A new Co(II) coordination polymer with the 2-(4-pyridyl)-terephthalate ligand: synthesis, crystal structure and magnetic properties

2019 ◽  
Vol 74 (7-8) ◽  
pp. 619-622
Author(s):  
Danian Tian ◽  
Runmei Ding ◽  
Bingbing Chen ◽  
Peipei Cen
Keyword(s):  
Magnetic Measurements ◽  
Layer Structure ◽  
Octahedral Geometry ◽  
Supramolecular Network ◽  
Asymmetric Unit ◽  
Temperature Dependent ◽  
X Ray ◽  
Hydrogen Bonding Interactions ◽  
Bimetallic Layer ◽  
Ferromagnetic Interactions

AbstractA new Co(II) complex, [Co(pta)(H2O)2]n (1), with the 2-(4-pyridyl)-terephthalate ligand (pta2−) has been synthesized and structurally and magnetically characterized. Single crystal X-ray analysis indicates that the unique Co(II) ion in the asymmetric unit of 1 displays stretched octahedral geometry. Compound 1 presents a bimetallic layer structure which is further expanded to a 3D supramolecular network through hydrogen bonding interactions. Magnetic measurements have revealed the temperature-dependent existence of antiferromagnetic and ferromagnetic interactions in compound 1.

Magnetic properties of a mononuclear iron(II) complex with a typical FeN6coordination octahedron

2012 ◽  
Vol 68 (10) ◽  
pp. m287-m290 ◽  
Author(s):  
Fan Yu
Keyword(s):  
Magnetic Measurements ◽  
Three Dimensional ◽  
High Spin State ◽  
Supramolecular Network ◽  
X Ray Diffraction ◽  
Temperature Dependent ◽  
Tripodal Ligand ◽  
Mononuclear Iron ◽  
Hydrogen Bonding Interactions ◽  
External Pressures

A mononuclear iron(II) complex with the tripodal ligand bis(pyridin-2-ylmethyl)(quinolin-2-ylmethyl)amine (dpqa) has been synthesized and structurally characterized, namely [bis(pyridin-2-ylmethyl)(quinolin-2-ylmethyl)amine-κ4N,N′,N′′,N′′′]bis(thiocyanato-κS)iron(II), [Fe(NCS)2(C22H20N4)], exhibits a three-dimensional supramolecular networkviaπ–π interactions and S...H—C hydrogen-bonding interactions between adjacent FeIIcentres. Temperature-dependent magnetic measurements under different external pressures and X-ray diffraction measurements indicate that all the FeIIcentres in this complex retain a high-spin state upon cooling from 300 to 2 K. The surprising absence of spin-crossover behaviour for this mononuclear iron(II) complex is attributed to the steric hindrance originating from the substituted quinoline ring in the dpqa ligand.

scholarly journals Pentaaqua(1H-benzimidazole-5,6-dicarboxylato-κN3)cobalt(II) pentahydrate

2009 ◽  
Vol 65 (6) ◽  
pp. m702-m702 ◽  
Author(s):  
Wen-Dong Song ◽  
Hao Wang ◽  
Shi-Jie Li ◽  
Pei-Wen Qin ◽  
Shi-Wei Hu
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Organic Ligand ◽  
Octahedral Geometry ◽  
Mononuclear Complex ◽  
Distorted Octahedral Geometry ◽  
Water Molecules ◽  
Supramolecular Network ◽  
Hydrogen Bonding Interactions ◽  
Distorted Octahedral

In the title mononuclear complex, [Co(C9H4N2O4)(H2O)5]·5H2O, the CoIIatom exhibits a distorted octahedral geometry involving an N atom of a 1H-benzimidazole-5,6-dicarboxylate ligand and five water O atoms. A supramolecular network is generated through intermolecular O—H...O hydrogen-bonding interactions involving the coordinated and uncoordinated water molecules and the carboxyl O atoms of the organic ligand. An intermolecular N—H...O hydrogen bond is also observed.

scholarly journals Crystal structure of bis{(3,5-dimethylpyrazol-1-yl)dihydro[3-(pyridin-2-yl)pyrazol-1-yl]borato}iron(II)

