Эмиссионные спектры молекулярных газов CHF-=SUB=-3-=/SUB=-, CCl-=SUB=-2-=/SUB=-F-=SUB=-2-=/SUB=-, SF-=SUB=-6-=/SUB=- в диапазоне 3-20 nm при импульсном лазерном возбуждении с использованием различных газовых струй в качестве мишеней

The article considers the results of studies of the emission spectra of CHF3, CCl2F2, SF6 upon excitation by pulsed laser radiation. We used Nd:YAG laser, λ = 1064 nm, τ = 5 ns, and Epulse = 0.8 J. The spectral range of 3-20 nm was studied. We used capillary and supersonic conical nozzles with dcrit = 145 μm, 2α = 12o, L = 5 mm, and dcrit = 450 μm, 2α = 11o, L = 5 mm to form an atomic cluster beam. The emission spectra for various gas targets were obtained, the obtained spectra were deciphered, and the ions emitting in this spectral range were determined. We observed that with increasing particle concentration in the zone of laser spark, the radiation intensity increases. In this case, the intensity of ion lines with high degrees of ionization increases faster.

Эмиссионные спектры легких инертных газов Ne и Ar в диапазоне 3-20 nm при импульсном лазерном возбуждении с использованием различных газовых струй в качестве мишеней

The article considers the results of studies of the emission spectra of Ne and Ar upon excitation by pulsed laser radiation. We used Nd: YAG laser, λ = 1064 nm, τ = 5 ns, and Epulse = 0.8 J. The spectral range of 3-20 nm was studied. We used capillary and supersonic conical nozzles with dcr = 145 μm, 2α = 12o, L = 5 mm, and dcr = 450 μm, 2α = 11o, L = 5 mm to form an atomic cluster beam. The emission spectra for various gas targets were obtained, the obtained spectra were deciphered, and the ions emitting in this spectral range were determined. We observed that with increasing particle concentration in the zone of laser spark, the radiation intensity increases. In this case, the intensity of ion lines with high degrees of ionization increases faster.

Эмиссионные спектры молекулярных газов N-=SUB=-2-=/SUB=- и CO-=SUB=-2-=/SUB=- в диапазоне 3-20 nm при импульсном лазерном возбуждении с использованием различных газовых струй в качестве мишеней

The article considers the results of studies of the emission spectra of N2 and CO2 upon excitation by pulsed laser radiation. We used Nd: YAG laser, λ = 1064 nm, τ = 5 ns, and Epulse = 0.8 J. The spectral range of 3-20 nm was studied. We used capillary and supersonic conical nozzles with dcr = 145 μm, 2α = 12o, L = 5 mm, and dcr = 450 μm, 2α = 11o, L = 5 mm to form an atomic cluster beam. The emission spectra for various gas targets were obtained, the obtained spectra were deciphered, and the ions emitting in this spectral range were determined. We observed that with increasing particle concentration in the zone of laser spark, the radiation intensity increases. In this case, the intensity of ion lines with high degrees of ionization increases faster.

Gas-Phase Synthesis of Functional Nanomaterials

Nanoparticles (NPs) of different types, especially those of metals and metal oxides, are widely used in research and industry for a variety of applications utilising their unique physical and chemical properties. In this article, the focus is put on the fabrication of nanomaterials by means of gas-phase aggregation, also known as the cluster beam technique. A short overview of the history of cluster sources development emphasising the main milestones is presented followed by the description of different regimes of cluster-surface interaction, namely, soft-landing, pinning, sputtering and implantation. The key phenomena and effects for every regime are discussed. The review is continued by the sections describing applications of nanomaterials produced by gas aggregation. These parts critically analyse the pros and cons of the cluster beam approach for catalysis, formation of ferromagnetic and superparamagnetic NPs, applications in sensor and detection technologies as well as the synthesis of coatings and composite films containing NPs in research and industrial applications covering a number of different areas, such as electronics, tribology, biology and medicine. At the end, the current state of the knowledge on the synthesis of nanomaterials using gas aggregation is summarised and the strategies towards industrial applications are outlined.

Formation of nanoripples on ZnO flat substrates and nanorods by gas cluster ion bombardment

In the present study Ar+ cluster ions accelerated by voltages in the range of 5–10 kV are used to irradiate single crystal ZnO substrates and nanorods to fabricate self-assembled surface nanoripple arrays. The ripple formation is observed when the incidence angle of the cluster beam is in the range of 30–70°. The influence of incidence angle, accelerating voltage, and fluence on the ripple formation is studied. Wavelength and height of the nanoripples increase with increasing accelerating voltage and fluence for both targets. The nanoripples formed on the flat substrates remind of aeolian sand ripples. The ripples formed at high ion fluences on the nanorod facets resemble well-ordered parallel steps or ribs. The more ordered ripple formation on nanorods can be associated with the confinement of the nanorod facets in comparison with the quasi-infinite surface of the flat substrates.

Antimicrobial Nanostructured Coatings: A Gas Phase Deposition and Magnetron Sputtering Perspective

Counteracting the spreading of multi-drug-resistant pathogens, taking place through surface-mediated cross-contamination, is amongst the higher priorities in public health policies. For these reason an appropriate design of antimicrobial nanostructured coatings may allow to exploit different antimicrobial mechanisms pathways, to be specifically activated by tailoring the coatings composition and morphology. Furthermore, their mechanical properties are of the utmost importance in view of the antimicrobial surface durability. Indeed, the coating properties might be tuned differently according to the specific synthesis method. The present review focuses on nanoparticle based bactericidal coatings obtained via magneton-spattering and supersonic cluster beam deposition. The bacteria–NP interaction mechanisms are first reviewed, thus making clear the requirements that a nanoparticle-based film should meet in order to serve as a bactericidal coating. Paradigmatic examples of coatings, obtained by magnetron sputtering and supersonic cluster beam deposition, are discussed. The emphasis is on widening the bactericidal spectrum so as to be effective both against gram-positive and gram-negative bacteria, while ensuring a good adhesion to a variety of substrates and mechanical durability. It is discussed how this goal may be achieved combining different elements into the coating.