Notizen: Kinetics of the Oxidation of Acetaldehyde by Manganese(III) Sulphate
1974 ◽
Vol 29
(9-10)
◽
pp. 691-693
◽
Oxidation of acetaldehyde with manganese(III)- sulphate is first order with respect to acetaldehyde and the oxidant. The rate is independent of acidity (2.0 > [H+] < 5.0 ᴍ and initial [Mn(II)]. Formaldehyde is one of the products of oxidation. Activation parameters for the reaction have been evaluated. The rate of enolisation under similar conditions is less than the rate of oxidation. A mechanism involving a direct attack on the aldehyde by Mn(III) has been suggested.
1992 ◽
Vol 57
(7)
◽
pp. 1451-1458
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2015 ◽
Vol 59
◽
pp. 81-92
2001 ◽
Vol 36
(3)
◽
pp. 589-604
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Keyword(s):
Keyword(s):
1982 ◽
Vol 47
(11)
◽
pp. 2831-2837
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