Toward a Modular Ionic Liquid" Platform for the Custom Design of Energetic Materials: Understanding How the Dual Nature of Ionic Liquids Relates Key Physical Properties to Target Structures"

A novel magnetic ionic liquid aqueous two-phase systems (MILATPs) has been developed, based on a series of novelly synthesized guanidinium-based magnetic ionic liquids.

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Ionic liquid regioisomers: structure effect on the thermal and physical properties

New Journal of Chemistry ◽

10.1039/c4nj01220h ◽

2015 ◽

Vol 39 (3) ◽

pp. 1563-1566 ◽

Cited By ~ 9

Author(s):

John D. Watkins ◽

Elliot A. Roth ◽

Michael Lartey ◽

Erik Albenze ◽

Mingjiang Zhong ◽

...

Keyword(s):

Ionic Liquid ◽

Ionic Liquids ◽

Physical Properties ◽

Alkyl Group ◽

Structure Effect ◽

Side Group ◽

Group Placement ◽

A Minor

Effects of side group placement was studied on triazolium ionic liquids and how a minor change in alkyl group placement results in very different properties.

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Ionic liquid solvents: the importance of microscopic interactions in predicting organic reaction outcomes

Pure and Applied Chemistry ◽

10.1515/pac-2016-1008 ◽

2017 ◽

Vol 89 (6) ◽

pp. 745-757 ◽

Cited By ~ 14

Author(s):

Sinead T. Keaveney ◽

Ronald S. Haines ◽

Jason B. Harper

Keyword(s):

Ionic Liquid ◽

Ionic Liquids ◽

Transition State ◽

Physical Properties ◽

Solvent Effects ◽

Recent Progress ◽

Comprehensive Understanding ◽

Organic Reaction ◽

Microscopic Interactions ◽

Molecular Solvents

AbstractIonic liquids are attractive alternatives to molecular solvents as they have many favourable physical properties and can produce different organic reaction outcomes compared to molecular solvents. Thus far, interactions between the ionic liquid components and specific sites (such as charged centres, lone pairs and π systems) on the reagents and transition state have been identified as affecting reaction outcome; a comprehensive understanding of these interactions is necessary to allow prediction of ionic liquid solvent effects. This manuscript summarises our recent progress in the development of a framework for predicting the effect of an ionic liquid solvent on the outcome of organic processes. There will be a particular focus on the importance of the different interactions between the ionic liquid components and the species along the reaction coordinate that are responsible for the changes in reaction outcome observed in the cases described.

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Physical Properties of Substituted Imidazolium Based Ionic Liquids Gel Electrolytes

Zeitschrift für Naturforschung A ◽

10.1515/zna-2002-1101 ◽

2002 ◽

Vol 57 (11) ◽

pp. 839-846 ◽

Cited By ~ 14

Author(s):

Thomas E. Sutto ◽

Hugh C. De Long ◽

Paul C. Trulove

Keyword(s):

Ionic Liquid ◽

Ionic Liquids ◽

Ionic Conductivity ◽

Physical Properties ◽

Molten Salt ◽

Polyacrylic Acid ◽

Molten Salts ◽

Polymer Gel ◽

Composite Gels ◽

Gel Electrolytes

The physical properties of solid gel electrolytes of either polyvinylidene diflurohexafluoropropylene or a combination of polyvinylidene hexafluoropropylene and polyacrylic acid, and the molten salts 1-ethyl-3-methylimidazolium tetrafluoroborate, 1,2-dimethyl-3-n-propylimidazolium tetrafluoroborate, and the new molten salts 1,2-dimethyl-3-n-butylimidazolium tetrafluoroborate, and 1,2-dimethyl-3-n-butylimidazolium hexafluorophosphate were characterized by temperature dependent ionic conductivity measurements for both the pure molten salt and of the molten salt with 0.5 M Li+ present. Ionic conductivity data indicate that for each of the molten salts, the highest concentration of molten salt allowable in a single component polymer gel was 85%, while gels composed of 90%molten salt were possible when using both polyvinylidene hexafluorophosphate and polyacrylic acid. For polymer gel composites prepared using lithium containing ionic liquids, the optimum polymer gel composite consisted of 85% of the 0.5 M Li+/ionic liquid, 12.75% polyvinylidene hexafluoropropylene, and 2.25% poly (1-carboxyethylene). The highest ionic conductivity observed was for the gel containing 90%1-ethyl-3-methyl-imidazolium tetrafluoroborate, 9.08 mS/cm. For the lithium containing ionic liquid gels, their ionic conductivity ranged from 1.45 to 0.05 mS/cm, which is comparable to the value of 0.91 mS/cm, observed for polymer composite gels containing 0.5 M LiBF4 in propylene carbonate.

