scholarly journals Conductivity and viscosity of dilute solutions of lithium nitrate and cadmium iodide in binary and ternary mixtures of acetone with methyl alcohol, ethyl alcohol and water

1909 ◽  
Vol 69 (1) ◽  
Author(s):  
Harry C. Jones ◽  
Edward G. Mahin
Keyword(s):  
Ethyl Alcohol ◽  
Methyl Alcohol ◽  
Ternary Mixtures ◽  
Lithium Nitrate ◽  
Cadmium Iodide ◽  
Dilute Solutions ◽  
Binary And Ternary Mixtures ◽  
Alcohol Ethyl

scholarly journals A METHOD OF ANALYSIS FOR THE SYSTEM: BENZENE – ETHYL ALCOHOL – CARBON TETRACHLORIDE

1947 ◽  
Vol 25b (3) ◽  
pp. 228-242 ◽  
Author(s):  
A. N. Campbell ◽  
S. I. Miller
Keyword(s):  
Carbon Tetrachloride ◽  
Ethyl Alcohol ◽  
Liquid Mixtures ◽  
Ternary Mixtures ◽  
Refractive Indices ◽  
Binary And Ternary Mixtures

The densities and refractive indices (Nc) of binary and ternary mixtures of benzene, ethyl alcohol, and carbon tetrachloride have been determined at 25 °C. From these data, a method for the analysis of ternary liquid mixtures of these components has been developed. The limit of accuracy in the analysis of ternary mixtures of the pure components is 0.3%. The method can be applied to the analysis of commercial materials with an accuracy of 2.0%.

scholarly journals Slow oxidations at high pressures I—Methane and ethane, II—Methyl alcohol, ethyl alcohol, acetaldehyde, and acetic acid

1934 ◽  
Vol 147 (862) ◽  
pp. 555-571 ◽  
Keyword(s):  
High Pressure ◽  
Acetic Acid ◽  
Optimum Condition ◽  
Ethyl Alcohol ◽  
Methyl Alcohol ◽  
High Pressures ◽  
Hydrocarbon Gases ◽  
Hydrocarbon Combustion ◽  
Liquid Products ◽  
Alcohol Ethyl

In two recent papers from these laboratories it was shown that when methane- and ethane-oxygen mixtures containing excess of the hydrocarbon react at high pressure various liquid products can be isolated. For methane-oxygen mixtures methyl alcohol and water are found, and for ethane-oxygen mixtures ethyl alcohol, acetaldehyde, methyl alcohol, acetic acid, formic acid, and water. These products being important for the light they throw on the mechanism of hydrocarbon combustion and because they suggest means for using waste hydrocarbon gases, further experiments have now been made with the object of finding the order of their formation and the optimum condition for their survival.

Reactions of nitro sugars. XI. Formation of 2,3-unsaturated hexonolactones by denitration of methyl deoxynitroglycosides

1969 ◽  
Vol 47 (15) ◽  
pp. 2811-2818 ◽  
Author(s):  
Hans H. Baer ◽  
Werner Rank
Keyword(s):  
Aluminum Oxide ◽  
Ethyl Alcohol ◽  
Methyl Alcohol ◽  
Crystalline Form ◽  
Unsaturated Lactone ◽  
Alcohol Ethyl ◽  
Basic Aluminum

Treatment of methyl 4,6-O-benzylidene-3-deoxy-3-nitro-β-D-glucopyranoside (1) and its α-anomer (3), as well as of methyl 4,6-O-benzylidene-2,3-dideoxy-3-nitro-β-D-erythro-hex-2-enopyranoside (2) and its α-anomer (4), with basic aluminum oxide in refluxing toluene, leads to loss of the nitro and glycosidic methoxyl groups. As a common product an α,β-unsaturated lactone, 4,6-O-benzylidene-2,3-dideoxy-D-erythro-hex-2-enono-1,5-lactone (5), was isolated in crystalline form. The β-D-manno isomer (6) of 1 incurs epimerization to 1 and partial conversion to 5. Methyl 4,6-O-benzylidene-3-deoxy-3-nitro-β-D-galacto-pyranoside (7) and methyl 4,6-O-benzylidene-2,3-dideoxy-3-nitro-β-D-threo-hex-2-enopyranoside (8) similarly yield a crystalline lactone, 4,6-O-benzylidene-2,3-dideoxy-D-threo-hex-2-enono-1,5-lactone (9). The mechanism of this novel reaction is discussed, and certain differences in reactivity in the gluco and galacto series are pointed out. Base-catalyzed additions of methyl alcohol, ethyl alcohol, and piperidine to 8 afford methyl 4,6-O-benzylidene-3-deoxy-2-O-methyl-3-nitro-β-D-galactopyranoside (10), its 2-O-ethyl analogue (11), and methyl 4,6-O-benzylidene-2,3-dideoxy-3-nitro-2-piperidino-β-D-galacto-pyranoside (12), respectively.

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