scholarly journals Phase diagram of solid hints new fundamental constant and sees atomic orbital

2021 ◽  
Author(s):  
Shapiullah Belalovich Abdulvagidov
Keyword(s):  
Phase Diagram ◽  
Solid State ◽  
Triple Point ◽  
Transition Metal Oxides ◽  
Atomic Orbital ◽  
Fundamental Constant ◽  
Molecular Volume ◽  
Zero Field ◽  
Covalent Bonds ◽  
State Tomography

Abstract Cold and pressure transform gas into liquid and then into solid. Van der Waals understood the phase diagram of liquefiable gas with the molecular volume and intermolecular attraction, however, was silent on how solid behaved1. Unfortunately, solid-state phase diagram have remained uncomprehended mystery; only its straight boundary2,3 was explained by struggle of order vs. chaos. Here we show that the volume of orbital overlap has its own energy, with the universal density 8.941 eV/Å3 announced as new fundamental atomic constant that determines the transition temperature TC. Furthermore, we devised solid-state tomography, valid to 5 TPa, - imaging orbital through the baric dependencies of TC. Triangle-shaped pattern of the diagram is explained by the only possible way, just as only one plane passes through triangle: -inflation of the intersection volume during the transition determines hysteresis, but its disappearance does triple point; -approaching ions, whose orbitals overlap, curves the line from zero-field-cooling (ZFC) TC to triple point; -the straight line between zero-field-heating (ZFH) TC and triple point is a consequence of straightening tilting angle. Diamond melting point, calculated from volumes of the tetrahedral covalent bonds, excellently agrees with real; furthermore, the points up to 2 TPa agree with experiment4. Our findings open up way to interpret antiferromagnetism and steric effect in mono, binary, and ternary transition-metal oxides and sulfides5-11, and advance in unravelling unconventional superconductivity12,13, ascertaining the roles of s- and p-hybridizations. Thereby, the importance of the solid-state tomography for organic conductors12,13 being high-compressible and interior of stars can scarcely be exaggerated.

scholarly journals Electronic Phenomena of Transition Metal Oxides

Crystals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 256
Author(s):  
Christian Rodenbücher ◽  
Kristof Szot
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Metal Oxides ◽  
Real World ◽  
Transition Metal Oxides ◽  
Major Research ◽  
Research Fields ◽  
Real World Applications

Transition metal oxides with ABO3 or BO2 structures have become one of the major research fields in solid state science, as they exhibit an impressive variety of unusual and exotic phenomena with potential for their exploitation in real-world applications [...]

scholarly journals Ground state and stability of the fractional plateau phase in metallic Shastry–Sutherland system TmB4

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Matúš Orendáč ◽  
Slavomír Gabáni ◽  
Pavol Farkašovský ◽  
Emil Gažo ◽  
Jozef Kačmarčík ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Phase Diagram ◽  
Ground State ◽  
Constant Magnetic Field ◽  
Paramagnetic Phase ◽  
The Other ◽  
Zero Field ◽  
Plateau Phase ◽  
Low Field ◽  
Zero Field Cooling

AbstractWe present a study of the ground state and stability of the fractional plateau phase (FPP) with M/Msat = 1/8 in the metallic Shastry–Sutherland system TmB4. Magnetization (M) measurements show that the FPP states are thermodynamically stable when the sample is cooled in constant magnetic field from the paramagnetic phase to the ordered one at 2 K. On the other hand, after zero-field cooling and subsequent magnetization these states appear to be of dynamic origin. In this case the FPP states are closely associated with the half plateau phase (HPP, M/Msat = ½), mediate the HPP to the low-field antiferromagnetic (AF) phase and depend on the thermodynamic history. Thus, in the same place of the phase diagram both, the stable and the metastable (dynamic) fractional plateau (FP) states, can be observed, depending on the way they are reached. In case of metastable FP states thermodynamic paths are identified that lead to very flat fractional plateaus in the FPP. Moreover, with a further decrease of magnetic field also the low-field AF phase becomes influenced and exhibits a plateau of the order of 1/1000 Msat.

Structural phase diagram for superconducting cuprates solid state processing for enhanced flux pinning

1992 ◽  
Vol 194 (1-2) ◽  
pp. 150-152 ◽  
Author(s):  
J.L. Tallon ◽  
D.M. Pooke ◽  
R.G. Buckley ◽  
M.R. Presland ◽  
A. Mawdsley ◽  
...  
Keyword(s):  
Phase Diagram ◽  
Solid State ◽  
Flux Pinning ◽  
Structural Phase ◽  
Superconducting Cuprates ◽  
State Processing

Interfacial Microstructure Evolution Between Eutectic SnAgCu Solder and Al/Ni(V)/Cu Thin Films

2002 ◽  
Vol 17 (7) ◽  
pp. 1612-1621 ◽  
Author(s):  
M. Li ◽  
F. Zhang ◽  
W. T. Chen ◽  
K. Zeng ◽  
K. N. Tu ◽  
...  
Keyword(s):  
Thin Films ◽  
Phase Diagram ◽  
Solid State ◽  
Brittle Failure ◽  
Ternary Phase ◽  
Interfacial Microstructure ◽  
Snagcu Solder ◽  
Ball Shear ◽  
Aging Study ◽  
Eutectic Snpb

