Carbacylamidophosphates: Synthesis, Properties, and Structure of Dimorfolido-N-trichloroacetylphosphorylamide
1998 ◽
Vol 53
(4)
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pp. 481-484
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Keyword(s):
X Ray
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Abstract Dimorpholido-N-trichloroacetylphosphorylamide: CCl3C(O)NHP(O)[N(CH2CH2)2O]2 [HL] and its sodium [NaL] and morpholine [HN(CH2-CH2)2O•HL] salts were synthesized for the first time. The compounds were studied by IR spectroscopy and assignments of the characteristic IR bands have been made. The structure of [HL] was determined by X-ray diffraction. Crystals are monoclinic, a = 11.412(2) Å, b = 16.056(3) Å, c = 9.622(2) Å, β = 108.55(3)°, space group P21/c; Z = 4. The refinement of the structure converged at R = 0.066. The molecules are connected into centrosymmetric dimers via hydrogen bonds formed by the phosphorylic oxygen atoms and hydrogen atoms of amide groups.
1994 ◽
Vol 49
(7)
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pp. 898-910
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2005 ◽
Vol 60
(9)
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pp. 978-983
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1979 ◽
Vol 34
(11)
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pp. 1487-1490
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Keyword(s):
1995 ◽
Vol 50
(4)
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pp. 699-701
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Keyword(s):
1983 ◽
Vol 38
(1)
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pp. 20-29
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