Radioactive Tracer Study Performed in a Dipole Geometry in a Highly Conductive Fracture Zone

1990 ◽  
Vol 212 ◽  
Author(s):  
Johan Byegård ◽  
Gunnar Skarnemark ◽  
Mats Skålberg
Keyword(s):  
Metal Ions ◽  
Metal Complexes ◽  
Fracture Zone ◽  
Radioactive Tracer ◽  
Tracer Experiment ◽  
Tracer Study ◽  
Redox Potentials ◽  
Chemical Analogue

ABSTRACTA radioactive tracer experiment has been performed in a highly conductive fracture zone, using a dipole geometry. Anions (131I− and 82Br−) and complexed metal ions (51Cr-EDTA, 58Co-EDTA, 111In-EDTA, 140La-DOTA, 160Tb-EDTA, 169Yb-EDTA and 177Lu-DOTA) have been injected and their properties as non-sorbing tracers were evaluated. Besides, studies of slightlysorbing cations (24Na+, 58Co2+, 86Rb+ and 201T1+) were performed. 99mTcO4 and its chemical analogue 186ReO4 were also injected to study the behaviour of Tc at low redox-potentials. Breakthrough was obtained for Re and for all metal complexes and anions. Some differences in the recovery yields could be seen. No transport of cations, except for Na, could be measured. No breakthrough of Tc could be observed. This indicates that TcO4− was reduced and sorbed.

Synthesis, Characterization and in vitro Biological Evaluation of a New Schiff Base Derived from Drug and its Complexes with Transition Metal Ions

2018 ◽  
Vol 69 (7) ◽  
pp. 1678-1681
Author(s):  
Amina Mumtaz ◽  
Tariq Mahmud ◽  
M. R. J. Elsegood ◽  
G. W. Weaver
Keyword(s):  
Schiff Base ◽  
Transition Metal ◽  
Metal Ions ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Free Ligand ◽  
Transition Metal Ions ◽  
Biological Evaluation ◽  
Pyridoxal Hydrochloride

New series of copper (II), cobalt (II), zinc (II), nickel (II), manganese (II), iron (II) complexes of a novel Schiff base were prepared by the condensation of sulphadizine and pyridoxal hydrochloride. The ligand and metal complexes were characterized by utilizing different instrumental procedures like microanalysis, thermogravimetric examination and spectroscopy. The integrated ligand and transition metal complexes were screened against various bacteria and fungus. The studies demonstrated the enhanced activity of metal complexes against reported microbes when compared with free ligand.

scholarly journals Carbonic Anhydrase Inhibitors Part 721 Synthesis and Antiglaucoma Properties of Metal Complexes of p-Fluorobenzolamide

1999 ◽  
Vol 6 (2) ◽  
pp. 67-73 ◽  
Author(s):  
Claudiu T. Supuran ◽  
Andrea Scozzafava ◽  
Luca Menabuoni ◽  
Francesco Mincione ◽  
Fabrizio Briganti ◽  
...  
Keyword(s):  
Intraocular Pressure ◽  
Carbonic Anhydrase ◽  
Metal Ions ◽  
Metal Complexes ◽  
Carbonic Anhydrase Inhibitors ◽  
Physico Chemical ◽  
New Compounds

Metal complexes of a heterocyclic sulfonamides possessing very strong carbonic anhydrase (CA) inhibitory properties, i.e., 5-(p-fluorobenzenesulfonylamido)-1,3,4-thiadiazole-2-sulfonamide (p-fluorobenzolamide) were prepared. The new complexes contained metal ions such as Zn(II), Cu(II), Co(II), Ni(II), Cd(II) and Mn(II). The new compounds were characterized by standard physico-chemical procedures, and assayed as inhibitors of three CA isozymes, CA I, II and IV. Very good inhibition has been evidenced both for the parent sulfonamides as well as for the prepared complexes, against all three investigated isozymes. Some of these new complexes as well as the parent sulfonamide, strongly lowered intraocular pressure (IOP) in normotensive rabbits when administered as a 2% solution into the eye.

scholarly journals Synthesis characterization of Cr(III), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) complexes of 2,12-dimethyl-3-13-di-n-propyl-l,4,ll,14-tetraazacycloeicosa-1,13,l1,13-tetraene

