scholarly journals Comparison of Particle Size Distribution Models for Polymer Swelling

2018 ◽  
Vol 46 (2) ◽  
pp. 79-84
Author(s):  
Ádám Wirnhardt ◽  
Tamás Varga

Abstract In polymer technologies, various particle shapes and size distributions can be found. One of these are heterodisperse polymer beads. The capabilities of polymer swelling can be used in industries, e.g in the production of ion-exchange resins, to intensify specific technological steps such as sulphonation in the manufacturing process of ion-exchange resins. According to the literature different approaches can be used to create models for describing the behavior of disperse systems, of which the simplest models are the particle size distribution models for a given state of the solid phase. The aim of our examination was to compare and evaluate these simple models in terms of modeling polymer swelling. Hence, most of these models examine how each of the investigated models can be applied to approximately describe growth in a heterodisperse polymer system and how the identified model parameters in each time step could be interpreted. All the models were fitted to generate particle size distributions based on a swelling rate constant. The swelling of a styrene divinylbenzene-based copolymer was chosen as the basis of our examination. A model is proposed that is capable of describing the changes in the size of beads over time in this system.

2019 ◽  
Vol 67 (2) ◽  
pp. 179-190
Author(s):  
Fatemeh Afrasiabi ◽  
Habib Khodaverdiloo ◽  
Farrokh Asadzadeh ◽  
Martinus Th. van Genuchten

Abstract Complete descriptions of the particle-size distribution (PSD) curve should provide more information about various soil properties as opposed to only the textural composition (sand, silt and clay (SSC) fractions). We evaluated the performance of 19 models describing PSD data of soils using a range of efficiency criteria. While different criteria produced different rankings of the models, six of the 19 models consistently performed the best. Mean errors of the six models were found to depend on the particle diameter, with larger error percentages occurring in the smaller size range. Neither SSC nor the geometric mean diameter and its standard deviation correlated significantly with the saturated hydraulic conductivity (Kfs); however, the parameters of several PSD models showed significant correlation with Kfs. Porosity, mean weight diameter of the aggregates, and bulk density also showed significant correlations with PSD model parameters. Results of this study are promising for developing more accurate pedotransfer functions.


1991 ◽  
Vol 113 (4) ◽  
pp. 402-411 ◽  
Author(s):  
T. J. Labus ◽  
K. F. Neusen ◽  
D. G. Alberts ◽  
T. J. Gores

A basic investigation of the factors which influence the abrasive jet mixing process was conducted. Particle size analysis was performed on abrasive samples for the “as-received” condition, at the exit of the mixing tube, and after cutting a target material. Grit size distributions were obtained through sieve analysis for both water and air collectors. Two different mixing chamber geometries were evaluated, as well as the effects of pressure, abrasive feed rate, cutting speed, and target material properties on particle size distributions. An analysis of the particle size distribution shows that the main particle breakdown is from 180 microns directly to 63 microns or less, for a nominal 80 grit garnet. This selective breakdown occurs during the cutting process, but not during the mixing process.


1982 ◽  
Vol 60 (8) ◽  
pp. 1101-1107
Author(s):  
C. V. Mathai ◽  
A. W. Harrison

As part of an ongoing general research program on the effects of atmospheric aerosols on visibility and its dependence on aerosol size distributions in Calgary, this paper presents the results of a comparative study of particle size distribution and visibility in residential (NW) and industrial (SE) sections of the city using a mobile laboratory. The study was conducted in the period October–December, 1979. An active scattering aerosol spectrometer measured the size distributions and the corresponding visibilities were deduced from scattering coefficients measured with an integrating nephelometer.The results of this transit study show significantly higher suspended particle concentrations and reduced visibilities in the SE than in the NW. The mean values of the visibilities are 44 and 97 km for the SE and the NW respectively. The exponent of R (particle radius) in the power law aerosol size distribution has a mean value of −3.36 ± 0.24 in the SE compared with the corresponding value of −3.89 ± 0.39 for the NW. These results arc in good agreement with the observations of Alberta Environment; however, they are in contradiction with a recent report published by the City of Calgary.


Metals ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 882
Author(s):  
Alfredo L. Coello-Velázquez ◽  
Víctor Quijano Arteaga ◽  
Juan M. Menéndez-Aguado ◽  
Francisco M. Pole ◽  
Luis Llorente

Mathematical models of particle size distribution (PSD) are necessary in the modelling and simulation of comminution circuits. In order to evaluate the application of the Swebrec PSD model (SWEF) in the grinding circuit at the Punta Gorda Ni-Co plant, a sampling campaign was carried out with variations in the operating parameters. Subsequently, the fitting of the data to the Gates-Gaudin-Schumann (GGS), Rosin-Rammler (RRS) and SWEF PSD functions was evaluated under statistical criteria. The fitting of the evaluated distribution models showed that these functions are characterized as being sufficiently accurate, as the estimation error does not exceed 3.0% in any of the cases. In the particular case of the Swebrec function, reproducibility for all the products is high. Furthermore, its estimation error does not exceed 2.7% in any of the cases, with a correlation coefficient of the ratio between experimental and simulated data greater than 0.99.


2010 ◽  
Vol 177 ◽  
pp. 22-24
Author(s):  
Zheng Min Li ◽  
Zhi Wei Chen ◽  
Min Tan ◽  
Ke Jing Xu ◽  
Bing Jiang

Nano-TiO2 coating film is one of the efficient photocatalysts. The particle size distribution of TiO2 has important influence on photocatalytic activity. A new method to determine the particle size distribution of TiO2 nano-film coated on ceramic was developed, by which the images of film acquired by Atom force microscope (AFM) were processed, and TiO2 particles contacted with others were separated and detected. The particle size distributions of two TiO2 nano-films were determined.


1994 ◽  
Vol 74 (2) ◽  
pp. 383-385 ◽  
Author(s):  
R. Soofi-Siawash ◽  
G. W. Mathison

Two studies were conducted to assess the possibility of using particle size distribution following grinding as a routine procedure of forage evaluation. It was concluded that although differences in particle size distribution could be detected when different feeds were ground, it would be difficult to standardize the technique since particle size distributions were influenced by type of mill used for grinding, particle size of forage before grinding, and moisture content of the forage. Key words: Forages, grinding, particle size, moisture, mill


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