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RESEARCH PROGRESS ON PREDICTION MODELS FOR PHYSICAL PROPERTIES OF IONIC LIQUID

Modern Physics Letters B ◽

10.1142/s0217984910023931 ◽

2010 ◽

Vol 24 (13) ◽

pp. 1487-1490 ◽

Cited By ~ 2

Author(s):

QUAN WANG ◽

XIAO MING WU ◽

DA YONG ZHANG

Keyword(s):

Ionic Liquid ◽

Ionic Liquids ◽

Physical Properties ◽

Recent Progress ◽

Prediction Models ◽

Research Progress ◽

Extensive Investigation ◽

Important Data ◽

Impossible Task ◽

The Given

The field of ionic liquid has gained rapid growth in recent years and occupied a forefront in green chemistry. As a useful instrument to the research and development of novel ionic liquids, the physical properties are of utmost importance. Thus, great efforts have been made to obtain these important data, as it is far from getting sufficient physiochemical information for intensive and extensive investigation which consequently becomes a bottleneck for the theoretical and applicable research of ionic liquids. Additionally, with the given immeasurable possible ionic liquids by various cation and anion combinations, it is an impossible task to find an ideal ionic liquid with desired physical properties using conventionally "try and error" process. For these reasons, exploration of novel prediction models for physical properties of ionic liquid is imperative. This paper gives an overview of recent progress of various prediction models.

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Polymeric ionic liquids: a strategy for preparation of novel polymeric materials

Chemical Papers ◽

10.1515/chempap-2015-0127 ◽

2015 ◽

Vol 69 (9) ◽

Cited By ~ 1

Author(s):

Manoochehr Farzin ◽

Keyvan Nosratzadegan ◽

Jamshid Azarnia ◽

Mohammad Ferdosi

Keyword(s):

Ionic Liquid ◽

Ionic Liquids ◽

Energetic Materials ◽

Polymeric Materials ◽

Catalyst Supports ◽

N Content ◽

Polymeric Ionic Liquids ◽

Polymeric Ionic Liquid

AbstractA novel polymeric ionic liquid (PIL), bearing high C-N and N-N content, potentially suitable for new safe energetic materials and catalyst supports was introduced. The PIL was prepared by way of radical co-polymerisation of 1-vinyl-3-p-nitrobenzylimidazolium bromide and 1-vinylimidazole at 80◦C using azobisisobutyronitrile (AIBN) as an initiator. The PIL thus produced was successfully transformed into NO

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Mapping the “Extra Solvent Power, ESP” of Ionic Liquids for Monomers, Polymers and Globular Nanoparticles

10.26434/chemrxiv.5384293.v1 ◽

2017 ◽

Author(s):

Jose A. Pomposo

Keyword(s):

Ionic Liquid ◽

Ionic Liquids ◽

Linear Polymers ◽

Green Solvents ◽

Ionic Polymers ◽

First Time ◽

Solvent Power

Understanding the miscibility behavior of ionic liquid (IL) / monomer, IL / polymer and IL / nanoparticle mixtures is critical for the use of ILs as green solvents in polymerization processes, and to rationalize recent observations concerning the superior solubility of some proteins in ILs when compared to standard solvents. In this work, the most relevant results obtained in terms of a three-component Flory-Huggins theory concerning the “Extra Solvent Power, ESP” of ILs when compared to traditional non-ionic solvents for monomeric solutes (case I), linear polymers (case II) and globular nanoparticles (case III) are presented. Moreover, useful ESP maps are drawn for the first time for IL mixtures corresponding to case I, II and III. Finally, a potential pathway to improve the miscibility of non-ionic polymers in ILs is also proposed.

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Dynamics of Ion Locking in Doubly Polymerized Ionic Liquids

10.26434/chemrxiv.13239059.v1 ◽

2020 ◽

Author(s):

Swati Arora ◽

Julisa Rozon ◽

Jennifer Laaser

Keyword(s):

