scholarly journals Electrochemical Removal of Cefazolin from Aqueous Media by Novel Composite Anodes: Effects of Electrolytes and Operating Parameters

2021 ◽  
pp. ArticleID:211249
Author(s):  
Ayşe Kurt ◽  
Author(s):  
Swapneel K. Bisen ◽  
Prashant S. Niphadkar ◽  
Sachin U. Nandanwar ◽  
Irina Simakova ◽  
Vijay V. Bokade

2019 ◽  
Vol 70 (1) ◽  
pp. 185-189
Author(s):  
Gabriela Elena Badea ◽  
Lotfi Aleya ◽  
Petronel Mustatea ◽  
Delia Mirela Tit ◽  
Laura Endres ◽  
...  

The electrochemical chlorate reduction at the Pt electrode in 0.5 M H2SO4 deaerated solutions has been studied using potentiostatic steady-state voltammetry. The kinetics parameters (Tafel slope, charge transfer coefficient, current density, and reaction order) were evaluated in function of chlorate concentration (1x10-4 � 0.2 M KClO3). The process of chlorate reduction is a complex one that implies two charge transfer controlled steps with formation of free radicals and an extent potential region controlled by the concentration polarization. The current density dependence of chlorate concentration tends to an exponential growth at concentration � 0.1 M KClO3 and becomes exponential in the conditions of the catalyst system presence. In the second charge transfer, a surface reaction between free radical �Cl-2 and platinum electrode with formation of complex anions PtCL42- and PtCL62- is responsible for the rapid increase of the reaction rate.


Author(s):  
P.J. Killingworth ◽  
M. Warren

Ultimate resolution in the scanning electron microscope is determined not only by the diameter of the incident electron beam, but by interaction of that beam with the specimen material. Generally, while minimum beam diameter diminishes with increasing voltage, due to the reduced effect of aberration component and magnetic interference, the excited volume within the sample increases with electron energy. Thus, for any given material and imaging signal, there is an optimum volt age to achieve best resolution.In the case of organic materials, which are in general of low density and electric ally non-conducting; and may in addition be susceptible to radiation and heat damage, the selection of correct operating parameters is extremely critical and is achiev ed by interative adjustment.


Author(s):  
David C Joy

The electron source is the most important component of the Scanning electron microscope (SEM) since it is this which will determine the overall performance of the machine. The gun performance can be described in terms of quantities such as its brightness, its source size, its energy spread, and its stability and, depending on the chosen application, any of these factors may be the most significant one. The task of the electron gun in an SEM is, in fact, particularly difficult because of the very wide range of operational parameters that may be required e.g a variation in probe size of from a few angstroms to a few microns, and a probe current which may go from less than a pico-amp to more than a microamp. This wide range of operating parameters makes the choice of the optimum source for scanning microscopy a difficult decision.Historically, the first step up from the sealed glass tube ‘cathode ray generator’ was the simple, diode, tungsten thermionic emitter.


2020 ◽  
Vol 56 (27) ◽  
pp. 3851-3854 ◽  
Author(s):  
Xiaomin Chai ◽  
Hai-Hua Huang ◽  
Huiping Liu ◽  
Zhuofeng Ke ◽  
Wen-Wen Yong ◽  
...  

A Co-based complex displayed the highest photocatalytic performance for CO2 to CO conversion in aqueous media.


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