In Situ X-ray Absorption Spectroscopy in the Soft Energy Range: Novel Prospects for the Chemical Characterization of Solid State Surfaces at High Pressure And High Temperature
AbstractAn instrument equipped with total electron yield detectors was designed and constructed for in situ X-ray absorption spectroscopy (XAS) investigations in the soft X-ray range (100 eV ≤ hν ≤ 1000 eV) at elevated pressures (mbar range) and sample temperatures (T ≤ 1000 K) [1]. This allows, for the first time, XAS studies in a surface-sensitive mode of the light elements (Z = 3-15). Furthermore, the gas phase XAS and the surface-related XAS of the solid state phase can be collected simultaneously in order to correlate the gas/solid reaction rate with the surface electronic structure under working conditions in a flow-through mode.The novel experimental tool represents a contribution to the experimental overcoming of the “pressure gap” in material science. In this work examples are presented belonging to the field of heterogeneous catalysis [2-4] and to the reactivity of diamond surfaces [5]. Additionally, prospects for in situ studies in material science will be given.
In Situ Solid-State Reactions Monitored by X-ray Absorption Spectroscopy: Temperature-Induced Proton Transfer Leads to Chemical Shifts