Nuclear Waste Repositories in Crystalline Rock- an Overview of Flow and Nuclide Transport Mechanisms

1994 ◽  
Vol 353 ◽  
Author(s):  
Ivars Neretnieks

AbstractNuclides eventually escaping from nuclear waste repositories in crystalline rock will move with the seeping water in the fracture network. Most important nuclides interact physically or chemically with the rock and are expected to be considerably retarded allowing them to decay to insignificant concentrations. Velocity variations may allow some portions of the nuclides to move faster. Matrix diffusion and sorption on the surfaces of the rock are by far the most powerful retardation mechanisms and depend, in addition to the sorption and diffusion properties, directly on the magnitude of the “flow wetted surface”which is the contact surface between the mobile water carrying the nuclides and the fracture surfaces over which the nuclides diffuse into the matrix.A number of field experiments have been performed over the last 15 years to help validate the concepts and models and to obtain data. A number of such experiments are described and discussed in relation to the above issues.

2012 ◽  
Vol 57 (4) ◽  
pp. 951-974 ◽  
Author(s):  
Andrzej Nowakowski ◽  
Mariusz Młynarczuk

Abstract Temperature is one of the basic factors influencing physical and structural properties of rocks. A quantitative and qualitative description of this influence becomes essential in underground construction and, in particular, in the construction of various underground storage facilities, including nuclear waste repositories. The present paper discusses the effects of temperature changes on selected mechanical and structural parameters of the Strzelin granites. Its authors focused on analyzing the changes of granite properties that accompany rapid temperature changes, for temperatures lower than 573ºC, which is the value at which the β - α phase transition in quartz occurs. Some of the criteria for selecting the temperature range were the results of measurements carried out at nuclear waste repositories. It was demonstrated that, as a result of the adopted procedure of heating and cooling of samples, the examined rock starts to reveal measurable structural changes, which, in turn, induces vital changes of its selected mechanical properties. In particular, it was shown that one of the quantities describing the structure of the rock - namely, the fracture network - grew significantly. As a consequence, vital changes could be observed in the following physical quantities characterizing the rock: primary wave velocity (vp), permeability coefficient (k), total porosity (n) and fracture porosity (η), limit of compressive strength (Rσ1) and the accompanying deformation (Rε1), Young’s modulus (E), and Poisson’s ratio (ν).


2001 ◽  
Vol 89 (11-12) ◽  
Author(s):  
A. Bilewicz ◽  
J. Narbutt

Dynamic adsorption of radiostrontium was studied on α-crystalline polyantimonic acid grains from aqueous solutions containing common components of liquid radioactive wastes - salts and chelating agents at moderate concentrations. Effective decontamination of the neutral solutions has been achieved, in the amounts of a few thousand bed volumes, depending on the flow rate through the column. After encapsulation in the matrix of Portland cement, the loaded adsorbent can serve as an effective primary barrier in nuclear waste repositories.


Geofluids ◽  
2017 ◽  
Vol 2017 ◽  
pp. 1-13 ◽  
Author(s):  
Yuexiu Wu ◽  
Quansheng Liu ◽  
Andrew H. C. Chan ◽  
Hongyuan Liu

It is essential to study nuclide transport with underground water in fractured rock masses in order to evaluate potential radionuclide leakage in nuclear waste disposal. A time-domain random-walk (TDRW) method was firstly implemented into a discrete element method (DEM), that is, UDEC, in this paper to address the pressing challenges of modelling the nuclide transport in fractured rock masses such as massive fractures and coupled hydromechanical effect. The implementation was then validated against analytical solutions for nuclide transport in a single fracture and a simple fracture network. After that, the proposed implementation was applied to model the nuclide transport in a complex fracture network investigated in the DECOVALEX 2011 project to analyze the effect of matrix diffusion and stress on the nuclide transport in the fractured rock masses. It was concluded that the implementation of the TDRW method into UDEC provided a valuable tool to study the nuclide transport in the fractured rock masses. Moreover, it was found that the total travel time of the nuclide particles in the fractured rock masses with the matrix diffusion and external stress modelled was much longer than that without the matrix diffusion and external stress modelled.


2021 ◽  
Vol 1 ◽  
pp. 173-174
Author(s):  
Carlos Guevara Morel​​​​​​​ ◽  
Jobst Maßmann ◽  
Jan Thiedau

Abstract. The disposal of heat-generating nuclear waste in deep geological formations is an internationally accepted concept. Several repository systems are under discussion in Germany, whereby claystone, salt or crystalline rock could act as the host rock. In this contribution we focus on repository systems where the Containment Providing Rock Zone (CRZ) ensures safe enclosure of the waste and thus the geologic barrier is essential. Even though the various rock types considered differ substantially in their mechanical, hydraulic, thermal and chemical behavior, they must all meet the same safety requirements as defined by the German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU) in 2020. As part of these safety requirements, it must be shown that the integrity of the CRZ is guaranteed for the verification period, i.e. the retention of the properties essential for the containment capacities must be demonstrated over 1 million years. Therefore, the formation of new pathways must be avoided and temperature development must not significantly impair the barrier effect. The anticipated stresses and fluid pressures should not exceed the dilatancy strength and the fluid pressure capacity, respectively. In order to assess the compliance of these requirements, numerical modelling is an essential and powerful tool. Even though great progress has been made regarding the efficiency of computational methods, multiphysical modelling on different length scales over long time periods is still a challenging task. Moreover, since readily available solutions do not exist, adapted methods have to be developed and evaluated, in order to verify concepts and numerical implementations. The BGR gained experience in the field of thermal, hydraulic, mechanical (THM) numerical analysis of the integrity of the CRZ in salt rock and clay stone joined research projects on German disposal options. For crystalline rocks, first concepts are currently being developed within the CHRISTA II project. Compared to clay stone and salt rock, special features have to be taken into account: First of all, crystalline rock is characterized by fractures and other discontinuities. Thus, it cannot be assumed that an undisturbed area of sufficient size can be found for the entire nuclear waste. Consequently, several smaller CRZs must be defined, each providing undisturbed rock. Numerical analysis must deal with smaller CRZs and mechanical and hydraulic boundary conditions that are influenced by fractures. In addition, the processes in the individual CRZs may influence each other (e.g. Temperature distribution). Preliminary modelling approaches and results of numerical THM analyses, considering an upscaled fracture network, are presented.


Chaotic systems behavior attracts many researchers in the field of image encryption. The major advantage of using chaos as the basis for developing a crypto-system is due to its sensitivity to initial conditions and parameter tunning as well as the random-like behavior which resembles the main ingredients of a good cipher namely the confusion and diffusion properties. In this article, we present a new scheme based on the synchronization of dual chaotic systems namely Lorenz and Chen chaotic systems and prove that those chaotic maps can be completely synchronized with other under suitable conditions and specific parameters that make a new addition to the chaotic based encryption systems. This addition provides a master-slave configuration that is utilized to construct the proposed dual synchronized chaos-based cipher scheme. The common security analyses are performed to validate the effectiveness of the proposed scheme. Based on all experiments and analyses, we can conclude that this scheme is secure, efficient, robust, reliable, and can be directly applied successfully for many practical security applications in insecure network channels such as the Internet


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