Studies of C60 Films Deposited Using Ionized Cluster Beam Deposition Technique

1994 ◽  
Vol 349 ◽  
Author(s):  
Zhong-Min Ren ◽  
Yuan-Cheng Du ◽  
Zhi-Feng Ying ◽  
Xia-Xing Xiong ◽  
Mao-Qi He ◽  
...  

ABSTRACTFilms (with thicknesses about thousands A) of a new form of carbon allotrope, CIO also known as Fullerenes, are deposited on Si(111) substrates using ionized cluster beam deposition (ICBD) technique at low (65V) accelerating voltage V. X-ray &-20 diffraction (XRD) have been used to investigate the structural properties of C6Ofi lms, indicating hexagonal close-packed structure with strong (002) XRD assignment together with weak (100), (112) and(004) assignments. Raman spectra, X-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES) are carried out to make detailed studies of the electronic properties of the films and to illustrate differences between CO films and amorphous carbon films which are deposited by ICBD at high accelerating voltage V >400V. Cio soccer-balls are found to be broken into fragments as accelerating field overtakes about 400V, indicated by the results of XPS, Raman spectra, XRD, and UV/visible absorption spectra.

2012 ◽  
Vol 520 (14) ◽  
pp. 4803-4807 ◽  
Author(s):  
Monica de Simone ◽  
Elena Snidero ◽  
Marcello Coreno ◽  
Gero Bongiorno ◽  
Luca Giorgetti ◽  
...  

1994 ◽  
Vol 359 ◽  
Author(s):  
Zhong-Min Ren ◽  
Xia-Xing Xiong ◽  
Yuan-Cheng Du ◽  
Zhi-Feng Ying ◽  
Liang-Yao Chen ◽  
...  

ABSTRACTC60 films have been deposited using a partially ionized cluster beam deposition (PIBD) technique. The experimental results show that as Va. exceeds about 400 V almost all the C60 molecules fragmentate at collision with the substrate and the obtained films turn to be amorphous carbon layers at elevated Va, indicated by measurements of Raman spectra, X-ray diffraction, and ellipsometry.


1997 ◽  
Vol 56 (11) ◽  
pp. 6958-6964 ◽  
Author(s):  
M. Ehbrecht ◽  
B. Kohn ◽  
F. Huisken ◽  
M. A. Laguna ◽  
V. Paillard

1999 ◽  
Vol 593 ◽  
Author(s):  
Oliver Goetzberger ◽  
Nobuaki Kojima ◽  
Aurangzeb Khan ◽  
Masafumi Yamaguchi

ABSTRACTStudies on the electrical conductivity of molecular beam deposited carbon films after annealing of the carbon films have been carried out. Detailed temperature dependence of conductivity on the as-deposited and on annealed samples has been investigated. The results were interpreted in terms of a model which includes a variable range hopping and strongly scattering metallic components. A correlation between annealing behavior of the electrical conductivity and the results of x-ray photoelectron spectroscopy and Raman spectroscopy is presented.


1996 ◽  
Vol 03 (01) ◽  
pp. 1007-1011
Author(s):  
P. MÉLINON ◽  
V. PAILLARD ◽  
V. DUPUIS ◽  
J.P. PEREZ ◽  
J. TUAILLON ◽  
...  

The properties of thin films obtained by low-energy cluster-beam deposition are reviewed. The main characteristics are the nanoscale granular structure and the memory effect of the free-cluster properties. The first point is evidenced by the specific magnetic properties of transition-metal films, which are intermediate between amorphous and bulk phases, while the second point is illustrated from carbon films exhibiting the electronic structure of the free carbon cluster.


2004 ◽  
Vol 100 (1-2) ◽  
pp. 173-176 ◽  
Author(s):  
M Bruzzi ◽  
S Miglio ◽  
M Scaringella ◽  
G Bongiorno ◽  
P Piseri ◽  
...  

2012 ◽  
Vol 549 ◽  
pp. 720-723
Author(s):  
Bo Cao ◽  
Tong Rui Yang ◽  
Gong Ping Li ◽  
Seong Jin Cho ◽  
Hee Kim

The Cu thin films were deposited on P type Si (111) substrates by ionized cluster beam (ICB) technique. The surface properties and atomic binding energy of Cu thin films were studied by X-ray Photoelectron Spectroscopy (XPS). The results show that for all XPS spectra of Cu/SiO2/Si (111) samples deposited by neutral cluster and ionized cluster beam (Va=5 kV), the atomic binding energy of the films was no differences with bulk materials. The reason may be that the local energy deposition and atomic restructuring caused by surface treatment process resulting in the XPS spectra of the copper films was similar with bulk standard copper.


2002 ◽  
Vol 89 (28) ◽  
Author(s):  
L. Ravagnan ◽  
F. Siviero ◽  
C. Lenardi ◽  
P. Piseri ◽  
E. Barborini ◽  
...  

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