Direct measurement of the viscoelectric effect in water

The viscoelectric effect concerns the increase in viscosity of a polar liquid in an electric field due to its interaction with the dipolar molecules and was first determined for polar organic liquids more than 80 y ago. For the case of water, however, the most common polar liquid, direct measurement of the viscoelectric effect is challenging and has not to date been carried out, despite its importance in a wide range of electrokinetic and flow effects. In consequence, estimates of its magnitude for water vary by more than three orders of magnitude. Here, we measure the viscoelectric effect in water directly using a surface force balance by measuring the dynamic approach of two molecularly smooth surfaces with a controlled, uniform electric field between them across highly purified water. As the water is squeezed out of the gap between the approaching surfaces, viscous damping dominates the approach dynamics; this is modulated by the viscoelectric effect under the uniform transverse electric field across the water, enabling its magnitude to be directly determined as a function of the field. We measured a value for this magnitude, which differs by one and by two orders of magnitude, respectively, from its highest and lowest previously estimated values.

Generalized Newtonian flow analysis in the microchannel manufactured by SLA considering nano-scale stair effect

SLA (stereolithography), as a rapid and accurate additive manufacturing method, can be used to mold the microchannel. The stair effect is inevitable when the part is printed layer by layer, which has an important influence on the printing performance. In the current work, the power-law flow in the microchannel with nano-scale stairs manufactured by SLA is simulated and investigated. To improve the stability caused by the non-Newtonian behavior, a modified lattice Boltzmann method (LBM) is proposed and validated. Then, a series of simulations are conducted and analyzed, the results show that both the stair effect and power-law index are important factors. The stairs on the surface force the streamlines to be curved and increase the outlet velocity. In addition, different power-law indexes result in completely different flows. The small power-law index leads to a much larger velocity than other cases, while the large power-law index makes the outlet velocity unstable at the middle position.

Microscopic origin of the effect of substrate metallicity on interfacial free energies

We investigate the effect of the metallic character of solid substrates on solid–liquid interfacial thermodynamics using molecular simulations. Building on the recent development of a semiclassical Thomas–Fermi model to tune the metallicity in classical molecular dynamics simulations, we introduce a thermodynamic integration framework to compute the evolution of the interfacial free energy as a function of the Thomas–Fermi screening length. We validate this approach against analytical results for empty capacitors and by comparing the predictions in the presence of an electrolyte with values determined from the contact angle of droplets on the surface. The general expression derived in this work highlights the role of the charge distribution within the metal. We further propose a simple model to interpret the evolution of the interfacial free energy with voltage and Thomas–Fermi length, which allows us to identify the charge correlations within the metal as the microscopic origin of the evolution of the interfacial free energy with the metallic character of the substrate. This methodology opens the door to the molecular-scale study of the effect of the metallic character of the substrate on confinement-induced transitions in ionic systems, as reported in recent atomic force microscopy and surface force apparatus experiments.

The contribution of plastic sink-in to the static friction of single asperity microscopic contacts

We report microscale friction experiments for diamond/metal and diamond/silica contacts under gigapascal contact pressures. Using a new nanoprobe technique that has a sufficient dynamic range of force and stiffness, we demonstrate the processes involved in the transition from purely interface sliding at the nanoscale to the situation where at least one of the sliding bodies undergoes some plastic deformation. For sliding of micrometre-sized tips on metallic substrates, additional local plastic yielding of the substrate resulting from tangential tractions causes the tip to sink into the surface, increasing the contact area in the direction of loading and resulting in a static friction coefficient higher than the kinetic during ploughing. This sink-in is largely absent in fused silica, and no friction drop is observed, along with lower friction in general. The transition from sink-in within the static friction regime to ploughing in the sliding friction regime is mediated by failure of the contact interface, indicated by a sharp increase in energy dissipation. At lower contact pressures, the elastic interfacial sliding behaviour characteristic of scanning probe or surface force apparatus experiments is recovered, bridging the gap between the exotic realm of nanotribology and plasticity-dominated macroscale friction.

Preliminary results on the simulation of the 1999 Orissa super cyclone using a GCM with a new boundary layer code

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Modifying of the dielectric properties of adsorbed water in the force field of a solid surface

The results of thermodynamic and acoustoelectric studies of changes in the dielectric properties of adsorbed water under the influence of a solid surface force field are presented. It is noted that the dielectric properties of adsorbed water depend not only on the characteristic size of the system, but also on the interaction energy with the solid surface. Near the hydrophilic solid surface, the density of adsorbed water is increased and the mobility of molecules is reduced. The opposite effect occurs for hydrophobic surfaces. The frequency dependences of the dielectric properties of adsorbed water, as in the case of water in the solid and liquid phase, can be characterized using Debye relaxation theory. It is shown that a significant increase in the orientational dielectric relaxation time in adsorbed water can be explained by taking into account the energy of interfacial boundaries.

Study on the Seepage Force-Induced Stress and Poroelastic Stress by Flow Through Porous Media Around a Vertical Wellbore

Fluid flowing through reservoir pores not only generates poroelastic stress but also exerts seepage force on rock skeleton. However, the mechanism of seepage force is not clear. Traditional methods of analyzing wellbore stability and hydraulic fracture initiation are mainly focused on the poroelastic stress without the effects of seepage force. Based on the linear elasticity and consolidation theory, this paper analyzed the mechanism of seepage force and poroelastic stress, and presented an analytical solution for seepage force-induced stress around a vertical wellbore. It also introduced how to calculate poroelastic stress by exerting hypothetical body force and surface force. Through comparison and superposition of stress fields, this paper studied the change characteristics of the poroelastic and seepage force-induced stress under different borehole pressures and the effects of seepage force on the wellbore tensile failure. Numerical simulation results show that when fluid flows through the rock, using traditional models without considering, the effect of seepage force to calculate the borehole pressure-induced stress will result in lower calculation results. Compared with the traditional model, seepage force-induced circumferential tensile stress is larger, and the seepage force significantly reduces the formation breakdown pressure. Rocks near the borehole wall with lower permeability and larger Poisson’s ratio have a greater action of seepage force. When fluid flows through the reservoir, the effects of seepage forces cannot be ignored in the analysis of hydraulic fracturing and wellbore stability.

Protein- and Cell-Resistance of Zwitterionic Peptide-Based Self-Assembled Monolayers: Anti-Biofouling Tests and Surface Force Analysis

Peptide-based self-assembled monolayers (peptide-SAMs) with specific zwitterionic amino acid sequences express an anti-biofouling property. In this work, we performed protein adsorption and cell adhesion tests using peptide-SAMs with repeating units of various zwitterionic pairs of amino acids (EK, DK, ER, and DR). The SAMs with the repeating units of EK and DK (EK and DK SAMs) manifested excellent bioinertness, whereas the SAMs with the repeating units of ER and DR (ER and DR SAMs) adhered proteins and cells. We also performed surface force measurements using atomic force microscopy to elucidate the mechanism underlying the difference in the anti-biofouling property. Our measurements revealed that water-induced repulsion with a range of about 8 nm acts between EK SAMs (immobilized on both probe and substrate) and DK SAMs, whereas such repulsion was not observed for ER and DR SAMs. The strength of the repulsion exhibited a clear correlation with the protein- and cell-resistance of the SAMs, indicating that the interfacial water in the vicinity of EK and DK SAMs is considered as a physical barrier to deter protein and cells from their adsorption or adhesion. The range of the repulsion observed for EK and DK SAMs is longer than 8 nm, indicating that the hydrogen bonding state of the interfacial water with a thickness of 4 nm is modified by EK and DK SAMs, resulting in the expression of the anti-biofouling property.