Enhancing Heavy-Oil-Recovery Efficiency by Combining Low-Salinity-Water and Polymer Flooding

SPE Journal ◽  
2020 ◽  
pp. 1-17
Author(s):  
Yang Zhao ◽  
Shize Yin ◽  
Randall S. Seright ◽  
Samson Ning ◽  
Yin Zhang ◽  
...  
Keyword(s):  
Oil Recovery ◽  
Heavy Oil ◽  
High Salinity ◽  
Polymer Flooding ◽  
Heavy Oil Recovery ◽  
Sweep Efficiency ◽  
Low Salinity ◽  
Low Salinity Water ◽  
Salinity Water ◽  
Increased Oil Recovery

Summary Combining low-salinity-water (LSW) and polymer flooding was proposed to unlock the tremendous heavy-oil resources on the Alaska North Slope (ANS). The synergy of LSW and polymer flooding was demonstrated through coreflooding experiments at various conditions. The results indicate that the high-salinity polymer (HSP) (salinity = 27,500 ppm) requires nearly two-thirds more polymer than the low-salinity polymer (LSP) (salinity = 2,500 ppm) to achieve the target viscosity at the condition of this study. Additional oil was recovered from LSW flooding after extensive high-salinity-water (HSW) flooding [3 to 9% of original oil in place (OOIP)]. LSW flooding performed in secondary mode achieved higher recovery than that in tertiary mode. Also, the occurrence of water breakthrough can be delayed in the LSW flooding compared with the HSW flooding. Strikingly, after extensive LSW flooding and HSP flooding, incremental oil recovery (approximately 8% of OOIP) was still achieved by LSP flooding with the same viscosity as the HSP. The pH increase of the effluent during LSW/LSP flooding was significantly greater than that during HSW/HSP flooding, indicating the presence of the low-salinity effect (LSE). The residual-oil-saturation (Sor) reduction induced by the LSE in the area unswept during the LSW flooding (mainly smaller pores) would contribute to the increased oil recovery. LSP flooding performed directly after waterflooding recovered more incremental oil (approximately 10% of OOIP) compared with HSP flooding performed in the same scheme. Apart from the improved sweep efficiency by polymer, the low-salinity-induced Sor reduction also would contribute to the increased oil recovery by the LSP. A nearly 2-year pilot test in the Milne Point Field on the ANS has shown impressive success of the proposed hybrid enhanced-oil-recovery (EOR) process: water-cut reduction (70 to less than 15%), increasing oil rate, and no polymer breakthrough so far. This work has demonstrated the remarkable economical and technical benefits of combining LSW and polymer flooding in enhancing heavy-oil recovery.

Displacement Efficiency for Low-Salinity Polymer Flooding Including Wettability Alteration

SPE Journal ◽  
2016 ◽  
Vol 22 (02) ◽  
pp. 417-430 ◽  
Author(s):  
Saeid Khorsandi ◽  
Changhe Qiao ◽  
Russell T. Johns
Keyword(s):  
Experimental Data ◽  
Oil Recovery ◽  
Analytical Solutions ◽  
Polymer Concentration ◽  
Polymer Flooding ◽  
Wettability Alteration ◽  
Displacement Efficiency ◽  
Low Salinity ◽  
Low Salinity Water ◽  
Salinity Water

Summary Polymer flooding can significantly improve sweep and delay breakthrough of injected water, thereby increasing oil recovery. Polymer viscosity degrades in reservoirs with high-salinity brines, so it is advantageous to inject low-salinity water as a preflush. Low-salinity waterflooding (LSW) can also improve local-displacement efficiency by changing the wettability of the reservoir rock from oil-wet to more water-wet. The mechanism for wettability alteration for LSW in sandstones is not very well-understood; however, experiments and field studies strongly support that cation-exchange (CE) reactions are the key elements in wettability alteration. The complex coupled effects of CE reactions, polymer properties, and multiphase flow and transport have not been explained to date. This paper presents the first analytical solutions for the coupled synergistic behavior of LSW and polymer flooding considering CE reactions, wettability alteration, adsorption, inaccessible pore volume (IPV), and salinity effects on polymer viscosity. A mechanistic approach that includes the CE of Ca2+, Mg2+, and Na+ is used to model the wettability alteration. The aqueous phase viscosity is a function of polymer and salt concentrations. Then, the coupled multiphase-flow and reactive-transport model is decoupled into three simpler subproblems—the first in which CE reactions are solved, the second in which a variable polymer concentration can be added to the reaction path, and the third in which fractional flows can be mapped onto the fixed cation and polymer-concentration paths. The solutions are used to develop a front-tracking algorithm, which can solve the slug-injection problem of low-salinity water as a preflush followed by polymer. The results are verified with experimental data and PennSim (2013), a general-purpose compositional simulator. The analytical solutions show that decoupling allows for estimation of key modeling parameters from experimental data, without considering the chemical reactions. Recovery can be significantly enhanced by a low-salinity preflush before polymer injection. For the cases studied, the improved oil recovery (IOR) for a chemically tuned low-salinity polymer (LSP) flood can be as much as 10% original oil in place (OOIP) greater than with considering polymer alone. The results show the structure of the solutions, and, in particular, the velocity of multiple shocks that develop. These shocks can interact, changing recovery. For example, poor recoveries obtained in corefloods for small-slug sizes of low salinity are explained by the intersection of shocks without considering mixing. The solutions can also be used to benchmark numerical solutions and for experimental design. We demonstrate the potential of LSP flooding as a less-expensive and more-effective way for performing polymer flooding when the reservoir wettability can be altered with chemically tuned low-salinity brine.

