scholarly journals Minimality via second variation for microphase separation of diblock copolymer melts

Author(s):  
Vesa Julin ◽  
Giovanni Pisante

AbstractWe consider a non-local isoperimetric problem arising as the sharp interface limit of the Ohta–Kawasaki free energy introduced to model microphase separation of diblock copolymers. We perform a second order variational analysis that allows us to provide a quantitative second order minimality condition. We show that critical configurations with positive second variation are indeed strict local minimizers of the problem. Moreover, we provide, via a suitable quantitative inequality of isoperimetric type, an estimate of the deviation from minimality for configurations close to the minimum in the

Soft Matter ◽  
2021 ◽  
Vol 17 (1) ◽  
pp. 90-101
Author(s):  
Dmitry A. Filatov ◽  
Elena N. Govorun

Amphiphilic polymer blocks can envelop the domains of major non-amphiphilic blocks in diblock copolymer melts: a theoretical study.


Polymers ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1262
Author(s):  
Mikhail A. Osipov ◽  
Maxim V. Gorkunov ◽  
Alexander A. Antonov

Density functional theory of rod-coil diblock copolymers, developed recently by the authors, has been generalised and used to study the liquid crystal ordering and microphase separation effects in the hexagonal, lamellar and nematic phases. The translational order parameters of rod and coil monomers and the orientational order parameters of rod-like fragments of the copolymer chains have been determined numerically by direct minimization of the free energy. The phase diagram has been derived containing the isotropic, the lamellar and the hexagonal phases which is consistent with typical experimental data. The order parameter profiles as functions of temperature and the copolymer composition have also been determined in different anisotropic phases. Finally, the spatial distributions of the density of rigid rod fragments and of the corresponding orientational order parameter in the hexagonal phase have been calculated.


2021 ◽  
Author(s):  
Jacob Ishibashi ◽  
Ian Pierce ◽  
Alice Chang ◽  
Aristotelis Zografos ◽  
Bassil El-Zaatari ◽  
...  

<p>The composition of low-T<sub>g</sub> <i>n</i>-butylacrylate-<i>block</i>-(acetoxyaceto)ethyl acrylate block polymers is investigated as a strategy to tune the properties of dynamically cross-linked vinylogous urethane vitrimers. As the proportion of the cross-linkable block is increased, the thermorheological properties, structure, and stress relaxation evolve in ways that cannot be explained by increasing cross-link density alone. Evidence is presented that network connectivity defects such as loops and dangling ends are increased by microphase separation. The thermomechanical and viscoelastic properties of block copolymer-derived vitrimers arise from the subtle interplay of microphase separation and network defects.</p><div><br></div><p></p>


2017 ◽  
Author(s):  
Juan José Mompó ◽  
Haritz Iribas ◽  
Javier Urricelqui ◽  
Alayn Loayssa
Keyword(s):  

1998 ◽  
Vol 31 (23) ◽  
pp. 8110-8116 ◽  
Author(s):  
Shao-Min Mai ◽  
J. Patrick A. Fairclough ◽  
Nicholas J. Terrill ◽  
Simon C. Turner ◽  
Ian W. Hamley ◽  
...  

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