Compositional Dependence of Thermal Stability and Soft Magnetic Properties for Fe-Al-Ga-P-C-B Glassy Alloys

1998 ◽  
Vol 554 ◽  
Author(s):  
T. Mizushima ◽  
A. Makino ◽  
S. Yoshida ◽  
A. Inoue
Keyword(s):  
Magnetic Properties ◽  
Composition Range ◽  
Glassy Alloy ◽  
Alloy System ◽  
Supercooled Liquid Region ◽  
Glass Forming Ability ◽  
Liquid Region ◽  
Soft Magnetic Properties ◽  
Soft Magnetic ◽  
Glass Forming

AbstractStructure, glass forming ability and soft magnetic properties for Fe-Al-Ga-P-C-B glassy alloy system were investigated in the compositional range of Fe from 69 to 78 at%, (Al+Ga) from 2 to 12 and (P+C+B) from 17 to 28. The saturation magnetization (σ5) rises gradually with increase of Fe concentration. The maximum value of 70K for supercooled liquid region (ΔTx=Tx-Tg, Tx: crystallization temperature, Tg: glass transition temperature:) and the maximum thickness of 180 μm for glass formation (tmax,) are found in the composition range around Fe=70at% and (Al+Ga)=7at%. The highest permeability (μc) of 20,000 at 1kHz and the lowest coercive force (Hc) of 2 A/m at the sample thickness of 30 μm can be also obtained at this composition. It was ascertained that the composition regions to yield the maximum glass forming ability and lowest magnetostriction were in agreement with that in which the most excellent soft magnetic properties were yielded. This results allow us to assume that the excellent soft magnetic properties for this glassy alloy system in the limited composition range are presumably due to high structural homogeneity resulting from significantly high glass-forming ability.

Soft Magnetic Properties of Nanocrystalline Fe–Co–B–Si–Nb–Cu Alloys in Ribbon and Bulk Forms

2003 ◽  
Vol 18 (12) ◽  
pp. 2799-2806 ◽  
Author(s):  
Akihisa Inoue ◽  
Baolong Shen
Keyword(s):  
Magnetic Properties ◽  
Melt Spinning ◽  
Glassy Alloy ◽  
Nanocrystalline Alloy ◽  
Supercooled Liquid ◽  
Supercooled Liquid Region ◽  
Exothermic Peak ◽  
Liquid Region ◽  
Soft Magnetic Properties ◽  
Soft Magnetic

Ribbon and bulk nanocrystalline body-centered-cubic (bcc) (Fe,Co) alloys exhibiting good soft magnetic properties were synthesized in Fe71.5-xCoxB13.5Si10Nb4Cu1 system by the simple production processes of melt-spinning or casting and annealing. The glass-type alloys were formed in the Co content range below 30 at.%. These glassy alloys crystallized through two exothermic reactions. The first stage was due to the precipitation of nanoscale bcc-(Fe,Co) phase with a grain size of about 10 nm, and the second stage resulted from the decomposition of the remaining amorphous phase to α–(Fe,Co), (Fe,Co)2B, (Fe,Co)23B6, (Fe,Co)3Si, and (Fe,Co)2Nb phases. The glass transition temperature increased from 820 to 827 K with increasing Co content from 5 to 20 at.%, while the supercooled liquid region decreased slightly from 37 to 30 K because of the nearly constant crystallization temperature. By choosing the 10 at.% Co-containing alloy, we produced cylindrical glassy alloy rods 1.0 and 1.5 mm in diameter by copper mold casting. The subsequent annealing for 300 s at 883 K corresponding to the temperature just above the first exothermic peak caused the formation of nanoscale bcc-(Fe,Co) structure. The bcc-(Fe,Co) alloy rods exhibited good soft magnetic properties of 1.26 T for saturation magnetization and 5.0 A/m for coercive force, which were comparable to those for the corresponding bcc-(Fe,Co) alloy ribbon. The nanocrystalline alloy in a bulk form is encouraging for future use as a new type of soft magnetic material that requires three-dimensional shapes.