2020 ◽  
Vol 76 (8) ◽  
pp. 1266-1270
Author(s):  
Sascha Ossinger ◽  
Christian Näther ◽  
Felix Tuczek
Keyword(s):  
Spin Crossover ◽  
Magnetic Measurements ◽  
Complex Molecule ◽  
High Spin State ◽  
Methyl Groups ◽  
Asymmetric Unit ◽  
Pure Sample ◽  
X Ray ◽  
Classical Hydrogen Bond

The structure determination of [Fe(C13H15BN5)2] was undertaken as part of a project on the modification of the recently published spin-crossover (SCO) complex [Fe{H2B(pz)(pypz)}2] (pz = pyrazole, pypz = pyridylpyrazole). To this end, a new ligand was synthesized in which two additional methyl groups are present. Its reaction with iron trifluoromethanesulfonate led to a pure sample of the title compound, as proven by X-ray powder diffraction. The asymmetric unit consists of one complex molecule in a general position. The FeII atom is coordinated by two tridentate N-binding {H2B(3,5-(CH3)2-pz)(pypz)}− ligands. The Fe—N bond lengths range between 2.1222 (13) and 2.3255 (15) Å, compatible with FeII in the high-spin state, which was also confirmed by magnetic measurements. Other than a very weak C—H...N non-classical hydrogen bond linking individual molecules into rows extending parallel to [010], there are no remarkable intermolecular interactions.

Crystal Structures of Seven Terephthaldiamide Derivatives

2002 ◽  
Vol 57 (8) ◽  
pp. 914-921 ◽  
Author(s):  
P. G. Jones ◽  
J. Ossowski ◽  
P. Kus
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Crystal Structures ◽  
Layer Structure ◽  
Inversion Symmetry ◽  
Asymmetric Unit ◽  
X Ray ◽  
Layer Structures ◽  
Structure Determinations ◽  
Independent Molecules

N,N′-Dibutyl-terephthaldiamide (1), N,N′-dihexyl-terephthaldiamide (2), N,N′-di(tert-butyl)- terephthaldiamide (3), N,N,N′,N′-tetrabutyl-terephthaldiamide (4), 1,1′-terephthaloylbis- pyrrolidine (5), 1,1′-terephthaloyl-bis-piperidine (6), and 4,4′-terephthaloyl-bis-morpholine (7) have been synthesised and physicochemically characterised. The X-ray structure determinations reveal imposed inversion symmetry for compounds 1-6; compound 3 has two independent molecules with inversion symmetry in the asymmetric unit. Compounds 1-3 form classical hydrogen bonds of the type N-H···O=C, leading to a ribbon-like arrangement of molecules (1 and 2) or a layer structure (3). Compound 3 also displays a very short C-H···O interaction, a type of hydrogen bond that is also observed in compounds 4-7, which lack classical donors; thereby compounds 4-6 form layer structures and 7 a complex threedimensional network.

Ferromagnetic interactions in a dicyanamide-bridged multinuclear metal-organic framework [Pr3NH]+ [Mn(dca)3]−·H2O

2019 ◽  
Vol 74 (6) ◽  
pp. 485-489
Author(s):  
Yuan Huang ◽  
Xiu-feng Yu ◽  
Zhen Rong ◽  
Yi-chun Ai ◽  
Kun Qian ◽  
...  
Keyword(s):  
Magnetic Susceptibility ◽  
Magnetic Measurements ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
X Ray Diffraction ◽  
Magnetic Susceptibility Data ◽  
X Ray ◽  
Susceptibility Data ◽  
Metal Organic ◽  
Ferromagnetic Interactions

AbstractA new complex [Pr3NH]+ [Mn(dca)3]− · H2O (dicyanamide = dca−) was synthesized, in which the Mn2+ cations are bridged by end-to-end dca anions to form three-dimensional [Mn(dca)3]nn− networks and tripropylammonium cations reside in the cavities of these networks. The complex has been characterized by single-crystal X-ray diffraction, infrared spectroscopy, elemental analysis, and magnetic measurements. Magnetic susceptibility data indicate ferromagnetic interactions among the MnII ions.

