Synthesis and characterization of nanocomposites with nanocellulose obtained through frontal polymerization and study of their properties

MRS Advances ◽  
2021 ◽  
Author(s):  
Dulce Cristel Arellano-Cruz ◽  
Javier Illescas ◽  
Sonia Martínez-Gallegos ◽  
María del Carmen Díaz-Nava
Keyword(s):  
Frontal Polymerization ◽  
Synthesis And Characterization

Synthesis and characterization of poly(ethylene glycol) diacrylate copolymers containing azobenzene groups prepared by frontal polymerization

2011 ◽  
Vol 49 (15) ◽  
pp. 3291-3298 ◽  
Author(s):  
Javier Illescas ◽  
Yessica S. Ramirez-Fuentes ◽  
Ernesto Rivera ◽  
Omar G. Morales-Saavedra ◽  
Antonio A. Rodríguez-Rosales ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Frontal Polymerization ◽  
Synthesis And Characterization ◽  
Poly Ethylene Glycol ◽  
Glycol Diacrylate ◽  
Poly Ethylene ◽  
Azobenzene Groups

Synthesis and characterization of a polyurethane prepared by frontal polymerization

e-Polymers ◽  
2003 ◽  
Vol 3 (1) ◽  
Author(s):  
Alberto Mariani ◽  
Simone Bidali ◽  
Stefano Fiori ◽  
Giulio Malucelli ◽  
Ester Sanna
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Reaction Times ◽  
Practical Interest ◽  
Frontal Polymerization ◽  
Synthesis And Characterization ◽  
Synthetic Route ◽  
Molecular Weights ◽  
Lower Melting Point

Abstract Frontal polymerization (FP) has been successfully applied to the preparation of a polyurethane (PU) having practical interest. By comparing the classical PU synthetic route with FP, the latter allowed for the obtainment of both higher molecular weights and yields. Furthermore, reaction times have been significantly reduced. Eventually, FP materials are characterized by higher glass transition temperature and lower melting point than their batch counterparts.

Synthesis and characterization of a polyester/styrene resin obtained by frontal polymerization

e-Polymers ◽  
2002 ◽  
Vol 2 (1) ◽  
Author(s):  
Stefano Fiori ◽  
Giulio Malucelli ◽  
Alberto Mariani ◽  
Laura Ricco ◽  
Elena Casazza
Keyword(s):  
Free Radical ◽  
Mechanical Behaviour ◽  
Unsaturated Polyester ◽  
Front Velocity ◽  
Frontal Polymerization ◽  
Maximum Temperature ◽  
Synthesis And Characterization ◽  
Free Radical Initiator ◽  
First Time

AbstractThe frontal polymerization technique has been successfully applied, for the first time, to obtain an unsaturated polyester/styrene resin. The effect of the ratio of the two aforementioned components, as well as of the type and amount of free-radical initiator on both front velocity and maximum temperature reached by the front, has been thoroughly studied. The resulting products have been characterized in terms of their thermal and dynamic-mechanical behaviour. A comparison of such products with the corresponding materials obtained by the classical batch polymerization technique has evidenced that frontal polymerization allows to reach a higher degree of crosslinking with respect to batch copolymerization and hence a better thermal and mechanical behaviour.

Synthesis and characterization of epoxy resin-montmorillonite nanocomposites obtained by frontal polymerization

2007 ◽  
Vol 45 (11) ◽  
pp. 2204-2211 ◽  
Author(s):  
Alberto Mariani ◽  
Simone Bidali ◽  
Giuseppe Caria ◽  
Orietta Monticelli ◽  
Saverio Russo ◽  
...  
Keyword(s):  
Epoxy Resin ◽  
Frontal Polymerization ◽  
Synthesis And Characterization ◽  
Montmorillonite Nanocomposites

Synthesis and Characterization of pH‐sensitive Poly(IA‐ co ‐AAc‐ co ‐AAm) Hydrogels via Frontal Polymerization

2019 ◽  
Vol 57 (22) ◽  
pp. 2214-2221 ◽  
Author(s):  
Muhammad Irfan ◽  
Xiang‐Yun Du ◽  
Xu Ran Xu ◽  
Rui Qi Shen ◽  
Su Chen ◽  
...  
Keyword(s):  
Ph Sensitive ◽  
Frontal Polymerization ◽  
Synthesis And Characterization

Synthesis and characterization of poly(2-hydroxyethylacrylate)/β-cyclodextrin hydrogels obtained by frontal polymerization

2016 ◽  
Vol 150 ◽  
pp. 166-171 ◽  
Author(s):  
Daniele Nuvoli ◽  
Valeria Alzari ◽  
Luca Nuvoli ◽  
Mariella Rassu ◽  
Davide Sanna ◽  
...  
Keyword(s):  
Frontal Polymerization ◽  
Synthesis And Characterization

Synthesis and Characterization of Functionally Gradient Materials Obtained by Frontal Polymerization

2015 ◽  
Vol 7 (6) ◽  
pp. 3600-3606 ◽  
Author(s):  
Daniele Nuvoli ◽  
Valeria Alzari ◽  
John A. Pojman ◽  
Vanna Sanna ◽  
Andrea Ruiu ◽  
...  
Keyword(s):  
Frontal Polymerization ◽  
Synthesis And Characterization ◽  
Functionally Gradient Materials ◽  
Gradient Materials ◽  
Functionally Gradient

Synthesis and characterization of unsaturated polyester resins cured by frontal polymerization

e-Polymers ◽  
2004 ◽  
Vol 4 (1) ◽  
Author(s):  
Stefano Fiori ◽  
Alberto Mariani ◽  
Simone Bidali ◽  
Giulio Malucelli
Keyword(s):  
Thermal Properties ◽  
Maleic Anhydride ◽  
Unsaturated Polyester ◽  
Front Velocity ◽  
Frontal Polymerization ◽  
Maximum Temperature ◽  
Synthesis And Characterization ◽  
Polyester Resins ◽  
Crosslinking Agents

Abstract Various crosslinking agents have been used to frontally cure the unsaturated polyester derived by the reaction of maleic anhydride and 1,2-propanediol. The effect of composition of the curing mixture on the front velocity and its maximum temperature, as well as on the thermal properties of the obtained materials, is described.

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