Initiation of localized steel corrosion in alkaline sulfate solution

2021 ◽  
Vol 54 (4) ◽  
Author(s):  
Samanbar Permeh ◽  
Kingsley Lau ◽  
Matthew Duncan ◽  
Ron Simmons
Keyword(s):  
Steel Corrosion ◽  
Sulfate Solution

Effect of Sulfate Ions on the Corrosion Behavior of Steel in Concrete Using Electrochemical Methods

2010 ◽  
Vol 163-167 ◽  
pp. 3049-3054 ◽  
Author(s):  
Jin Jie Shi ◽  
Wei Sun
Keyword(s):  
Corrosion Rate ◽  
Corrosion Behavior ◽  
Chloride Solution ◽  
High Performance ◽  
High Performance Concrete ◽  
Electrochemical Impedance ◽  
Steel Corrosion ◽  
Sulfate Solution ◽  
Cyclic Polarization ◽  
Sulfate Ions

The effect of sulfate ions on the corrosion behavior of steel in ordinary Portland concrete (OPC) and high performance concrete (HPC) were investigated. Steel corrosion was evaluated by means of corrosion potential (Ecorr), linear polarization resistance (LPR), electrochemical impedance spectroscopy (EIS) and cyclic polarization (CP). The electrochemical results indicated that, compared to the pure chloride solution, the presence of sulfate ions in the chloride solution both reduced the time to corrosion initiation and lead to an increase in corrosion rate of steel in OPC specimens; however, the sulfate ions had negligible effect in HPC specimens. Furthermore, the corrosion rate of steel exposed to chloride solution was higher that to the sulfate solution both in OPC and HPC specimens.

Research on the Corrosive Factors of Q235 Steel in Simulate Ammonium Sulfate Solution of Ammonia Desulphurization

2014 ◽  
Vol 941-944 ◽  
pp. 165-168
Author(s):  
Lian He ◽  
Dong Sheng Chen ◽  
Fei Fei Lou ◽  
Qin Qin Ye ◽  
Wu Ji Wei ◽  
...  
Keyword(s):  
Corrosion Rate ◽  
Flow Velocity ◽  
Ammonium Sulfate ◽  
Steel Corrosion ◽  
Sulfate Solution ◽  
Ammonium Sulfate Solution ◽  
Q235 Steel ◽  
Electrode Processes ◽  
Maximum Value ◽  
Weight Loss Method

Corrosion behaviors of Q235 steel in simulate ammonium sulfate solution were studied. Effects of the ammonium sulfate concentration, Cl- concentration, pH and the flow velocity on corrosion of Q235 steel in simulate ammonium sulfate solution were investigated by the weight-loss method, and the electrode processes were studied by polarization curves. The result showed that: (1) the corrosion rate of Q235 steel increased with the increase of Cl- concentration firstly. When Cl- concentration was 10000ppm, the corrosion rate reached the maximum value of 6.698 mm/a, and then, with the increase of Cl- concentration, the corrosion rate decreased. (2)With pH increasing, the corrosion rate of Q235 steel decreased. (3)The corrosion rate increased with the increase of the concentration of ammonium sulfate firstly. When the concentration of ammonium sulfate was 5%, the corrosion rate reached the maximum value of 5.462 mm/a. And then the corrosion rate decreased. (4)The influence of the flow velocity on Q235 steel corrosion was remarkable, with the increase of the flow velocity, the corrosion rate increased rapidly.

Protective postaction of inhibitor IFKhAN-92 for chromium-nickel stainless steel corrosion in hydrochloric acid

2019 ◽  
pp. 20-25
Author(s):  
Ya.G. Avdeev ◽  
◽  
Yu.B. Makarychev ◽  
D.S. Kuznetsov ◽  
L.P. Kazanskii ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Hydrochloric Acid ◽  
Steel Corrosion

Inhibition of pipeline steel corrosion in acidic environment using sulphadoxine and pyrimethamine

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Inhibition Efficiency ◽  
Pipeline Steel ◽  
Electrochemical Techniques ◽  
Steel Corrosion ◽  
Acidic Environment ◽  
Inhibitor Concentration ◽  
Adsorption Data ◽  
Corrosion Inhibition Efficiency ◽  
Inhibitive Action ◽  
Sulphadoxine Pyrimethamine

The anti-corrosive properties of sulphadoxine + pyrimethamine (S+P) on the corrosion of pipeline steel in acidic environment were investigated using electrochemical techniques. The results obtained showed an excellent inhibition efficiency which increased with increase in inhibitor concentration. The corrosion inhibition efficiency increased up to 99.04 % at 0.01M S+P and decreased with rise in temperature down to 85.93 % at 333 K and 0.01 M S+P, suggesting a physiosorptive mechanism of adsorption. Also the adsorption data was fitted into Langmuir and Temkin adsorption isotherms, while the inhibitive action was shown to proceed by mixed inhibition mode.

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