Effect of Nb Addition on the Glass-Forming Ability, Soft-Magnetic Properties and Mechanical Properties of CoFeNiBSiNb Bulk Glassy Alloys

2013 ◽  
Vol 745-746 ◽  
pp. 815-822
Author(s):  
Ya Qiang Dong ◽  
Qi Kui Man ◽  
Bao Long Shen
Keyword(s):  
Mechanical Properties ◽  
Magnetic Properties ◽  
Supercooled Liquid ◽  
Glass Forming Ability ◽  
Liquid Region ◽  
Soft Magnetic Properties ◽  
Soft Magnetic ◽  
Glass Forming ◽  
Glassy Alloys ◽  
Nb Addition

The effect of Nb addition on the glass-forming ability (GFA), soft-magnetic properties and mechanical properties of [(Co0.65Fe0.35)0.9Ni0.1]73-xB21.9Si5.1Nbx(x=36) alloy system were investigated. The results showed that by adjusting the content of Nb, the thermal stability of the supercooled liquid and the GFA increased effectively. With increasing the amount of Nb, the supercooled liquid region (ΔTx) increased from 45 to 65 K and the reduced glass transition temperature (Trg=Tg/Tl) was located in the range of 0.5840.644. As a result, the [(Co0.65Fe0.35)0.9Ni0.1]73-xB21.9Si5.1Nbx bulk glassy alloys (BGAs) with diameters up to 5.0 mm were produced by copper mold casting. In addition to the high GFA, the Co-based glassy alloys exhibited excellent soft-magnetic properties, i.e., saturation magnetization of 0.530.81 T, low coercive force of 0.511.75 A/m, and high effective permeability of (1.522.53)×104 at 1 kHz under a field of 1 A/m. Besides, the Co-based BGAs also exhibited super high fracture strength of 42704490 MPa and vickers hardness of 11271182.

Structure and Soft Magnetic Properties of Bulk Fe-Al-Ga-P-C-B-Si Glassy Alloys Prepared by Consolidating Glassy Powders

2000 ◽  
Vol 644 ◽  
Author(s):  
Akihisa Inoue ◽  
Shoji Yoshida ◽  
Takao Mizushima ◽  
Akihiro Makino
Keyword(s):  
Magnetic Properties ◽  
Glassy Alloy ◽  
Supercooled Liquid ◽  
Supercooled Liquid Region ◽  
Liquid Region ◽  
Soft Magnetic Properties ◽  
Powder Metallurgy Technique ◽  
Soft Magnetic ◽  
High Relative Density ◽  
Bulk Glassy Alloy

AbstractWith the aim of developing a bulk glassy Fe-based alloy with good soft magnetic properties by the powder metallurgy technique, we have applied the pulse current sintering technique to a Fe70Al5Ga2P9.65C5.75B4.6Si3 glassy alloy powder with a large supercooled liquid region of 60K before crystallization. The existence of the supercooled liquid region was found to enable us to form a bulk glassy alloy with a very high relative density of 99%. The resulting bulk glassy alloy exhibits good soft magnetic properties, i.e., 1.17T for flux density at a field of 800A/m, 12.0A/m for coercive force and 8000 for maximum permeability which are much superior to those for the bulk amorphous Fe-Si-B alloy prepared by the same sintering method. The much better soft magnetic properties for the multicomponent Fe-based bulk alloy are attributed to the combination of the high relative density and the unique amorphous structure with the features of high packing density and long-range homogeneous atomic configurations. The first success of forming the bulk amorphous alloy with good soft magnetic properties by the powder metallurgy technique is expected to enable us to use as practical soft magnetic materials.

Effects of Minor Additions on Ni- and Be-Free Ti-Based Bulk Glassy Alloys

2015 ◽  
Vol 833 ◽  
pp. 79-84 ◽  
Author(s):  
Sheng Li Zhu ◽  
Guo Qiang Xie ◽  
Akihisa Inoue ◽  
Zhen Duo Cui ◽  
Xian Jin Yang ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Glassy Alloy ◽  
Alloy System ◽  
Supercooled Liquid ◽  
Supercooled Liquid Region ◽  
Glass Forming Ability ◽  
Liquid Region ◽  
Glass Forming ◽  
Glassy Alloys ◽  
Si Addition

We investigated the effects of addition elements (Sn, Al, Si, Ag, Fe, Cr) with a small amount on the glass-forming ability, thermal stability and mechanical properties of the Ti-Zr-Cu-Pd glassy alloy system. The results revealed that minor Sn addition improved the glass-forming ability, thermal stability and plasticity, Si addition enlarged the supercooled liquid region, and Fe addition improved the plasticity, while minor additions of Si, Ag, Fe, and Cr lowered the glass-forming ability, and Al and Cr additions were harmful to the plasticity of the Ti-Zr-Cu-Pd glassy alloy system.

