scholarly journals Corrosion of carbon steel and cast iron in gas phase above salt melts used in magnesium industry

Author(s):  
I. M. Komelin ◽  
A. P. Lysenko ◽  
D. S. Kondrat'eva

Corrosion tests of SCh15 cast iron, Steel 3 and Steel 3 with aluminized coating in some compositions of 10%MgCl2-KCl-NaCl and 10%MgCl2-KCl-Naa-Caa2 salt melts with 10 %, 25 % and 40 % CaCl2 concentrations, and also in 10MgCl2-45%KCl-20%NaCl-25%NaBr melt, and in the gas phase above these melts at 700 °C. A gravimetric method was used to determine corrosion rates of metal samples. Chemical analysis of absorption solutions was used to determine concentrations of halide and hydrogen halide impurities in air blown through the reactor with melts and samples. It was shown that carbon steel aluminizing can reduce the corrosion rate in the gas phase over the salt melt by a factor of 5 to 70. The formation mechanism of gases aggressive in relation to carbon steel and cast iron in atmospheric air in contact with salt chloride melt was considered. Accelerated hydrogen chloride and chlorine formation during the salt melt interaction with atmospheric air under the influence of iron corrosion products was found.

2019 ◽  
Vol 60 (2) ◽  
pp. 125-138
Author(s):  
I. M. Komelin ◽  
A. P. Lysenko ◽  
D. S. Kondrateva
Keyword(s):  

1988 ◽  
Vol 15 (1) ◽  
pp. 79-90 ◽  
Author(s):  
Louise Millette ◽  
Donald S. Mavinic

The Greater Vancouver Regional District distributes drinking water that displays several attributes of an aggressive water: low pH, low alkalinity, and high dissolved oxygen. A study, consisting of two experimental sessions, was conducted at the University of British Columbia to examine the effects of pH adjustment on internal corrosion of residential cast-iron and copper water distribution pipes.Because of its aggressive nature, this water accelerates the corrosion of water pipes, which not only increases maintenance costs, but also encourages high levels of metal in the water. This last finding was confirmed by a preliminary survey wherein, after one month's sampling of six dwellings, it was found that the recommended maximum level of 1.0 mg/L was exceeded in 67% of the morning cold water first-flush samples.Adjustment of pH with hydrated lime, Ca(OH)2, was used for corrosion control. Cast-iron and copper samples were exposed to pH-adjusted water for varying lengths of time, in two flow-through experimental systems (gravity-fed and system-pressure-fed).Although the corrosion rates were different for the two experimental sessions, analysis of the pH-related corrosion rates variation led to the same two findings. The corrosion rates of cast iron were 10 times those of copper; the increased pH enhanced these cast-iron corrosion rates by approximately 15%. However, a pH increase reduced copper corrosion by as much as 68%. The effects of increased pressure on corrosion were different for both metals; a higher pressure greatly enhanced cast-iron corrosion but had little effect on copper corrosion. Key words: aggressive water, cast iron, corrosion, copper, lime, pH adjustment, water pipes.


Alloy Digest ◽  
2003 ◽  
Vol 52 (12) ◽  

Abstract Algoma AR225 is a carbon steel developed primarily to supply a low-cost material for high-abrasion applications. It is furnished in the form of as-rolled plate with a relatively high carbon content (0.35-0.45%). AR-225 is sold on the basis of chemical analysis only; the number 225 signifies the approximate Brinell hardness. On thicknesses one-half inch and over, this Brinell value may be lower than 225 because of higher finishing temperatures. This datasheet provides information on composition, physical properties, hardness, and elasticity. It also includes information on forming, heat treating, machining, and joining. Filing Code: CS-138. Producer or source: Algoma Steel Corporation Ltd.


Microbiome ◽  
2018 ◽  
Vol 6 (1) ◽  
Author(s):  
Guijuan Zhang ◽  
Bing Li ◽  
Jie Liu ◽  
Mingqiang Luan ◽  
Long Yue ◽  
...  

1985 ◽  
Vol 38 (8) ◽  
pp. 1133 ◽  
Author(s):  
BG Pound ◽  
MH Abdurrahman ◽  
MP Glucina ◽  
GA Wright ◽  
RM Sharp

The corrosion rates of low-carbon steel, and 304, 316 and 410/420 stainless steels in simulated geothermal media containing hydrogen sulfide have been measured by means of the polarization resistance technique. Good agreement was found between weight-loss and polarization resistance measurements of the corrosion rate for all the metals tested. Carbon steel formed a non-adherent film of mackinawite (Fe1 + xS). The lack of protection afforded to the steel by the film resulted in an approximately constant corrosion rate. The stainless steels also exhibited corrosion rates that were independent of time. However, the 410 and 420 alloys formed an adherent film consisting mainly of troilite ( FeS ) which provided only limited passivity. In contrast, the 304 and 316 alloys appeared to be essentially protected by a passive film which did not seem to involve an iron sulfide phase. However, all the stainless steels, particularly the 410 and 420 alloys, showed pitting, which indicated that some breakdown of the passive films occurred.


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