2002 ◽  
Vol 67 (12) ◽  
pp. 825-832 ◽  
Author(s):  
Raghu Prasad ◽  
Mala Mathur
Keyword(s):  
Metal Ions ◽  
Metal Complexes ◽  
Electronic Spectra ◽  
Magnetic Measurements ◽  
Elemental Analyses

Metal complexes of a 20-membered tetraazamacrocycle 2,12-dimethyl-3,13-di-n-propyl 1,4,11,14-tetraazacycloeicosa-1,3,11,13-tetraene(L) of the type [MLX2]X(M=Cr(III), Fe(III); X=NO3)[CoLNO3]NO3, [NiL(NO3)2], [CuL]Cl2 and [ZnLCl2]have been prepared by 2+2 cyclocondensation of 2,3-hexanedione with 1,6-diaminohexane in the presence of metal ions as templates. These complexes were characterized by elemental analyses, conductances, IR and electronic spectra and magnetic measurements.

scholarly journals RECENTES APLICAÇÕES DO ORGANOFOTOCATALISADOR 1,2,3,5-TETRAQUIS(CARBAZOL-9-IL)-4,6- DICIANOBENZENO EM TRANSFORMAÇÕES QUÍMICAS

Química Nova ◽  
2020 ◽  
Author(s):  
Lucas Pugnal ◽  
Emanuele Pissinati ◽  
Karina Quaglio ◽  
Márcio Paixão
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Chemical Transformations ◽  
Redox Potentials ◽  
Research Groups ◽  
Organic Fluorophores ◽  
Metal Free ◽  
Polypyridine Complexes ◽  
Distinguished Research

RECENT APPLICATIONS OF THE ORGANIC PHOTOCATALYST 1,2,3,5-TETRAKIS(CARBAZOL-9-YL)- 4,6-DICIANOBENZENE IN CHEMICAL TRANSFORMATIONS. Ruthenium and iridium polypyridine complexes are among the most employed photocatalysts described in literature. The broad applicability is due to the redox potentials and long half-life times of the excited state which these molecules presented. The pursuit for metal-free alternatives has been intensified in the last few years, therefore, many organic fluorophores were successfully employed as photocatalysts. Among them, 1,2,3,5-tetrakis(carbazol-9-yl)- 4,6-dicianobenzene (4CzIPN) recently drawn attention of the community, and it’s been widely employed by distinguished research groups. Recent studies have shown that this catalyst do not only present similar properties to transition metal complexes, but also, its synthesis can be accomplished more easily and less expensive when compared with the metallic photocatalysts above mentioned. Therefore, 4CzIPN constitutes a metal-free alternative to replace transition metal complexes in conventional photochemical protocols. Moreover, it’s as a powerful ally in the development of new photochemical approaches. In this work, we aim to summarize recent applications of 4CzIPN as catalyst in the emerging field of redox photocatalysis.

scholarly journals Synthesis and Spectral Analysis of Some Metal Ions Complexes with Mixed Ligands of Schiff Base and 1, 10-Phenanthroline

2017 ◽  
Vol 14 (1) ◽  
pp. 135-147
Author(s):  
Baghdad Science Journal
Keyword(s):  
Schiff Base ◽  
Metal Ions ◽  
Metal Complexes ◽  
Mass Spectrometer ◽  
Schiff Base Ligand ◽  
Metal Ion ◽  
Molecular Structures ◽  
Spectroscopic Techniques ◽  
Metal Ion Complexes ◽  
Free Schiff Base

The free Schiff base ligand (HL1) is prepared by being mixed with the co-ligand 1, 10-phenanthroline (L2). The product then is reacted with metal ions: (Cr+3, Fe+3, Co+2, Ni+2, Cu+2 and Cd+2) to get new metal ion complexes. The ligand is prepared and its metal ion complexes are characterized by physic-chemical spectroscopic techniques such as: FT-IR, UV-Vis, spectra, mass spectrometer, molar conductivity, magnetic moment, metal content, chloride content and microanalysis (C.H.N) techniques. The results show the formation of the free Schiff base ligand (HL1). The fragments of the prepared free Schiff base ligand are identified by the mass spectrometer technique. All the analysis of ligand and its metal complexes are in good agreement with the theoretical values indicating the purity of Schiff base ligand and the metal complexes. From the above data, the molecular structures for all the metal complexes are proposed to be octahedral

