scholarly journals Investigation of the Laser Radiation Effects on Lignite with the Products Analysis by Mass Spectrometry

2020 ◽  
Vol 22 (1) ◽  
pp. 3
Author(s):  
Y.V. Kraft ◽  
D.R. Nurmukhametov ◽  
B.P. Aduev ◽  
Z.R. Ismagilov

In this paper, one studied the effect of pulsed laser radiation (1064 nm, 120 μs) on lignite. The method of mass spectrometry was used to analyze the formed gaseous reaction products after the exposing of coal samples to the laser radiation. The pressed out of the pre-milled coal particles tablets were used as samples. In the mass spectra of the reaction products of laser radiation of the samples, the peaks with a mass to ion charge ratio m/z = 2, 18, 44 were detected, that corresponds to the main peaks of H2, H2O, and CO2 molecules. The pattern of formation of the end products CO2, H2, H2O when heating a sample of coal by laser radiation is proposed. The energy release factor is calculated, which is defined as the ratio of the calorific value, released during combustion of the sample to the dose of energy absorbed by the sample during irradiation.




2021 ◽  
Vol 1 ◽  
pp. 134
Author(s):  
Konstantin V. Beglov ◽  
◽  
Alexander I. Brunetkin ◽  
Maxim M. Maximov ◽  
Elena O. Ulitskaya ◽  
...  

The issues of organization of the process of slow pyrolysis of organic substances, in the general case of unknown and variable composition, are considered. The relevance of the work is determined by considering the possibility of using various organic waste (domestic, agricultural, industrial) without their preliminary sorting and drying to obtain secondary energy resources of a known (controlled) composition. The novelty of the work is due to the development of a model for the method of controlled pyrolysis or gasification of organic substances with a minimum amount of solid residues at a maximum calorific value of the resulting mixture of combustible gases. A process based on filtration combustion in superadiabatic mode is considered. In existing devices, when this mode is implemented, a counter flow of the feedstock and reaction products is organized. As a result, a part of the water vapor generated at the drying stage is part of the mixture of reaction products and, accordingly, reduce their energy value. The scheme of the process proposed for consideration is based on the organization of the associated flow of feedstock and reaction products. As a result, the resulting carbon dioxide and water vapor are used as additional oxidizing agents. As a result, the carbonaceous residue decreases with a simultaneous increase in the composition of the mixture of gaseous products of carbon monoxide and hydrogen. A scheme for real-time monitoring of the composition of the feedstock during pyrolysis (gasification) is proposed. Knowledge of the composition makes it possible to control the process of its processing in order to: a) organize the optimal gasification process in terms of maximizing the amount and energy value of the mixture of gaseous reaction products; b) control the consumption of the processed feedstock in order to produce the required amount of product gas at any given time.



2014 ◽  
Vol 59 (12) ◽  
pp. 1149-1154
Author(s):  
A.D. Mamuta ◽  
◽  
V.S. Voitsekhovich ◽  
N.M. Kachalova ◽  
L.F. Golovko ◽  
...  




Cancers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 3197
Author(s):  
Rita Casadonte ◽  
Mark Kriegsmann ◽  
Katharina Kriegsmann ◽  
Isabella Hauk ◽  
Rolf R. Meliß ◽  
...  

The discrimination of malignant melanoma from benign nevi may be difficult in some cases. For this reason, immunohistological and molecular techniques are included in the differential diagnostic toolbox for these lesions. These methods are time consuming when applied subsequently and, in some cases, no definitive diagnosis can be made. We studied both lesions by imaging mass spectrometry (IMS) in a large cohort (n = 203) to determine a different proteomic profile between cutaneous melanomas and melanocytic nevi. Sample preparation and instrument setting were tested to obtain optimal results in term of data quality and reproducibility. A proteomic signature was found by linear discriminant analysis to discern malignant melanoma from benign nevus (n = 113) with an overall accuracy of >98%. The prediction model was tested in an independent set (n = 90) reaching an overall accuracy of 93% in classifying melanoma from nevi. Statistical analysis of the IMS data revealed mass-to-charge ratio (m/z) peaks which varied significantly (Area under the receiver operating characteristic curve > 0.7) between the two tissue types. To our knowledge, this is the largest IMS study of cutaneous melanoma and nevi performed up to now. Our findings clearly show that discrimination of melanocytic nevi from melanoma is possible by IMS.



2003 ◽  
Vol 37 (4) ◽  
pp. 396-398 ◽  
Author(s):  
V. A. Gnatyuk ◽  
O. S. Gorodnychenko


2011 ◽  
Vol 22 (29) ◽  
pp. 295304 ◽  
Author(s):  
A Pérez del Pino ◽  
E György ◽  
I C Marcus ◽  
J Roqueta ◽  
M I Alonso


2007 ◽  
Vol 36 (5) ◽  
pp. 467-470 ◽  
Author(s):  
P. Yu. Kikin ◽  
V. N. Perevezentsev ◽  
A. I. Pchelintsev ◽  
E. E. Rusin


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