scholarly journals Addition of Reed-Derived Cellulose Nanofibers to Change Handsheet Properties

2020 ◽  
Vol 76 (5) ◽  
pp. 144-150
Author(s):  
Hailan Jin ◽  
Ryota Kose ◽  
Takayuki Okayama
TAPPI Journal ◽  
2013 ◽  
Vol 12 (3) ◽  
pp. 17-23 ◽  
Author(s):  
WANHEE IM ◽  
HAK LAE LEE ◽  
HYE JUNG YOUN ◽  
DONGIL SEO

Preflocculation of filler particles before their addition to pulp stock provides the most viable and practical solution to increase filler content while minimizing strength loss. The characteristics of filler flocs, such as floc size and structure, have a strong influence on preflocculation efficiency. The influence of flocculant systems on the structural characteristics of filler flocs was examined using a mass fractal analysis method. Mass fractal dimensions of filler flocs under high shear conditions were obtained using light diffraction spectroscopy for three different flocculants. A single polymer (C-PAM), a dual cationic polymer (p-DADMAC/C-PAM) and a C-PAM/micropolymer system were used as flocculants, and their effects on handsheet properties were investigated. The C-PAM/micropolymer system gave the greatest improvement in tensile index. The mass fractal analysis showed that this can be attributed to the formation of highly dense and spherical flocs by this flocculant. A cross-sectional analysis of the handsheets showed that filler flocs with more uniform size were formed when a C-PAM/micropolymer was used. The results suggest that a better understanding of the characteristics of preflocculated fillers and their influence on the properties of paper can be gained based on a fractal analysis.


2018 ◽  
Vol 72 (1) ◽  
pp. 59-65
Author(s):  
Masayuki Kawasaki
Keyword(s):  

2020 ◽  
Vol 31 (7) ◽  
pp. 2932-2941 ◽  
Author(s):  
Annie M. Rahmatika ◽  
Yohsuke Goi ◽  
Takeo Kitamura ◽  
Yuko Morita ◽  
Ferry Iskandar ◽  
...  

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1841
Author(s):  
Kang Li ◽  
Xuejie Zhang ◽  
Yan Qin ◽  
Ying Li

Aerogels have been widely used in the adsorption of pollutants because of their large specific surface area. As an environmentally friendly natural polysaccharide, cellulose is a good candidate for the preparation of aerogels due to its wide sources and abundant polar groups. In this paper, an approach to construct cellulose nanofibers aerogels with both the good mechanical property and the high pollutants adsorption capability through chemical crosslinking was explored. On this basis, TiO2 nanoparticles were loaded on the aerogel through the sol-gel method followed by the hydrothermal method, thereby the enriched pollutants in the aerogel could be degraded synchronously. The chemical cross-linker not only helps build the three-dimensional network structure of aerogels, but also provides loading sites for TiO2. The degradation efficiency of pollutants by the TiO2@CNF Aerogel can reach more than 90% after 4 h, and the efficiency is still more than 70% after five cycles. The prepared TiO2@CNF Aerogels have high potential in the field of environmental management, because of the high efficiency of treating organic pollutes and the sustainability of the materials. The work also provides a choice for the functional utilization of cellulose, offering a valuable method to utilize the large amount of cellulose in nature.


2021 ◽  
Vol 33 (28) ◽  
pp. 2170219
Author(s):  
Tomas Rosén ◽  
Benjamin S. Hsiao ◽  
L. Daniel Söderberg
Keyword(s):  

Cellulose ◽  
2021 ◽  
Author(s):  
Katri S. Kontturi ◽  
Koon-Yang Lee ◽  
Mitchell P. Jones ◽  
William W. Sampson ◽  
Alexander Bismarck ◽  
...  

Abstract Cellulose nanopapers provide diverse, strong and lightweight templates prepared entirely from sustainable raw materials, cellulose nanofibers (CNFs). Yet the strength of CNFs has not been fully capitalized in the resulting nanopapers and the relative influence of CNF strength, their bonding, and biological origin to nanopaper strength are unknown. Here, we show that basic principles from paper physics can be applied to CNF nanopapers to illuminate those relationships. Importantly, it appeared that ~ 200 MPa was the theoretical maximum for nanopapers with random fibril orientation. Furthermore, we demonstrate the contrast in tensile strength for nanopapers prepared from bacterial cellulose (BC) and wood-based nanofibrillated cellulose (NFC). Endemic amorphous polysaccharides (hemicelluloses) in NFC act as matrix in NFC nanopapers, strengthening the bonding between CNFs just like it improves the bonding between CNFs in the primary cell wall of plants. The conclusions apply to all composites containing non-woven fiber mats as reinforcement. Graphic abstract


2021 ◽  
Vol 27 ◽  
pp. 100180
Author(s):  
A.M. Serpa Guerra ◽  
C. Gómez Hoyos ◽  
J.A. Velásquez-Cock ◽  
P. Gañán Rojo ◽  
A. Eceiza ◽  
...  

Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2315
Author(s):  
Ramin Hosseinnezhad

The shear-induced and cellulose-nanofiber nucleated crystallization of two novel aliphatic–aromatic copolyesters is outlined due to its significance for the in situ generation of biodegradable nanocomposites, which require the crystallization of nanofibrous sheared inclusions at higher temperatures. The shear-induced non-isothermal crystallization of two copolyesters, namely, poly(butylene adipate-co-succinate-co-glutarate-co-terephthalate) (PBASGT) and poly(butylene adipate-co-terephthalate) (PBAT), was studied following a light depolarization technique. To have a deep insight into the process, the effects of the shear rate, shear time, shearing temperature and cooling rate on the initiation, kinetics, growth and termination of crystals were investigated. Films of 60 μm were subjected to various shear rates (100–800 s−1) for different time intervals during cooling. The effects of the shearing time and increasing the shear rate were found to be an elevated crystallization temperature, increased nucleation density, reduced growth size of lamella stacks and decreased crystallization time. Due to the boosted nucleation sites, the nuclei impinged with each other quickly and growth was hindered. The effect of the cooling rate was more significant at lower shear rates. Shearing the samples at lower temperatures, but still above the nominal melting point, further shifted the non-isothermal crystallization to higher temperatures. As a result of cellulose nanofibers’ presence, the crystallization of PBAT, analyzed by DSC, was shifted to higher temperatures.


Sign in / Sign up

Export Citation Format

Share Document