Modulating extraction and retention of fluorinated β-diketonate metal complexes in perfluorocarbons through the use of non-fluorinated neutral ligands

2021 ◽  
Vol 8 (20) ◽  
pp. 4488-4496
Author(s):  
Tyler L. King ◽  
Orhi Esarte Palomero ◽  
Dawson A. Grimes ◽  
Sean T. Goralski ◽  
Richard A. Jones ◽  
...  
Keyword(s):  
Medical Imaging ◽  
Metal Ions ◽  
Metal Complexes ◽  
Synergistic Extraction ◽  
Donor Ligands ◽  
Nuclear Fuels ◽  
Nitrogen Donor Ligands ◽  
Nitrogen Donor ◽  
Neutral Ligands

Extraction of metal ions into perfluorocarbon solvent with a fluorinated acac ligand is described as well as synergistic extraction with neutral nitrogen donor ligands. Applications include catalysis, nuclear fuels reprocessing, and medical imaging.

scholarly journals Nano-Azo Ligand and Its Superhydrophobic Complexes: Synthesis, Characterization, DFT, Contact Angle, Molecular Docking, and Antimicrobial Studies

2020 ◽  
Vol 2020 ◽  
pp. 1-19
Author(s):  
Gehad G. Mohamed ◽  
Walaa H. Mahmoud ◽  
Ahmed M. Refaat
Keyword(s):  
Crystal Structure ◽  
Contact Angle ◽  
Molecular Docking ◽  
Metal Ions ◽  
Metal Complexes ◽  
Biological Activities ◽  
Thermal Studies ◽  
Free Ligand ◽  
Aminobenzoic Acid ◽  
Azo Ligand

Metal complexes of the 2,2'-(1,3-phenylenebis(diazene-2,1-diyl))bis(4-aminobenzoic acid) diazo ligand (H2L) derived from m-phenylenediamine and p-aminobenzoic acid were synthesized and characterized by different spectral, thermal, and analytical tools. The H2L ligand reacted with the metal ions Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II), and Cd(II) as 1 : 1 stoichiometry. All complexes displayed an octahedral geometry according to the electronic and magnetic moment measurements. The IR spectra revealed the binding of the azo ligand to the metal ions via two azo nitrogen atoms and protonated carboxylate O in a neutral tetradentate manner. Both IR and 1H NMR spectra documented the involvement of the carboxylate group without proton displacement. The thermal studies pointed out that the complexes had higher thermal stability comparable with that of the free ligand. SEM images revealed the presence of the diazo ligand and its Cd(II) complex in a nanostructure form. The contact angle measurements proved that the Cd(II) complex can be considered as a superhydrophobic material. The molecular and electronic structure of H2L and [Cd(H2L)Cl2].H2O were optimized theoretically, and the quantum chemical parameters were calculated. The biological activities of the ligand, as well as its metal complexes, have been tested in vitro against some bacteria and fungi species. The results showed that all the tested compounds have significant biological activities with different sensitivity levels. The binding between H2L and its Cd(II) complex with receptors of the crystal structure of S. aureus (PDB ID: 3Q8U), crystal structure of protein phosphatase (PPZ1) of Candida albicans (PDB ID: 5JPE), receptors of breast cancer mutant oxidoreductase (PDB ID: 3HB5), and crystal structure of Escherichia coli (PDB ID: 3T88) was predicted and given in detail using molecular docking.

Influence of Metal Ions and of Metal Complexes on the Hydrolysis of Salicyl Phosphate

1962 ◽  
Vol 84 (16) ◽  
pp. 3041-3046 ◽  
Author(s):  
Robert. Hofstetter ◽  
Yukito. Murakami ◽  
George. Mont ◽  
Arthur E. Martell
Keyword(s):  
Metal Ions ◽  
Metal Complexes ◽  
Hydrolysis Of
Sign in / Sign up

Export Citation Format

Share Document