The Decisive Role of Microdispersion Formation in Improved Oil Recovery by Low-Salinity-Water Injection in Sandstone Formations

SPE Journal ◽  
2019 ◽  
Vol 24 (06) ◽  
pp. 2859-2873 ◽  
Author(s):  
Pedram Mahzari ◽  
Mehran Sohrabi ◽  
Juliana M. Façanha
Keyword(s):  
Crude Oil ◽  
Oil Recovery ◽  
High Salinity ◽  
Quartz Substrate ◽  
Water Injection ◽  
Improved Oil Recovery ◽  
Low Salinity ◽  
Low Salinity Water ◽  
Salinity Water ◽  
Low Salinity Water Injection

Summary Efficiency of low–salinity–water injection primarily depends on oil/brine/rock interactions. Microdispersion formation (as the dominant interfacial interaction between oil and low–salinity water) is one of the mechanisms proposed for the reported additional oil recovery by low–salinity–water injection. Using similar rock and brines, here in this work, different crude–oil samples were selected to examine the relationship between crude–oil potency to form microdispersions and improved oil recovery (IOR) by low–salinity–water injection in sandstone cores. First, the potential of the crude–oil samples to form microdispersions was measured; next, coreflood tests were performed to evaluate the performance of low–salinity–water injection in tertiary mode. Sandstone core plugs taken from a whole reservoir core were used for the experiments. The tests started with spontaneous imbibition followed by forced imbibition of high–salinity brine. Low–salinity brine was then injected in tertiary mode. The oil–recovery profiles and compositions of the produced brine were measured to investigate the IOR benefits as well as the geochemical interactions. The results demonstrate that the ratio of the microdispersion quantity to bond water is the main factor controlling the effectiveness of low–salinity–water injection. In general, a monotonic trend was observed between incremental oil recovery and the microdispersion ratio of the different crude–oil samples. In addition, it can be inferred from the results that geochemical interactions (pH and ionic interactions) would be mainly controlled by the rock's initial wettability, and also that these processes could not affect the additional oil recovery by low-salinity-water injection. To further verify the observations of geochemical interactions, a novel experiment was designed and performed on a quartz substrate to investigate the ionic interactions on the film of water between an oil droplet and a flat quartz substrate, when the high–salinity brine was replaced with the low–salinity brine. The results of the flat–substrate test indicated that the water film beneath the oil could not interact with the surrounding brine, which is in line with the results of the core tests.

New Insights into Geochemical Modeling of Hybrid Low Salinity/Engineered Water and Polymer Injections in Carbonates

2021 ◽  
Author(s):  
Emad W. Al-Shalabi ◽  
Waleed Alameri
Keyword(s):  
Oil Recovery ◽  
Water Injection ◽  
Polymer Rheology ◽  
Hybrid Polymer ◽  
Sweep Efficiency ◽  
Low Salinity ◽  
Low Salinity Water ◽  
Salinity Water ◽  
Harsh Conditions

