Hydroxo Verbindungen, 11. Zinn(II)-Ethylenglykolat, SnC2H4O2, ein polymerer Chelatkomplex mit 2-fach funktionellem Sauerstoff/ Hydroxy Compounds, 11. Tin(II) Ethylen Glycolate, SnC2H4O2, a Polymerie Chelate Complex with Bi-Functional Oxygen

1982 ◽  
Vol 37 (9) ◽  
pp. 1144-1145 ◽  
Author(s):  
Reinhard Nesper ◽  
Hans Georg von Schnering
Keyword(s):  
Ethylene Glycol ◽  
Single Crystals ◽  
Chelate Complex ◽  
3 Dimensional ◽  
Hydroxy Compounds ◽  
Rhombohedral Symmetry

AbstractTin(II) ethylene glycolate is prepared from freshly precipitated “tin(II)-hydroxide” on heating in ethylene glycol under reflux. The colourless single crystals, slightly distorted cubes, exhibit rhombohedral symmetry (R3̄-C3i2, ah = 1547.7 pm, cn= 871.6 pm, Z = 18). The structure is a 3-dimensional networks of linked tin(II) ethylene glycol chelates.

Chemical recycling of the waste anodic electrolyte from the TiO2 nanotube preparation process to synthesize facet-controlled TiO2 single crystals as an efficient photocatalyst

2014 ◽  
Vol 16 (5) ◽  
pp. 2745-2753 ◽  
Author(s):  
Ai-Yong Zhang ◽  
Lu-Lu Long ◽  
Chang Liu ◽  
Wen-Wei Li ◽  
Han-Qing Yu
Keyword(s):  
Water Treatment ◽  
Ethylene Glycol ◽  
Single Crystals ◽  
Tio2 Nanotube ◽  
Anodic Process ◽  
Chemical Recycling ◽  
Preparation Process

To prepare TiO2 single crystals by recycling the waste ethylene glycol electrolyte from the widely-used anodic process for efficient photocatalytic water treatment.

Recrystallization of AA1050 Studied by 3DXRD

2006 ◽  
Vol 519-521 ◽  
pp. 1569-1578
Author(s):  
Dorte Juul Jensen
Keyword(s):  
Single Crystals ◽  
High Energy ◽  
Nucleation And Growth ◽  
X Rays ◽  
X Ray Diffraction ◽  
Orientation Relationships ◽  
X Ray ◽  
3 Dimensional ◽  
Kinetics Of

By 3 dimensional X-ray diffraction (3DXRD) using high energy X-rays from synchrotron sources it is possible to study in-situ the nucleation and growth during recrystallization. In this paper it is described and discussed how 3DXRD can supplement EBSP measurements of nucleation and growth. Three types of studies are considered: i) orientation relationships between nuclei and parent deformed matrix, ii) recrystallization kinetics of individual bulk grains and iii) filming of growing grains in deformed single crystals.

K+ auf einer mit Ca2+ unterbesetzten Punktlage in Ca3( VO4)2: Ein Beitrag über KCa10V7O28 / K+ at an Deficient Ca2+ Point Position in Ca3( VO4) 2: On KCa10V7O28

1996 ◽  
Vol 51 (4) ◽  
pp. 473-476 ◽  
Author(s):  
O. Schrandt ◽  
Hk. Müller-Buschbaum
Keyword(s):  
Single Crystals ◽  
Crystal Chemistry ◽  
Space Group ◽  
Point Position ◽  
Rhombohedral Symmetry

Abstract Single crystals of K Ca10V7O28 have been prepared by crystallization from flux. The yellow-green crystals show rhombohedral symmetry (trigonal space group C63V-R3c, a = 10.830(1), c = 37.860(1) Å , Z = 6). The differences of the crystal chemistry are discussed with respect to the isotypic compound Ca3(VO4)2. K+ replaces exclusively Ca2+ ions at one deficient point position.

Über einen 9L-Perowskit der Zusammensetzung Ba9Ru3,2Mn5,8O27/ On a 9L-Perovskite of the Composition Ba9Ru3.2Mn5.8O27

1995 ◽  
Vol 50 (4) ◽  
pp. 585-588 ◽  
Author(s):  
S. Frenzen ◽  
Hk. Müller-Buschbaum
Keyword(s):  
Crystal Structure ◽  
Single Crystals ◽  
Space Group ◽  
X Ray ◽  
Group D ◽  
Symmetry Space ◽  
Symmetry Space Group ◽  
Rhombohedral Symmetry

Single crystals of Ba9Ru3.2Mn5.8O27 have been prepared by flux techniques. X-ray four circle diffractometer measurements led to trigonal (rhombohedral) symmetry, space group D53d - R3̄̄̄m , a = 5.7043(5), c = 21.255(4) Å , Z = 1. This phase is isotypic to BaRuO3. The crystal structure and the occupation of the M3O12 triple octahedra by ruthenium and manganese are discussed with respect to other oxides containing M3O12 groups in an ordered and disordered way.

Characterization of novel extremely extended regime in conductive rod-like polyaniline nanobrush-covered poly(ethylene glycol) single crystals

2016 ◽  
Vol 82 ◽  
pp. 196-207 ◽  
Author(s):  
Samira Agbolaghi ◽  
Maryam Nazari ◽  
Saleheh Abbaspoor ◽  
Homa Gheybi ◽  
Farhang Abbasi
Keyword(s):  
Ethylene Glycol ◽  
Single Crystals ◽  
Poly Ethylene Glycol ◽  
Poly Ethylene

Fabrication of hybrid composites based on biomineralization of phosphorylated poly(ethylene glycol) hydrogels

2009 ◽  
Vol 24 (1) ◽  
pp. 50-57 ◽  
Author(s):  
Chan Woo Kim ◽  
Sung Eun Kim ◽  
Yong Woo Kim ◽  
Hong Jae Lee ◽  
Hyung Woo Choi ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Inductively Coupled Plasma ◽  
Hybrid Composites ◽  
Molar Ratio ◽  
X Ray Diffraction ◽  
Poly Ethylene Glycol ◽  
3 Dimensional ◽  
Inductively Coupled ◽  
Poly Ethylene

A novel route to organic-inorganic composites was described based on biomineralization of poly(ethylene glycol) (PEG)-based hydrogels. The 3-dimensional hydrogels were synthesized by radical crosslinking polymerization of poly(ethylene glycol fumarate) (PEGF) in the presence of ethylene glycol methacrylate phosphate (EGMP) as an apatite-nuclating monomer, acrylamide (AAm) as a composition-modulating comonomer, and potassium persulfate (PPS) as a radical initiator. We used the urea-mediated solution precipitation technique for biomineralization of hydrogels. The apatite grown on the surface and interior of the hydrogel was similar to biological apatites in the composition and crystalline structure. Powder x-ray diffraction (XRD) showed that the calcium phosphate crystalline platelets on hydrogels are preferentially aligned along the crystallographic c-axis direction. Inductively-coupled plasma mass spectroscopy (ICP-MS) analysis showed that the Ca/P molar ratio of apatites grown on the hydrogel template was found to be 1.60, which is identical to that of natural bones. In vitro cell experiments showed that the cell adhesion/proliferation on the mineralized hydrogel was more pronounced than on the pure polymer hydrogel.

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