Dielectric Constant ◽

Ionic Liquid ◽

Ionic Liquids ◽

Ion Pairs ◽

Polymer Chains ◽

Ion Motion ◽

Charged Species ◽

Broadband Dielectric Spectroscopy ◽

Covalently Linked ◽

Insight Into

<div>In this work, we investigate the dynamics of ion motion in “doubly-polymerized” ionic liquids (DPILs) in which both charged species of an ionic liquid are covalently linked to the same polymer chains. Broadband dielectric spectroscopy is used to characterize these materials over a broad frequency and temperature range, and their behavior is compared to that of conventional “singly-polymerized” ionic liquids (SPILs) in which only one of the charged species is attached to the polymer chains. Polymerization of the DPIL decreases the bulk ionic conductivity by four orders of magnitude relative to both SPILs. The timescales for local ionic rearrangement are similarly found to be approximately four orders of magnitude slower in the DPILs than in the SPILs, and the DPILs also have a lower static dielectric constant. These results suggest that copolymerization of the ionic monomers affects ion motion on both the bulk and the local scales, with ion pairs serving to form strong physical crosslinks between the polymer chains. This study provides quantitative insight into the energetics and timescales of ion motion that drive the phenomenon of “ion locking” currently under investigation for new classes of organic electronics.</div>

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Ionic Liquid Assisted Synthesis of Some 2-Aminobenzenethiols

Letters in Organic Chemistry ◽

10.2174/1570178615666181011114454 ◽

2019 ◽

Vol 16 (7) ◽

pp. 550-555

Author(s):

Dinesh K. Jangid ◽

Keshav L. Ameta ◽

Surbhi Dhadda ◽

Anjali Guleria ◽

Prakash G. Goswami ◽

...

Keyword(s):

Ionic Liquid ◽

Ionic Liquids ◽

Comparative Study ◽

Maximum Yield ◽

Efficient Synthesis ◽

Target Molecules ◽

Presence And Absence

Ionic Liquid assisted efficient synthesis of some 2-aminobenzenethiols has been reported using three different Ionic Liquids (ILs) namely methylimidazolium tetrafluoroborate [MIM]+[BF4]−, methylimidazolium chloride [MIM]+[Cl]− and methylimidazolium nitrate [MIM]+[NO3]−. A comparative study has been carried out for the synthesis of target molecules in the presence and absence of IL, leading to conclusion that maximum yield has been observed with [MIM]+[BF4]−.

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Dispersive Liquid-Liquid Microextraction Based on Ionic Liquid and Spectrophotometric Determination of Bilirubin in Biological Samples

Current Analytical Chemistry ◽

10.2174/1573411015666190212123437 ◽

2020 ◽

Vol 16 (5) ◽

pp. 652-659

Author(s):

Asiye A. Avan ◽

Hayati Filik

Keyword(s):

Ionic Liquid ◽

Ionic Liquids ◽

Biological Samples ◽

Urine Samples ◽

Spectrophotometric Detection ◽

Full Color ◽

Dispersive Liquid Liquid Microextraction ◽

Urine And Serum ◽

Liquid Microextraction

Background: An Ionic Liquid-based based Dispersive Liquid-Liquid Microextraction (IL-DLLME) method was not applied to preconcentration and determination of bilirubin. Ionic Liquids (ILs) are new chemical compounds. In recent years, Ionic Liquids (ILs) have been employed as alternative solvents to toxic organic solvents. Due to these perfect properties, ILs have already been applied in many analytical extraction processes, presenting high extraction yield and selectivity for analytes. Methods: In this study, IL-DLLME was applied to biological samples (urine and serum) for the spectrophotometric detection of bilirubin. For bilirubin analysis, the full-color development was based on the reaction with periodate in the presence of hydrochloric acid. The high affinity of bilirubin for the ionic liquid phase gave extraction percentages above 98% in 0.3 M HCl solution. Results: Several IL-extraction parameters were optimized and room temperature ionic liquid 1-butyl- 1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide and ethanol were used as extraction and disperser solution. The linear range was found in the range of 0.5-6.0 μM (0.3-3.5 μg mL-1) and the limits of detection of the proposed method was 0.5 μM (0.3 μg mL-1). The proposed method was applied for the preconcentration and separation of trace bilirubin in real urine samples. Also, the recoveries for bilirubin in spiked biological samples (urine and serum) were found to be acceptable, between 95-102%. Conclusion: The proposed IL-DLLMEapproach was employed for the enrichment and determination of trace levels of bilirubin in urine samples using NaIO4 as an oxidizing agent and Uv-vis spectrophotometric detection. The periodate oxidation of bilirubin is rapid, effective, selective, and simple to perform. The method contains only HCl, NaOI4, and an anionic surfactant. The method may be useful for economizing in the consumption of reagents in bilirubin determining. The IL-DLLMEmethod ensures a high yield and has a low toxicity no skin sensitization, no mutagenicity and no ecotoxicity in an aquatic environment since only very low quantities of an IL is required. For full-color formation, no any extra auxiliary reagents are required. Besides, the IL-DLLME technique uses a low-cost instrument such as Uv-vis which is present in most of the medical laboratories.

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