Organic Contaminants in Canadian Coal Wastewaters and Associated Sediments
Abstract Wastewater and sediment samples were collected from 11 coal operations across Canada: 3 coal storage transfer terminals, 7 operating mines, 3 of which had on-site preparation plants, and 1 separate preparation plant. Samples were analyzed for specific organic and inorganic constituents. Only the results of the organic analyses are presented here. The wastewater samples were analyzed for 18 target compounds. Sediment samples were analyzed for these 18 target compounds plus a suite of organic priority pollutants. Twelve of the 18 target compounds were detected in wastewater, only 4 of which were found in excess of 10 μg/L in more than 10 percent of the samples. Sixteen compounds were found in the sediments at levels from less than 1 μg/g to a maximum of 27 μg/g. Limited experimentation indicated that coal sediments were unlikely to contribute organic contaminants to the water column but rather were more likely to absorb material out of the water column.