scholarly journals Solid–Liquid Interfaces: Molecular Structure, Thermodynamics, and Crystallization

MRS Bulletin ◽  
2004 ◽  
Vol 29 (12) ◽  
pp. 920-926 ◽  
Author(s):  
Mark Asta ◽  
Frans Spaepen ◽  
J. Friso van der Veen

AbstractMaterials phenomena ranging from the melting or freezing of ice to biomineralization in living organisms, to lubrication and the commercial casting of superalloys, are known to be critically influenced by molecular-scale structure and processes occurring at the interfaces between the crystalline solid and liquid phases. The properties of solid–liquid interfaces have long been a topic of intense interest in materials science, primarily because of their role in governing nucleation, growth, and morphological evolution in crystal growth from the melt or solutions.This issue of the MRS Bulletin provides an overview, highlighting new developments in experiment, theory, and modeling techniques that have led to substantial recent progress in the characterization of the molecular-level structural and thermodynamic properties of solid–liquid interfaces and their consequences for a variety of crystallization phenomena.

MRS Bulletin ◽  
2019 ◽  
Vol 44 (12) ◽  
pp. 949-955 ◽  
Author(s):  
Michael J. Zachman ◽  
Niels de Jonge ◽  
Robert Fischer ◽  
Katherine L. Jungjohann ◽  
Daniel E. Perea

Abstract


2016 ◽  
Vol 264 (1) ◽  
pp. 64-70 ◽  
Author(s):  
S. ESWARA ◽  
C. MITTERBAUER ◽  
T. WIRTZ ◽  
S. KUJAWA ◽  
J.M. HOWE

2019 ◽  
Vol 91 (4) ◽  
pp. 707-716 ◽  
Author(s):  
Kazue Kurihara

Abstract This article reviews the surface forces measurement as a novel tool for materials science. The history of the measurement is briefly described in the Introduction. The general overview covers specific features of the surface forces measurement as a tool for studying the solid-liquid interface, confined liquids and soft matter. This measurement is a powerful way for understanding interaction forces, and for characterizing (sometime unknown) phenomena at solid-liquid interfaces and soft complex matters. The surface force apparatus (SFA) we developed for opaque samples can study not only opaque samples in various media, but also electrochemical processes under various electrochemical conditions. Electrochemical SFA enables us to determine the distribution of counterions between strongly bound ones in the Stern layer and those diffused in the Gouy-Chapman layer. The shear measurement is another active area of the SFA research. We introduced a resonance method, i.e. the resonance shear measurement (RSM), that is used to study the effective viscosity and lubricity of confined liquids in their thickness from μm to contact. Advantages of these measurements are discussed by describing examples of each measurement. These studies demonstrate how the forces measurement is used for characterizing solid-liquid interfaces, confined liquids and reveal unknown phenomena. The readers will be introduced to the broad applications of the forces measurement in the materials science field.


2001 ◽  
Vol 73 (10) ◽  
pp. 1613-1623 ◽  
Author(s):  
Tsuguo Sawada

Among the recent topics of photothermal (PT) applications of lasers, we focus on ultrafast (<=1.0 ns) photothermal/photoacoustic (PT/PA) phenomena occurring at interfaces, which play important roles in nanoscale materials science and technology. Here, we describe our recently developed novel PT techniques called transient reflecting grating (TRG) spectrometries. These techniques have been applied to the studies of solid surfaces, film substrates, and solid/liquid interfaces.


2005 ◽  
Vol 20 (7) ◽  
pp. 1629-1640 ◽  
Author(s):  
H. Saka ◽  
K. Sasaki ◽  
S. Tsukimoto ◽  
S. Arai

Recent progress in in situ observation of solid–liquid interfaces by means of transmission electron microscopy, carried out by the Nagoya group, was reviewed. The results obtained on pure materials are discussed based on Jackson's theory. The structure of the solid–liquid interfaces of eutectic alloys was also observed. The in situ observation technique of solid–liquid interface is applied to industrially important reactions which include liquid phases.


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