The Effect of Co Addition on Glassy Forming Ability and Soft Magnetic Properties of Fe-Si-B-P Bulk Metallic Glass

2012 ◽  
Vol 508 ◽  
pp. 112-116 ◽  
Author(s):  
Xue Li ◽  
Yan Zhang ◽  
Hidemi Kato ◽  
Akihiro Makino ◽  
Akihisa Inoue
Keyword(s):  
Magnetic Properties ◽  
Metallic Glass ◽  
Bulk Metallic Glass ◽  
Glassy Alloy ◽  
High Strength ◽  
Alloy System ◽  
Soft Magnetic Properties ◽  
Soft Magnetic ◽  
Co Addition ◽  
Ferromagnetic Bulk

We Successfully Prepared the Rod Glassy Samples of (Fe1-xCox)76Si9B10P5 (x = 0~0.4) Bulk Metallic Glass (BMG) with the Diameters up to 3.0 mm by Substituting Fe for a Small Amount of Co Element. A Certain Amount of Co Substitution for Fe Contributes to the Increase of the Glass-Forming Ability (GFA) while Maintaining Good Mechanical Properties (the Fracture Strength up to 3700 MPa). This Co-Added Ferromagnetic Bulk Glassy Alloy System Also Exhibits a Higher Saturation Magnetization of 1.49 T and Lower Coercive Force (Hc, 1.2 A/m). The Fe-Based BMGs with Alloying a Small Amount of Co Element Demonstrate Excellent Combination of High GFA, Good Soft-Magnetic Properties as Well as High Strength.

scholarly journals Bulk Glassy Co43Fe20Ta5.5B31.5 Alloy with High Glass-Forming Ability and Good Soft Magnetic Properties

2001 ◽  
Vol 42 (10) ◽  
pp. 2136-2139 ◽  
Author(s):  
Baolong Shen ◽  
Hisato Koshiba ◽  
Akihisa Inoue ◽  
Hisamichi Kimura ◽  
Takao Mizushima
Keyword(s):  
Magnetic Properties ◽  
Glass Forming Ability ◽  
Soft Magnetic Properties ◽  
Soft Magnetic ◽  
Glass Forming

Fabrication of large-size Fe-based glassy cores with good soft magnetic properties by spark plasma sintering

2003 ◽  
Vol 18 (9) ◽  
pp. 2115-2121 ◽  
Author(s):  
Baolong Shen ◽  
Akihisa Inoue
Keyword(s):  
Magnetic Properties ◽  
Supercooled Liquid ◽  
Supercooled Liquid Region ◽  
Liquid Region ◽  
Soft Magnetic Properties ◽  
Soft Magnetic ◽  
Large Size ◽  
High Relative Density ◽  
Plasma Sintering ◽  
Spark Plasma

Glassy Fe65Co10Ga5P12C4B4 alloy powders with a large supercooled liquid region of 50 K before crystallization were synthesized in the particle size range below 125 μm by Ar gas atomization. With the aim of developing a large-size Fe-based glassy core with good soft magnetic properties, the consolidation method of spark plasma sintering was applied to the Fe65Co10Ga5P12C4B4 glassy powders. The existence of the supercooled liquid region enabled us to form a large-size glassy alloy disc 20 mm in diameter and 5 mm in thickness with a high relative density of 99.7% at the glass-transition temperature of 723 K and under the external applied pressure of 300 MPa. The resulting glassy core of 18 mm in outer diameter, 10 mm in inner diameter, and 4 mm in thickness exhibits good soft magnetic properties: 1.20 T for saturation magnetization, 6 A/m for coercive force, and 8900 for maximum permeability. The good soft magnetic properties of the Fe-based bulk glassy core are attributed to the combination of the high relative density and the maintenance of the single glassy structure.

Enhancement of glass-forming ability of CoFeBSiNb bulk glassy alloys with excellent soft-magnetic properties and superhigh strength

2010 ◽  
Vol 18 (10) ◽  
pp. 1876-1879 ◽  
Author(s):  
Qikui Man ◽  
Huaijun Sun ◽  
Yaqiang Dong ◽  
Baolong Shen ◽  
Hisamichi Kimura ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Glass Forming Ability ◽  
Soft Magnetic Properties ◽  
Soft Magnetic ◽  
Glass Forming ◽  
Glassy Alloys
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