Research on the Corrosive Factors of Q235 Steel in Simulate Ammonium Sulfate Solution of Ammonia Desulphurization

2014 ◽  
Vol 941-944 ◽  
pp. 165-168
Author(s):  
Lian He ◽  
Dong Sheng Chen ◽  
Fei Fei Lou ◽  
Qin Qin Ye ◽  
Wu Ji Wei ◽  
...  

Corrosion behaviors of Q235 steel in simulate ammonium sulfate solution were studied. Effects of the ammonium sulfate concentration, Cl- concentration, pH and the flow velocity on corrosion of Q235 steel in simulate ammonium sulfate solution were investigated by the weight-loss method, and the electrode processes were studied by polarization curves. The result showed that: (1) the corrosion rate of Q235 steel increased with the increase of Cl- concentration firstly. When Cl- concentration was 10000ppm, the corrosion rate reached the maximum value of 6.698 mm/a, and then, with the increase of Cl- concentration, the corrosion rate decreased. (2)With pH increasing, the corrosion rate of Q235 steel decreased. (3)The corrosion rate increased with the increase of the concentration of ammonium sulfate firstly. When the concentration of ammonium sulfate was 5%, the corrosion rate reached the maximum value of 5.462 mm/a. And then the corrosion rate decreased. (4)The influence of the flow velocity on Q235 steel corrosion was remarkable, with the increase of the flow velocity, the corrosion rate increased rapidly.

2017 ◽  
Vol 169 ◽  
pp. 534-541 ◽  
Author(s):  
Kun Yang ◽  
Libo Zhang ◽  
Chao Lv ◽  
Jinhui Peng ◽  
Shiwei Li ◽  
...  

2017 ◽  
Vol 64 (4) ◽  
pp. 432-442
Author(s):  
Zhouyang Lian ◽  
Zhengwei Luo ◽  
Lirui Yuan ◽  
Mulin Guo ◽  
Wuji Wei ◽  
...  

Purpose This paper aims to evaluate diethylenetriamine (DETA) as an inhibitor on Q235 (Gr. D) steel in ammonia flue gas desulfurization (AFGD) system. Design/methodology/approach This research was carried out by weight loss, electrochemical measurements, scanning electron microscopy and X-ray photoelectron spectrometry. The effects of DETA on crystallization of ammonium sulfate and its co-crystallization were also investigated by X-ray diffraction and infrared spectroscopy. Findings The inhibition efficiency of DETA reached a maximum value of 98.96 per cent. DETA is postulated to adsorb on Q235 steel surface, resulting in the formation of a protective film by the accumulation of many flat particles, and the thickness of protective film is 8 μm. DETA had no effect on the crystallization of ammonium sulfate product. Originality/value DETA can be used in AFGD system as an inhibitor to protect the equipment well.


2014 ◽  
Vol 34 (3) ◽  
pp. 0330004
Author(s):  
孙松 Sun Song ◽  
蔡廷栋 Cai Tingdong ◽  
刘莹 Liu Ying ◽  
王静静 Wang Jingjing ◽  
叶勇 Ye Yong ◽  
...  

1980 ◽  
Vol 26 (2) ◽  
pp. 277-281
Author(s):  
M Mitnick ◽  
B DeMarco ◽  
J M Gibbons

Abstract We describe a stepwise-development thin-layer-chromatographic technique for separating phosphatidylglycerol and phosphatidylinositol in samples of amniotic fluid. Plates are prepared from silica gel G slurried in a 50 g/L ammonium sulfate solution. Phospholipid phosphorus determination is not needed. Phospholipid phosphorus determination is not needed. Phosphatidylglycerol and phosphatidylinositol, measured densitometrically, are expressed as ratios to the sphingomyelin present. These ratios are correlated with the lecithin/sphingomyelin ratio and age of gestation in normal and abnormal pregnancies.


Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 343 ◽  
Author(s):  
Dong Wang ◽  
Wenqiao Meng ◽  
Yunna Lei ◽  
Chunxu Li ◽  
Jiaji Cheng ◽  
...  

To improve sulfuric acid recovery from sodium sulfate wastewater, a lab-scale bipolar membrane electrodialysis (BMED) process was used for the treatment of simulated sodium sulfate wastewater. In order to increase the concentration of sulfuric acid (H2SO4) generated during the process, a certain concentration of ammonium sulfate solution was added into the feed compartment. To study the influencing factors of sulfuric acid yield, we prepared different concentrations of ammonium sulfate solution, different feed solution volumes, and different membrane configurations in this experiment. As it can be seen from the results, when adding 8% (NH4)2SO4 into 15% Na2SO4 under the experimental conditions where the current density was 50 mA/cm2, the concentration of H2SO4 increased from 0.89 to 1.215 mol/L, and the current efficiency and energy consumption could be up to 60.12% and 2.59 kWh/kg, respectively. Furthermore, with the increase of the volume of the feed compartment, the concentration of H2SO4 also increased. At the same time, the configuration also affects the final concentration of the sulfuric acid; in the BP-A-C-BP (“BP” means bipolar membrane, “A” means anion exchange membrane, and “C” means cation exchange membrane; “BP-A-C-BP” means that two bipolar membranes, an anion exchange membrane, and a cation exchange membrane are alternately arranged to form a repeating unit of the membrane stack) configuration, a higher H2SO4 concentration was generated and less energy was consumed. The results show that the addition of the double conjugate salt is an effective method to increase the concentration of acid produced in the BMED process.


1967 ◽  
Vol 13 (5) ◽  
pp. 423-425
Author(s):  
H Bruce Collier

Abstract The Gilford Absorbance Indicator was recalibrated, for absolute absorbance readings, with (1) a U. S. Bureau of Standards calibrated cobalt-blue glass standard; (2) a standard cobalt ammonium sulfate solution at 512 mµ (3) standard potassium chromate solutions at 373 mµ These three standards agreed with 1%. Readings on the indicator's absorbance scale had decreased by about 7% over 2 years.


2018 ◽  
Vol 69 (11) ◽  
pp. 1597-1608 ◽  
Author(s):  
Kun Li ◽  
Zhuoyuan Chen ◽  
Jiarun Li ◽  
Xiaoying Sun ◽  
Fengling Xu ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document