scholarly journals Preparation and study of the structural and optical properties of Bi2S3 thin films by Spray pyrolysis method

2017 ◽  
Vol 14 (1) ◽  
pp. 75-79
Author(s):  
Baghdad Science Journal

In this research Bi2S3 thin films have been prepared on glass substrates using chemical spray pyrolysis method at substrate temperature (300oC) and molarity (0.015) mol. Structural and optical properties of the thin films above have been studied; XRD analysis demonstrated that the Bi2S3 films are polycrystalline with (031) orientation and with Orthorhombic structure. The optical properties were studied using the spectral of the absorbance and transmission of films in wavelength ranging (300-1100) nm. The study showed that the films have high transmission within the range of the visible spectrum. Also absorption coefficient, extinction coefficient and the optical energy gap (Eg) was calculated, found that the film have direct energy gap equal to 2.8 eV.

Author(s):  
Sabah A. Salman ◽  
Ziad T. Khodair ◽  
Sahar J. Abed

Cobalt Ferrite CoFe2O4 thin films have been deposited by chemical spray pyrolysis method (CSP) on glass substrates at different substrate temperatures (300, 350, 400 and 450°C) with an interval of (50°C) using Cobalt Nitrate and Ferric Nitrate as Cobalt and Iron sources respectively, at thickness (400±20) nm. The effect of substrate temperatures change on the optical properties for all prepared films was studied. The optical properties for all the films were studied by recording the transmittance and absorbance spectrum in the range of (300-900) nm. The results showed decreases in transmittance and increases in absorbance with increasing the substrate temperatures. the optical energy gap for allowed direct electronic transition was calculated and it was found that decreases with increasesing the substrate temperatures (2.40-2.22 eV), the Urbach energy increases with increasesing the substrate temperatures and it is values range between (634.6-700.5) meV. The optical constants (absorption coefficient, refractive index, extinction coefficient, real and imaginary parts of dielectric constant and optical conductivity) as a function of photon energy for all prepared films were calculated.


2019 ◽  
Vol 14 (29) ◽  
pp. 182-190
Author(s):  
Nadia Jasim Ghdeeb

CdS and CdS:Sn thin films were successfully deposited on glasssubstrates by spray pyrolysis method. The films were grown atsubstrate temperatures 300 C°. The effects of Sn concentration on thestructural and optical properties were studied.The XRD profiles showed that the films are polycrystalline withhexagonal structure grown preferentially along the (002) axis. Theoptical studies exhibit direct allowed transition. Energy band gapvary from 3.2 to 2.7 eV.


2014 ◽  
Vol 11 (2) ◽  
pp. 518-526
Author(s):  
Baghdad Science Journal

Thin films of pure tin mono-sulfide SnS and tin mono-sulfide for (1,2,3,4)% fluorine SnS:F with Thicknesses of (0.85 ±0.05) ?m and (0.45±0.05) ?m respectively were prepared by chemical spray pyrolysis technique. the effect of doping of F on structural and optical properties has been studied. X-Ray diffraction analysis showed that the prepared films were polycrystalline with orthorhombic structure. It was found that doping increased the intensity of diffraction peaks. Optical properties of all samples were studied by recording the absorption and transmission spectrum in range of wave lengths (300-900) nm. The optical energy gap for direct forbidden transition and indirect allowed transition were evaluated It is found that for doping less than 2% the optical energy gap increases as the percentage of doping increases in the samples while for doping more than 2% the values of the optical energy gap decreases as the percentage of doping increases.


Coatings ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1392
Author(s):  
Oleksii Diachenko ◽  
Jaroslav Kováč ◽  
Oleksandr Dobrozhan ◽  
Patrik Novák ◽  
Jaroslav Kováč ◽  
...  

Copper oxide thin films were obtained using pulsating spray pyrolysis method. The morphological, structural, and optical properties of fabricated films were studied. X-ray analysis revealed that the CuO thin films are single-phase. The study of films morphology by SEM and AFM methods showed that the obtained films have a fairly high surface roughness and contain grains of different shapes and sizes. It was found that the obtained films of copper oxide have high values of the absorption coefficient, which confirms the possibility of their use as absorbing layers for solar cells. The obtained values of the optical band gap of the material are in the range from 1.45 eV to 1.60 eV. Raman spectroscopy revealed three modes A1g, B1g, and B2g, of the crystal structure of monoclinic CuO. The devices based on p-type copper oxide are promising for solar cells fabrication because they can reduce production costs, due to their low cost and inexpensive production methods compared to silicon solar cells fabrication.


Author(s):  
Khalid Haneen Abass

Spray pyrolysis method that used to prepare Cu:NiO thin films onto glass substrate with various annealing temperature. Spectral transmittance of prepared thin films determined by UV-Visible spectrophotometer in the range of (380-900) nm. The transmittance decreased with increasing annealing temperature. While the absorption coefficient and extinction coefficient increased with increasing annealing temperature. Energy gap decreased from 2.9 eV before annealing to 2.78 eV after 500 °C annealing temperature.


2009 ◽  
Vol 6 (3) ◽  
pp. 519-225
Author(s):  
Baghdad Science Journal

In this research we prepared CdS thin films by Spray pyrolysis method on a glass substrates and we study its structural , optical , electrical properties .The result of (X-Ray ) diffraction showed that all thin films have a polycrystalline structure , The relation of the transmission as a function of wavelength for the CdS films had been studied , The investigated of direct energy gap of the CdS its value is (2.83 eV). In Hall effect measurement of the CdS we find the charge carriers is p – type and Hall coefficient 1157.33(cm3/c) ,Hall mobility 6.77(cm2/v.s)


2019 ◽  
Vol 30 (1) ◽  
pp. 193
Author(s):  
Karrar Mahdi Saleh

In the present work, undoped CdS and doped with iron CdS:Fe+3 thin films have been prepared by chemical spray pyrolysis method on glass substrate with different temperature from cadmium nitrate solution with constant thickness(450 ± 5 nm), and study the effect of the percentage of doping with iron on optical properties of prepared films. The optical properties have been studied from transmittance and absorbance spectral within wavelengths range (380-900 nm). The results showed that all the prepared films has direct electronic transitions and optical energy gap between (2.31-2.44 eV). They also showed that the transmittance and optical energy gap of films prepared from nitrate solution increase with increasing of substrate temperature, then transmittance start downward with the continued increase in temperature (400, 450 oC), and a decrease in the optical energy gap with increasing doping percentage with iron.


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