The evolution of interfacial microstructure of eutectic SnAgCu and SnPb solders on Al/Ni(V)/Cu thin films was investigated after various heat treatments. In the eutectic SnPb system, the Ni(V) layer was well protected after 20 reflow cycles at 220 °C. In the SnAgCu solder system, after 5 reflow cycles at 260 °C, the (Cu,Ni)6Sn5 ternary phase formed and Sn was detected in the Ni(V) layer. After 20 reflow cycles, the Ni(V) layer disappeared and spalling of the (Cu,Ni)6Sn5 was observed, which explains the transition to brittle failure mode after ball shear testing. The different interfacial reactions that occurred in the molten SnAgCu and SnPb systems were explained in terms of different solubilities of Cu in the two systems. The dissolution and formation of the (Cu,Ni)6Sn5phase were discussed on the basis of a Sn–Ni–Cu phase diagram. In the solid-state aging study of the SnAgCu samples annealed at 150 °C for up to 1000 h, the Ni(V) layer was intact and the intermetallic compound formed was Cu6Sn5 and not (Cu,Ni)6Sn5, which is the same as was observed for the eutectic SnPb system.

Phase diagram of water in the vicinity of the triple point

1996 ◽  
Vol 105 (9) ◽  
pp. 3722-3725 ◽  
Author(s):  
Sergey N. Tkachev ◽  
Rashit M. Nasimov ◽  
Vladimir A. Kalinin
Keyword(s):  
Phase Diagram ◽  
Triple Point

scholarly journals Covalency, double-counting, and the metal-insulator phase diagram in transition metal oxides

2012 ◽  
Vol 86 (19) ◽  
Author(s):  
Xin Wang ◽  
M. J. Han ◽  
Luca de' Medici ◽  
Hyowon Park ◽  
C. A. Marianetti ◽  
...  
Keyword(s):  
Phase Diagram ◽  
Transition Metal ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
Double Counting ◽  
Metal Insulator

High Oxidation State Alkali-Metal Late-Transition-Metal Oxides

2000 ◽  
Vol 658 ◽  
Author(s):  
David B. Currie ◽  
Andrew L. Hector ◽  
Emmanuelle A. Raekelboom ◽  
John R. Owen ◽  
Mark T. Weller
Keyword(s):  
High Pressure ◽  
Solid State ◽  
Transition Metal Oxides ◽  
Late Transition Metal ◽  
High Oxidation State ◽  
Powder Neutron Diffraction ◽  
Nmr Study ◽  
High Oxidation ◽  
Late Transition ◽  
Cation Sites

ABSTRACTLi2NaCu2O4 has been prepared by solid state reaction under high-pressure (250 Atm) oxygen. A structural study, using time-of-flight powder neutron diffraction on a sample made with 7Li, shows a material isostructural with Li3Cu2O4, with sodium occupying the octahedral and lithium the tetrahedral A-cation sites. A 7Li MAS-NMR study of Li3Cu2O4, Li2NaCu2O4 and Li2CuO2 has been used to confirm the Li/Na site ordering.

Thermochemische Untersuchungen zu den Systemen SE2O3-SeO2. V. Ytterbiumselenoxide auf dem Schnitt Yb2O3-SeO2/Thermochemical Investigations of Systems RE2O3-SeO2. V. Ytterbium Selenium Oxides on the Line Yb2O3-SeO2

2002 ◽  
Vol 57 (8) ◽  
pp. 868-876 ◽  
Author(s):  
H. Oppermann ◽  
M. Zhang-Preße ◽  
P. Schmidt
Keyword(s):  
Thermal Analysis ◽  
Phase Diagram ◽  
Solid State ◽  
Ir Spectroscopy ◽  
Powder Diffraction ◽  
Solid State Reaction ◽  
Total Pressure ◽  
Pressure Measurements ◽  
Thermodynamical Equilibrium ◽  
X Ray

The pure ternary phases on the line Yb2O3-SeO2 in thermodynamical equilibrium have been synthesized by solid state reaction and characterized using X-ray powder diffraction and IR-spectroscopy. There exist three phases: Yb2SeO5, Yb2Se3O9 and Yb2Se4O11, the last one with a homogeneiety range extending a higher SeO2-content. The thermal decompositions have been determined by total pressure measurements, and the thermodynamical data of the compounds have been derived. The phase diagram and the phase barogram have been established using the results of thermal analysis and total pressure measurements.

scholarly journals Vortex phase diagram and the normal state of cuprates with charge and spin orders

2020 ◽  
Vol 6 (7) ◽  
pp. eaay8946 ◽  
Author(s):  
Zhenzhong Shi ◽  
P. G. Baity ◽  
T. Sasagawa ◽  
Dragana Popović
Keyword(s):  
Phase Diagram ◽  
Normal State ◽  
Ground State ◽  
High Field ◽  
High Temperature Superconductors ◽  
Upper Critical Field ◽  
Energy Scale ◽  
Zero Field ◽  
Vortex Matter ◽  
Nonlinear Transport

The phase diagram of underdoped cuprates in a magnetic field (H) is key to understanding the anomalous normal state of these high-temperature superconductors. However, the upper critical field (Hc2), the extent of superconducting (SC) phase with vortices, and the role of charge orders at high H remain controversial. Here we study stripe-ordered La-214, i.e., cuprates in which charge orders are most pronounced and zero-field SC transition temperatures Tc0 are lowest. This enables us to explore the vortex phases in a previously inaccessible energy scale window. By combining linear and nonlinear transport techniques sensitive to vortex matter, we determine the T − H phase diagram, directly detect Hc2, and reveal novel properties of the high-field ground state. Our results demonstrate that quantum fluctuations and disorder play a key role as T → 0, while the high-field ground state is likely a metal, not an insulator, due to the presence of stripes.

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