Synthesis, Crystal Structure and Magnetic Properties of a Copper(II) p-Formylbenzoate Complex

2012 ◽  
Vol 67 (11) ◽  
pp. 1185-1190 ◽  
Author(s):  
Jin-Li Qi ◽  
Wei Xu ◽  
Yue-Qing Zheng
Keyword(s):  
Room Temperature ◽  
Magnetic Measurements ◽  
X Ray Diffraction ◽  
Complex Molecules ◽  
Triclinic Space Group ◽  
X Ray ◽  
Cell Dimensions ◽  
Ferromagnetic Interactions ◽  
Aqueous Conditions ◽  
Discrete Complex

A new Cu(II) complex was prepared at room temperature from the reaction of p-formylbenzoic acid, phenanthroline, CuCl2⋅2H2O, and NaOH under ethanolic aqueous conditions. The complex has been characterized by X-ray diffraction, IR spectroscopy, TG-DTA analyses, and magnetic measurements. Single-crystal X-ray diffraction analysis indicated that the complex crystallizes in the triclinic space group P1̄ with the cell dimensions a=7.875(2), b=10.724(2), c=15.317(3) Å , α =102.65(3), β =93.71(3), γ =107:64(3)°. The Cu atoms are in the environment of distorted CuN2O3 tetragonal pyramids. These discrete complex molecules are packed through intermolecular π...π-stacking interactions and C-H...O hydrogen bonds forming a supramolecular structure. The title complex obeys the Curie-Weiss law with a Curie constant C=0:53 cm3 K mol-1 and a Weiss constant θ = -0:27 K. The shape of the xmT curve is characteristic of weak ferromagnetic interactions between the Cu(II) centers from 300 to 7 K, while there are weak antiferromagnetic interactions below 7 K.

Two new CdII MOFs of 1,4-bis(1H-benzimidazol-1-yl)butane and flexible dicarboxylate ligands: luminescence sensing towards Fe3+

2020 ◽  
Vol 76 (11) ◽  
pp. 1024-1033
Author(s):  
Fang-Hua Zhao ◽  
Shi-Yao Li ◽  
Wen-Yu Guo ◽  
Zi-Hao Zhao ◽  
Xiao-Wen Guo ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Solid State ◽  
Hydrogen Bonds ◽  
Layer Structure ◽  
Three Dimensional ◽  
Supramolecular Network ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
X Ray ◽  
Vis Spectroscopy

Two new CdII MOFs, namely, two-dimensional (2D) poly[[[μ2-1,4-bis(1H-benzimidazol-1-yl)butane](μ2-heptanedioato)cadmium(II)] tetrahydrate], {[Cd(C7H10O4)(C18H18N4)]·4H2O} n or {[Cd(Pim)(bbimb)]·4H2O} n (1), and 2D poly[diaqua[μ2-1,4-bis(1H-benzimidazol-1-yl)butane](μ4-decanedioato)(μ2-decanedioato)dicadmium(II)], [Cd2(C10H16O4)2(C18H18N4)(H2O)2] n or [Cd(Seb)(bbimb)0.5(H2O)] n (2), have been synthesized hydrothermally based on the 1,4-bis(1H-benzimidazol-1-yl)butane (bbimb) and pimelate (Pim2−, heptanedioate) or sebacate (Seb2−, decanedioate) ligands. Both MOFs were structurally characterized by single-crystal X-ray diffraction. In 1, the CdII centres are connected by bbimb and Pim2− ligands to generate a 2D sql layer structure with an octameric (H2O)8 water cluster. The 2D layers are further connected by O—H...O hydrogen bonds, resulting in a three-dimensional (3D) supramolecular structure. In 2, the CdII centres are coordinated by Seb2− ligands to form binuclear Cd2 units which are linked by bbimb and Seb2− ligands into a 2D hxl layer. The 2D layers are further connected by O—H...O hydrogen bonds, leading to an 8-connected 3D hex supramolecular network. IR and UV–Vis spectroscopy, thermogravimetric analysis and solid-state photoluminescence analysis were carried out on both MOFs. Luminescence sensing experiments reveal that both MOFs have good selective sensing towards Fe3+ in aqueous solution.

scholarly journals Crystal structure ofcatena-poly[bis(formato-κO)bis[μ2-1,1′-(1,4-phenylene)bis(1H-imidazole)-κ2N3:N3′]cobalt(II)]

2015 ◽  
Vol 71 (9) ◽  
pp. m156-m157
Author(s):  
Guo-Wang Xu ◽  
Ye-Nan Wang ◽  
Hong-Xu Xia ◽  
Zhong-Long Wang
Keyword(s):  
Crystal Structure ◽  
Three Dimensional ◽  
Dimensional Structure ◽  
Supramolecular Network ◽  
Nitrate Hexahydrate ◽  
Coordination Geometry ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Hydrogen Bonding Interactions ◽  
Block Shaped Crystal

