Development of a Backfill for Containment of High-Level Nuclear Waste

1981 ◽  
Vol 11 ◽  
Author(s):  
Floyd N. Hodges ◽  
Joseph H. Westsik ◽  
Lane A. Bray

ABSTRACTSodium and calcium bentonites, pressed to densities between 1.9 and 2.2 g/cm3, have hydraulic conductivities in the range of 10−11 to 10−13 cm/s. Batch sorption distribution ratios (Rd) indicate that Sr, Cs, and Am are strongly sorbed on bentonites and zeolites, that Np and U are moderately sorbed on bentonites and zeolites, and that Am, Np, U, I, and Tc are strongly sorbed on charcoal. Sorption results with basalt and tuff ground waters are similar; however, iodine in tuff ground water sorbs more strongly on bentonites Thermal diffusivity measurements for dry, compacted (p ∼ 2.1 g/cm3) sodium bentonite indicate that the thermal conductivity of a high density bentonite backfill should be roughly similar to that of silicate host rocks (basalt, granite, tuff). These results indicate that a bentonite backfill can significantly delay the first release of many radionuclides into the host rock and that by forming a diffusion barrier a bentonite backfill can significantly decrease the longterm release rate of radionuclides from the waste package.

2020 ◽  
Vol 205 ◽  
pp. 01001
Author(s):  
Antonio Gens ◽  
Ramon B. de Vasconcelos ◽  
Sebastià Olivella

Recently, there is a tendency to explore the possibility of increasing the maximum design temperature in deep geological repositories for high-level nuclear waste and spent fuel. In the paper, a number of issues related to the use of higher temperatures are reviewed. Both bentonite barriers and argillaceous host rocks are addressed. An application involving the modelling of a large-scale field test conducted at a maximum temperature of 140ºC is presented. It is shown that currently available theoretical formulations and computer codes are capable to deal with temperatures above 100ºC and to reproduce satisfactorily the thermally-induced overpressures in the rock.


1986 ◽  
Vol 84 ◽  
Author(s):  
S. G. Pitman

AbstractIn current conceptual designs, a mild steel (ASTM A?16 Grade WCA) is the relerence container material for use in high level nuclear waste packages intended for emplacement in a salt repository. The resistance of the steel to stress corrosion crackinq (SCC) is being investigated as part of the effort underway to verify the suitability of the material for waste package applications. Static tests (U-bend and bolt-loaded fracture toughness specimens) and dynamic tests (slow strain rate and corrosion fatigue) were conducted on both as-cast and weldment specimens of the material, in both low-Mg and high-Mg halite-saturated brines, in the temperature range of 90 to 200°C. The investigations indicate that the steel is not susceptible to SCC under the test conditions employed.


1984 ◽  
Vol 44 ◽  
Author(s):  
M. J. Steindler ◽  
W. B. Seefeldt

Some nuclear waste is destined for disposal in deep geological formations. The disposal system for wastes from commercial nuclear activities, and perhaps also for high-level wastes from defense-related activities, is to be designed and operated by the Department of Energy (DOE) and licensed by the Nuclear Regulatory Commission (NRC). The Nuclear Waste Policy Act [1] outlines some of the procedures and schedules that are to be followed by DOE in carrying out its assignment in the disposal of high-level nuclear waste (HLW). The regulations of the NRC that deal with HLW [2] are only partly in place, and amendments (e.g., related to the unsaturated zone) are yet to be approved and issued. The Environmental Protection Agency (EPA) has issued only draft versions of the regulations pertaining to HLW disposal [3], but key features of these drafts are at present in adequate agreement with NRC documents. On the basis of the trends that have become evident in the last few years, the DOE will be required to substantiate performance predictions for all pertinent aspects of a repository, especially the performance of the engineered waste package. The basis for demonstrating that the waste package performance in the repository will be in concert with the requirements is data on the waste package materials. These key materials data must clearly be highly reliable, and DOE will be required to assure this reliability. This paper addresses the organization and functions that have been assembled to aid in establishing the quality of materials data that are important in the licensing of a waste repository.


2002 ◽  
Vol 713 ◽  
Author(s):  
Joon H. Lee ◽  
Kevin G. Mon ◽  
Dennis E. Longsine ◽  
Bryan E. Bullard ◽  
Ahmed M. Moniba

ABSTRACTThe technical basis for Site Recommendation (SR) of the potential repository for high-level nuclear waste at Yucca Mountain, Nevada has been completed. Long-term containment of the waste and subsequent slow release of radionuclides from the engineered barrier system (EBS) into the geosphere will rely on a robust waste package (WP) design, among other EBS components as well as the natural barrier system. The WP and drip shield (DS) degradation analyses for the total system performance assessment (TSPA) baseline model for the SR have shown that, based on the current corrosion models and assumptions, both the DSs and WPs do not fail within the regulatory compliance time period (10,000 years). From the perspective of initial WP failure time, the analysis results are encouraging because the upper bounds of the baseline case are likely to represent the worst case combination of key corrosion model parameters that significantly affect long-term performance of WPs in the potential repository. The estimated long life-time of the WPs in the current analysis is attributed mostly to the following two factors that delay the onset of stress corrosion cracking (SCC): (1) the stress mitigation to substantial depths from the outer surface in the dual closure-lid weld regions; and (2) the very low general-corrosion rate applied to the closure-lid weld regions to corrode the compressive stress zones. Uncertainties are associated with the current WP SCC analysis. These are stress mitigation on the closure-lid welds, characterization of manufacturing flaws applied to SCC, and general corrosion rate applied to the closurelid weld regions. These uncertainties are expected to be reduced as additional data and analyses are developed.


2013 ◽  
Vol 3 (1) ◽  
pp. 60-69 ◽  
Author(s):  
Hamid Aït Abderrahim ◽  
Didier De Bruyn ◽  
Gert Van den Eynde ◽  
Sidney Michiels

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