Über ein Barium-Lanthanoid-Oxozinkat-Platinat(IV): Ba17Yb16Zn8Pt4O57
1996 ◽
Vol 51
(2)
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pp. 220-224
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Keyword(s):
Abstract Reactions of BaCO3, ZnO and Yb2O3 mixtures at temperatures up to 1300 °C using platinum crucibles led to yellow needles of Ba17Y b16Zn8Pt4O57. The compound crystallizes with a hitherto unknown tetragonal crystal structure, space group C54h-I4/m, a = 22.731(1), c = 5.682(1) Å , Z = 2. The crystal structure is characterized by PtO6 octahedra and tetragonal ZnO5 pyramids. Yb3+ shows a mono-capped trigonal prismatic coordination and Ba2+ several different coordination environments (C .N = 9 to 10, by O2-). The relationship to the Ba5Ln8M4O21 type is discussed.
2020 ◽
Vol 235
(6-7)
◽
pp. 175-181
2022 ◽
Vol 78
(1)
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2013 ◽
Vol 69
(12)
◽
pp. 1503-1508
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1979 ◽
Vol 34
(10)
◽
pp. 1373-1376
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Neutron Powder Diffraction on Ce11B2C2and Nd11B2C2: A New Model for the Tetragonal Crystal Structure
1999 ◽
Vol 68
(7)
◽
pp. 2287-2291
◽
1986 ◽
Vol 41
(11)
◽
pp. 1363-1366
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Keyword(s):