A red block-shaped crystal of the title compound, [Co(HCOO)2(C12H10N4)2]n, was obtained by the reaction of cobalt(II) nitrate hexahydrate, formic acid and 1,1′-(1,4-phenylene)bis(1H-imidazole) (bib) molecules. The asymmetric unit consists of one CoIIcation, one formate ligand and two halves of a bib ligand. The central CoIIcation, located on an inversion centre, is coordinated by two carboxylate O atoms and four N atoms from bib ligands, completing an octahedral coordination geometry. The CoIIcentres are bridged by bib ligands, giving a two-dimensional net. Topologically, taking the CoIIatoms as nodes and the bib ligands as linkers, the two-dimensional structure can be simplified as a typicalsql/Shubnikov tetragonal plane network. The structure features C—H...O hydrogen-bonding interactions between formate and bib ligands, resulting in a three-dimensional supramolecular network.

Two New Copper (II) Complexes with the Same NNO Donor Schiff Base Ligand: A Monomer and a Dimer

2012 ◽  
Vol 67 (3) ◽  
pp. 192-196
Author(s):  
Bao Lin Liu ◽  
Yan Xia Wang ◽  
Ruo Jie Tao
Keyword(s):  
Experimental Data ◽  
Thermal Analysis ◽  
Schiff Base ◽  
Magnetic Measurements ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Antiferromagnetic Exchange ◽  
X Ray ◽  
Distorted Octahedral ◽  
Best Fit

Two new copper(II) complexes, [(CuL)2(μ1,1-N3)2]・2H2O (1) and [Cu(HL)(2,2ʹ-bipy)- (CH3COO)]・ClO4・H2O (2), have been synthesized using the tridentate NNO Schiffbase ligand 2- [(2-aminoethylimino)methyl]-6-methoxyphenol (HL). They have been characterized by elemental analysis, IR spectroscopy, thermal analysis, and single-crystal X-ray analysis. The copper environment is distorted square pyramidal in complex 1: two nitrogen atoms and one oxygen atom from the ligands and two nitrogen atoms from two azido ligands build the coordination polyhedron around the copper atom. The Cu-Nazide-Cu angle in complex 1 is 85.6°. This is unusually small in comparison with the same angle in other end-on doubly azido-bridged dimers. Complex 2 is mononuclear with the Cu atom having a slightly distorted octahedral geometry. Magnetic measurements of 1 have been performed in the temperature range from 2 to 300 K. The experimental data indicate an antiferromagnetic exchange interaction between copper(II) ions bridged by the azido ligand. The best-fit parameters for complex 1 are g = 2.18 and J = −1.31 cm−1.

scholarly journals Single-crystal X-ray diffraction study of a host–guest system comprising monofunctionalized-hydroxy pillar[5]arene and 1-octanamine

2018 ◽  
Vol 74 (8) ◽  
pp. 1117-1120
Author(s):  
Talal F. Al-Azemi ◽  
Mickey Vinodh ◽  
Abdirahman A. Mohamod ◽  
Fatemeh H. Alipour
Keyword(s):  
Hydrogen Bonding ◽  
Alkyl Chain ◽  
Supramolecular Interactions ◽  
Asymmetric Unit ◽  
X Ray Diffraction ◽  
X Ray ◽  
Hydrogen Bonding Interactions ◽  
Guest Species ◽  
Guest System ◽  
Macrocycle Cavity

Co-crystallization of a monofunctionalized hydroxy pillar[5]arene with 1-octanamine resulted in the formation of an inclusion complex where the alkyl chain is threaded in the macrocycle cavity, namely 1,2,3,4-(1,4-dimethoxy)-5-(1-hydroxy-4-methoxy)-pillar[5]arene–1-octanamine–water (1/1/1), C44H48O10·C8H19N·H2O. The guest compound is stabilized inside the cavity by hydrogen-bonding and C—H...π interactions. The water molecule in the asymmetric unit mediates the formation of a supramolecular dimer by hydrogen-bonding interactions. These functionalized-pillararene hosts expand the possibility of exploring more supramolecular interactions with various guest species.

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