X-Ray and Raman Investigations on Cyanides ofMono- and DivalentMetals and Synthesis, Crystal Structure and Raman Spectrum of Tl5(CO3)2(CN)
2002 ◽
Vol 57
(8)
◽
pp. 895-900
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Keyword(s):
X Ray
◽
Pseudobinary cyanides of monovalent and divalent metals were synthesized, and X-ray and Raman data of the cyanides were measured. Single crystal X-ray structure analyses were performed on Zn(CN)2 (Pn3̄m (No. 224), a = 591.32(7) pm), Hg(CN)2 (I4̄2d (No. 122), a = 969.22(14) and c = 890,15(18) pm) and for the first time on AgCN (I4̄2d (No. 166), a = 600.58(8) and c = 526.28(11) pm). The data are compared with literature data. The reaction of TlF and NaCN in 25% aqueous ammonia solution in air led to Tl5(CO3)2(CN) which was characterized by X-ray (Cmca (No. 64), 1468.1(3), 1171.6(2) and 1266.0(3) pm) and Raman spectroscopy.
Keyword(s):
2003 ◽
Vol 58
(1)
◽
pp. 201-204
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Keyword(s):
2013 ◽
Vol 68
(3)
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pp. 296-300
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1978 ◽
Vol 33
(3)
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pp. 265-267
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