scholarly journals Epoxy-based nanocomposites with amine modified single walled carbon nanotubes

e-Polymers ◽  
2010 ◽  
Vol 10 (1) ◽  
Author(s):  
Celina-Maria Petrea ◽  
Corina Andronescu ◽  
Andreea Madalina Pandele ◽  
Sorina Alexandra Garea ◽  
Horia Iovu

AbstractCarboxylated Single Walled Carbon Nanotubes (SWNT-COOH) were functionalized using different types of amines as modifier agents to improve the compatibility with the epoxy matrix. Covalent attachment was proved by XPS and Raman spectroscopy. TGA showed that only long chain modifier agents improved the thermal stability of modified SWNTs. Epoxy-based composites were synthesized using diglycidyl ether of bisphenol A (DGEBA) as polymer matrix and modified SWNTs as reinforcing agent.

2015 ◽  
Vol 331 ◽  
pp. 271-277 ◽  
Author(s):  
Andrés Rodríguez-Galván ◽  
Alejandro Heredia ◽  
Oscar Amelines-Sarria ◽  
Margarita Rivera ◽  
Luis A. Medina ◽  
...  

2004 ◽  
Vol 858 ◽  
Author(s):  
SungHo Jhang ◽  
SangWook Lee ◽  
DongSu Lee ◽  
Eleanor E. B. Campbell ◽  
Siegmar Roth ◽  
...  

ABSTRACTThe switching of resistance between two discrete values, known as random telegraph noise (RTN), was observed in individual single-walled carbon nanotubes (SWNTs). The RTN has been studied as a function of bias-voltage and gate-voltage as well as temperature. By analyzing the features of the RTN, we identify three different types of RTN existing in the SWNT related systems. While the RTN can be generated by the various charge traps in the vicinity of the SWNTs, the RTN for metallic SWNTs is mainly due to reversible defect motions between two metastable states, activated by inelastic scattering with electrons.


Author(s):  
R. Graupner ◽  
F. Hauke

This article examines the chemical functionalization and structural alteration of single-walled carbon nanotubes (SWCNTs). It describes the covalent functionalization of the SWCNT framework that is the covalent attachment of functional entities onto the CNT scaffold. In particular, it considers the chemical modification and reactivity of SWCNTs in the context of the reactivity of graphite and fullerenes. It also discusses the defect and sidewall functionalization of SWCNTs, along with various techniques used in the characterization ofSWCNTs upon functionalization, namely: thermogravimetric analysis, spectroscopic techniques such as UV-Vis-NIR spectroscopy and Raman spectroscopy, and microscopic techniques like transmission electron microscopy, atomic force microscopy and scanning tunnelling microscopy.


Author(s):  
Paola Jaramillo ◽  
Haym Benaroya

Carbon nanotubes are composed of C-C covalent bonds, which are the strongest bonds found in nature. Hence, carbon nanotubes are identified as the “ultimate fiber” due to their great strength in the direction of the nanotube axis and their ability to enhance the elastic properties of materials. The first indications of synthesizing carbon nanotubes date back to 1952. Russian scientists Radushkevich and Lukyanovich [1] were able to produce nanosized hollow carbon filaments. Nevertheless, it was until 1991 that multi-walled carbon nanotubes (MWCNTs) were discovered by Sumio lijima [2, 3] at NEC Corporation Lab, which was followed by his study and synthesis of single-walled carbon nanotubes (SWCNTs) in 1993. Since their discovery, there has been a constant pursuit to understand the properties and identify the optimal applications of these structures. The paper focuses on the importance of carbon nanotubes and their ability to enhance the mechanical properties of other materials due to their unique elastic properties. Additionally, carbon nanotubes can improve the capabilities and properties of other materials, like polymer composite. Currently, there is an ongoing process to accurately understand the fundamental characteristics of these structures, in particular, to develop the governing laws necessary to control, predict, and manipulate these properties. This will eventually have an impact on the bulk properties of materials where carbon nanotubes may be incorporated. The current research focuses on the ability to create simplified models that can accurately predict the response of carbon nanotube structures undergoing different types of loading conditions. In this way, the mechanical characteristics regarding single-walled carbon nanotubes (SWCNTs) through finite element modeling are computed. A simplified finite element model is created in ANSYS for different types of SWCNTs with varying input parameters. An input array for the elastic modulus and load is generated to control the physical effects of these parameters in the nanotube structure. The geometries of the nanotubes are altered through various thicknesses employed for the construction of the C–C bonds. The current work contributes to the generation of different model responses to monitor the stress distribution employing a wide range of parameter values. The ability to introduce variability in the parameters and boundary conditions without altering the capabilities and computational time in the model represents the main contribution of this work.


Sign in / Sign up

Export Citation Format

Share Document