Effect of Oxygen Plasma Treatments on Polypropylene-Epoxy Interfacial Strength

1989 ◽  
Vol 153 ◽  
Author(s):  
E. Occhiello ◽  
M. Morra ◽  
G. Morini ◽  
F. Garbassi

AbstractThe effect of oxygen plasma treatment on adhesion and surface properties of polypropylene (PP) was assessed. An oxygen rich modified PP layer, immiscible with bulk PP, was formed by the treatment. Contact angle measurements showed that macromolecular motions led with time to rearrangements of the surface layer drastically decreasing its wettability, while its composition, measured by XPS, remained unaffected.The shear strength of PP-epoxy joints increased after plasma treatment. The locus of failure was found to occur at the PP/epoxy interface for untreated PP, within PP in the case of oxygen-plasma-treated samples, close to the modified PP/bulk PP interface. This result suggests that the plasma treament improves the interaction at the PP/epoxy interface, but weakens the mechanical strength of the surface layer thereby creating a weak point at the modified PP/bulk PP interface.

1989 ◽  
Vol 154 ◽  
Author(s):  
E. Occhiello ◽  
M. Morra ◽  
G. Morini ◽  
F. Garbassi

AbstractThe effect of oxygen plasma treatment on adhesion and surface properties of polypropylene (PP) was assessed. An oxygen rich modified PP layer, immiscible with bulk PP, was formed by the treatment. Contact angle measurements showed that macromolecular motions led with time to rearrangements of the surface layer drastically decreasing its wettability, while its composition, measured by XPS, remained unaffected.The shear strength of PP-epoxy joints increased after plasma treatment. The locus of failure was found to occur at the PP/epoxy interface for untreated PP, within PP in the case of oxygen-plasma-treated samples, close to the modified PP/bulk PP interface. This result suggests that the plasma treament improves the interaction at the PP/epoxy interface, but weakens the mechanical strength of the surface layer thereby creating a weak point at the modified PP/bulk PP interface.


2010 ◽  
Vol 24 (15n16) ◽  
pp. 2682-2687 ◽  
Author(s):  
JONG-HYOUNG KIM ◽  
NORITSUGU UMEHARA ◽  
HIROYUKI KOUSAKA ◽  
MAMORU SHIMADA ◽  
MITSURU HASEGAWA

This paper has reported the effect of oxygen and argon plasma treatments of CIIR rubber using Attenuated Total Reflectance (ATR) and surface energy measurements. Plasma treatment led to changes in the surface energy from 31 to 45.7 mN/m. Plasma treatment conditions influenced both the changes in surface energy and stability, and they also became more difficult to obtain good contact angle measurements. However, plasma treatments made the interfacial properties to be stabilized. ATR measurements revealed that changes in surface energy with treatment time are due mostly to increased oxygen functionality.


2011 ◽  
Vol 11 (11) ◽  
pp. 3031-3035 ◽  
Author(s):  
W. S. Shih ◽  
S. J. Young ◽  
L. W. Ji ◽  
W. Water ◽  
T. H. Meen ◽  
...  

2017 ◽  
Vol 724 ◽  
pp. 348-352 ◽  
Author(s):  
Shubhangi Khadtare ◽  
Avinash S. Bansode ◽  
V.L. Mathe ◽  
Nabeen K. Shrestha ◽  
Chinna Bathula ◽  
...  

1995 ◽  
Vol 176 (1) ◽  
pp. 128-137 ◽  
Author(s):  
M. DOMINGO-GARCIA ◽  
I. FERNÁNDEZ-MORALES ◽  
F.J. LÓPEZ-GARZÓN ◽  
C. MORENO-CASTILLA ◽  
M. PYDA

2017 ◽  
Vol 9 (2) ◽  
Author(s):  
Bekim Osmani ◽  
Gabriela Gerganova ◽  
Bert Müller

AbstractPolydimethylsiloxanes (PDMS) have drawn attention because of their applicability in medical implants, soft robotics and microfluidic devices. This article examines the formation of dedicated nanostructures on liquid submicrometer PDMS films when exposed to oxygen-plasma treatment. We show that by using a vinyl-terminated PDMS prepolymer with a molecular weight of 800 g/mol, one can bypass the need of solvent, copolymer, or catalyst to fabricate wrinkled films. The amplitude and periodicity of the wrinkles is tuned varying the thickness of the PDMS film between 150 and 600 nm. The duration of the plasma treatment and the oxygen pressure determine the surface morphology. The amplitude was found between 30 and 300 nm with periodicities ranging from 500 to 2800 nm. Atomic force microscopy was used to measure film thickness, amplitude and wrinkle periodicity. The hydrophobic recovery of the nanostructured PDMS surface, as assessed by dynamic contact angle measurements, scales with nanostructure’s fineness, associated with an improved biocompatibility. The mechanical properties were extracted out of 10,000 nanoindentations on 50×50-μm


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