Abstract For decades, polymer flooding proved to be one of the most effective enhanced oil recovery (EOR) methods. In addition, low salinity/engineered water injection (LSWI/EWI) has been gaining momentum over the last few years. Both techniques seem to be cheaper than other EOR methods. This resulted in an increased interest among operators in these techniques. Moreover, low-salinity water is usually less viscous compared to formation fluids, which warrants a lower volumetric sweep efficiency, especially at high temperatures and in highly heterogeneous formations. The reduction in macroscopic sweep efficiency impairs the improvement in recovery efficiency by low-salinity water. In addition, experimental studies showed that polymer viscosity is considerably improved in less saline water. In this study, hybrid polymer and LSWI/EWI flooding performance is numerically evaluated in carbonate formations under conditions of mixed-to-oil wettability, high temperature, high salinity, and low permeability. A numerical 1D model was constructed using a commercial compositional simulator. The model captures the polymer rheology of a newly developed and commercially available synthetic polymer. Also, the effect of LSWI/EWI on polymer rheology and performance was studied. Oil recovery, pressure drop, and in-situ saturation data were history matched for seawater, polymer, and low salinity water injection cycles. Furthermore, the matched experimental data were utilized to examine the combined polymer and low salinity water effect on the improvement in microscopic displacement efficiency of linear models under reservoir flow conditions. The simulation results showed that hybrid polymer and LSWI/EWI is a viable EOR method for carbonate reservoirs under harsh conditions. Moreover, this work provides new insights into the hybrid application of LSWI/EWI and polymer flooding in carbonates under harsh conditions, the impact of low-salinity water on in-situ polymer rheology, and it promotes further field-scale applications of hybrid polymer-LSWI/EWI to improve volumetric sweep efficiency and overall recovery efficiency.

Development of hybrid low salinity water polymer flooding numerical reservoir simulator and smart proxy model for chemical enhanced oil recovery (CEOR)

2020 ◽  
Vol 187 ◽  
pp. 106751 ◽  
Author(s):  
Eric Thompson Brantson ◽  
Binshan Ju ◽  
Prince Opoku Appau ◽  
Perpetual Hope Akwensi ◽  
Godwill Agyare Peprah ◽  
...  
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Polymer Flooding ◽  
Low Salinity ◽  
Proxy Model ◽  
Low Salinity Water ◽  
Salinity Water ◽  
Reservoir Simulator

scholarly journals Evaluation of a low salinity water flooding with polymer gel treatment in Trinidad and Tobago

2020 ◽  
Vol 10 (8) ◽  
pp. 3971-3981
Author(s):  
Sanyah Ramkissoon ◽  
David Alexander ◽  
Rean Maharaj ◽  
Mohammad Soroush
Keyword(s):  
Trinidad And Tobago ◽  
Oil Recovery ◽  
Xanthan Gum ◽  
Oil Production ◽  
Polymer Flooding ◽  
Water Flooding ◽  
Caribbean Region ◽  
Low Salinity ◽  
Low Salinity Water ◽  
Salinity Water

Abstract Trinidad and Tobago (TT) has a rich history of crude oil production and is still one of the largest oil- and gas-producing countries in the Caribbean region. The energy sector contributes approximately 35% of GDP to its economy; however, economic headwinds due to steadily decreasing oil production, low commodity prices and increased competition worldwide have highlighted the need for more economical methods of enhanced oil recovery (EOR) techniques. Although the use of low salinity polymer flooding for EOR has had success in other countries, critical information relating associated flooding system parameters such as soil type, additive type, adsorption characteristics, rheological (flow) characteristics, pH and salinity is not available and is critical if this type of EOR is to be implemented in TT. The nature and inter-relationship of these parameters are unique to a particular reservoir, and studies in this regard will provide key input data for simulations to produce near realistic projections of this EOR strategy. These projections can be used to evaluate the usefulness of a low salinity polymer flooding in TT and guide for the proper implementation of the strategy. The EOR 33 wells located in the lower Forest sands in Southern Trinidad was selected for study as they satisfied the screening criteria. Laboratory studies of the adsorption of xanthan gum concentrations of 0 to 4000 ppm in combination with NaCl solutions (0–40,000 ppm) onto gravel packed sand found that the mixture of 1000 ppm polymer containing 1000 ppm NaCl exhibited the lowest adsorption capacity. The Langmuir coefficients were derived for each salinity, and together with results from the viscosity studies were inputted within the simulation models. Simulations of a sector of the EOR 33 projected that the highest oil recovery occurred using NaCl < 2000 ppm was 11% greater than water flood. A combination of brine (NaCl < 2000 ppm) with gel technology (1000 ppm polymer) produced the highest oil recovery factor (54%), almost twice that of water flooding, the highest average reservoir pressure and lowest water cut value. The improved performance characteristics observed using low salinity water flood with xanthan gum gel for injection can be associated with improved displacement efficiency and improved the sweep efficiency suggesting the strategy to be a technically feasible option for the EOR well in Trinidad.

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