Zirconium Alloy ◽  
Hydrogen Adsorption ◽  
Zirconium Alloys ◽  
Nickel Film ◽  
Protective Film ◽  
Nickel Films ◽  
Hydrogen Penetration

Nickel films formed on the surface of zirconium alloys are often used to protect materials against hydrogen penetration. Hydrogen adsorption on nickel is faster since the latter actively interacts with hydrogen, oxidizes and forms a protective film. The goal of the study is to develop a method providing control of hydrogen absorption by nickel films during vacuum-magnetron sputtering and hydrogenation via measuring thermoEMF. Zirconium alloy E110 was saturated from the gas phase with hydrogen at a temperature of 350°C and a pressure of 2 atm. A specialized Rainbow Spectrum unit was used for coating. It is shown that a nickel film present on the surface significantly affects the hydrogen penetration into the alloy. A coating with a thickness of more than 2 μm deposited by magnetron sputtering on the surface of a zirconium alloy with 1% Nb, almost completely protects the alloy against hydrogen penetration. The magnitude of thermoemf depends on the hydrogen concentration in the zirconium alloy and film thickness. An analysis of the hysteresis width of the thermoEMF temperature loop and a method for determining the effective activation energy of the conductivity of a hydrogenated material coated with a nickel film are presented. The results of the study can be used in assessing the hydrogen concentration and, hence, corrosion protection of the material.

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