scholarly journals Crystallization Features of Porous TiNi Made by SHS

2017 ◽  
Vol 2 (1) ◽  
pp. 80 ◽  
Author(s):  
Yu.F. Yasenchuk Yu. ◽  
N.V. Artyuhova ◽  
K.V. Almaeva ◽  
A.S. Garin ◽  
V.A. Novikov ◽  
...  

The surface layers and fracture surfaces of porous titanium nickelide obtained by self-propagating high temperature synthesis (SHS) in a flow reactor in an argon atmosphere are studied by SEM and energy dispersive analysis. It is alleged that primary pores 5–15 µ in size and the related granular layer are formed due to segregation and capillary force effect during peritectic crystallization of some porous alloy areas. Coarsening and deformation of pores, as well as migration and growth of granular layers, is caused by reaction gases. Carbon and oxygen impurities present in the reaction gases and the protective atmosphere penetrate into the melt film on the pore surface to form strong and corrosion-resistant nanostructured layers of intermetallic carbides, nitrides and oxides.

2017 ◽  
Vol 2 (1) ◽  
pp. 168 ◽  
Author(s):  
Yu. Yasenchuk ◽  
N.V. Artyuhova ◽  
K.V. Almaeva ◽  
A.S. Garin ◽  
V.E Gunther

The research considers the contribution of gases to the surface formation during self-propagating high-temperature synthesis (SHS) of porous titanium nickelide based alloys. The structure of the obtained porous alloys was analyzed using the methods of secondary ion mass spectrometry (SIMS), optical microscopy, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Nanocrystalline intermetallic oxycarbonitrides of a complicated structure were found on the porous titanium nickelide surface. A dense double gradient layer was found under the outer loose deposits. It is concluded that the dense gradient layer of intermetallic oxycarbonitride provides chemical passivity of the investigated porous alloys. Loose surface deposits of intermetallic oxycarbonitrides ensure successful integration of the alloy into the biological tissue in case of implantation. 


1997 ◽  
Vol 40 (1) ◽  
pp. 17-20
Author(s):  
A. A. Klopotov ◽  
N. V. Girsova ◽  
V. É. Gyunter ◽  
V. I. Itin

2010 ◽  
Vol 654-656 ◽  
pp. 1852-1855 ◽  
Author(s):  
Y.A. Minaev

The obtained generalized equation for description of a fundamental property of solid crystalline materials i.e. first-order phase transition of the grain boundaries with formation of two-dimensional liquid has been used for calculating of transition temperature of any metals, which value lies in range 0.55 – 086 of melting point. Based on these conclusions to develop strategies for effective forming of coatings by synthesis of nitrides and carbonitrides on surface layers of hard metals and chromium steels have been made. It was shown the hardening of thin surface layer (0.1-0.5mm) due enriched of a nitrides in steels and carbonitrides with diamond like structure and strengthening the following layer by recristallization of W carbides in WC-Co and WC-TiC-Co hard metal. These result to increase of alloys hardness, ductility, and resistance to wear and decrease of sensibility to fragile rupture. Industrial tests have been made.


1995 ◽  
Vol 33 (1-2) ◽  
pp. 82-84
Author(s):  
S. M. Solonin ◽  
I. F. Martynova ◽  
V. V. Semida ◽  
N. V. Goncharuk

2000 ◽  
Vol 26 (1) ◽  
pp. 35-37 ◽  
Author(s):  
V. É. Gyunter ◽  
Yu. F. Yasenchuk ◽  
A. A. Klopotov ◽  
V. N. Khodorenko

2020 ◽  
Vol 82 (3) ◽  
pp. 353-363
Author(s):  
E.G. Glazova ◽  
I.A. Turygina ◽  
I.A. Modin

This article presents a mathematical model that describes, in a one-dimensional approximation, the interconnected processes of unsteady deformation of flat permeable granular layers. The model consists of solid particles and wave processes in pore and surrounding gas. The model is based on nonlinear equations of dynamics of two interpenetrating continua. As interfacial forces, drag forces are taken into account when gas flows around ball particles and friction forces. The numerical solution of the equations is carried out according to the modified scheme of S.K. Godunov, adapted to the problems of the dynamics of interpenetrating media. The contact surfaces of pure gas with the porous granular layer and pore gas are the surface of the fracture of porosity and permeability. The numerical implementation of contact conditions is based on the solution of the problem of disintegration of a gap at a jump in porosity. Solutions are obtained for the effects of plane shock waves on a deformable granular layer. We study the transformation of waves passing through an elastoplastic granular layer with and without taking into account changes in the permeability of the layer. When solving problems, the dependence of the change in the permeability of a layer on its compression is used, which is also obtained numerically when modeling the compression of symmetric fragments of granular layers in a spatial setting. Numerical studies of the processes of nonlinear interaction of shock waves with deformable permeable granular layers have shown that the parameters of transmitted and reflected waves substantially depend on the degree of compression of the granular layers. Assessment of the protective properties of permeable barriers when exposed to strong shock waves should be carried out taking into account changes in their permeability due to deformation.


2010 ◽  
Vol 9 (4) ◽  
pp. 129-131
Author(s):  
S. I. Tokmakova ◽  
T. N. Ul’ko ◽  
O. V. Bondarenko ◽  
O. V. Sysoyeva ◽  
T. V. Voblova ◽  
...  

The efficiency of treatment of herpetic stomatitis by autonomous porous titanium nickelide applicators with the use of liquid nitrogen was assessed. In 43 patients, the Hossley-Bergman pain index and erosion epithelization terms after the cryo treatment compared to traditional methods were taken into account. The developed treatment method is characterized by the simplicity, low cost, absence of contraindication and side effects.


2005 ◽  
Vol 44 (34) ◽  
pp. 5447-5451 ◽  
Author(s):  
Brian K. H. Yen ◽  
Axel Günther ◽  
Martin A. Schmidt ◽  
Klavs F. Jensen ◽  
Moungi G. Bawendi

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