Protecting our Great Lakes: assessing the effectiveness of wastewater treatments for the removal of chemicals of emerging concern

2014 ◽  
Vol 49 (1) ◽  
pp. 23-31 ◽  
Author(s):  
Antonette Arvai ◽  
Gary Klecka ◽  
Saad Jasim ◽  
Henryk Melcer ◽  
Michael T. Laitta

The Great Lakes and their connecting channels form the largest fresh surface water system on earth. Over the past 10 years, focus on environmental monitoring has shifted to an array of recently discovered compounds known as ‘chemicals of emerging concern’ (CEC). These chemicals are found in products used daily in households, businesses, agriculture and industry, such as flame retardants, pharmaceuticals, personal care products, and pesticides. Wastewater treatment plants are among the important pathways by which CEC enter the Great Lakes, with concentrations highest in the vicinity of wastewater discharges. Treated sewage is often discharged into the nearshore waters, which also provide a source of drinking water to the public. In 2009–2011, the International Joint Commission addressed the need to assess the effectiveness of existing wastewater treatment technologies in the basin to remove CEC, as well as to gain insight on potential advanced technologies to improve their removal. This assessment encompassed three major activities, development of an inventory of municipal wastewater treatment plants that discharge in the basin; a survey of detailed operational data for selected wastewater facilities; and a comprehensive literature review and analysis of the effectiveness of various wastewater treatment technologies to remove chemicals of emerging concern.

2016 ◽  
Vol 74 (7) ◽  
pp. 1602-1609 ◽  
Author(s):  
Long Pang ◽  
Peijie Yang ◽  
Jihong Zhao ◽  
Hongzhong Zhang

Organophosphate esters (OPs), widely used as flame retardants and plasticizers, are regarded as a class of emerging pollutants. The effluent of municipal wastewater treatment plants is generally considered to be the main contributor of OP pollution to the surface water. In this study, anoxic–oxic (AO) and University of Capetown (UCT) processes were selected to investigate the removal efficiency of OPs. The results indicated that the UCT process showed better removal efficiency than that of the AO process. For the chlorinated OPs, approximately 12.3% of tri(2-chloroethyl)phosphate and 11.8% of tri(chloropropyl)phosphate can be removed in the UCT process, which was 12% and 7.8% higher than that of the AO process. In contrast, non-chlorinated OPs, including tris(2-butoxyethyal)phosphate, triphenyl phosphate, and tributyl phosphate, were able to be removed in both processes, with the removal rate of 85.1%, 74.9%, and 29.1% in the AO process, and 88.4%, 63.6%, and 25.2% in the UCT process. Furthermore, linear correlation between the removal rate and logKow of OPs (r2 = 0.539) was observed in the AO process, indicating that OPs with high Kow value (e.g. tri(dichloropropyl)phosphate and triphenyl phosphate) are prone to be removed by adsorption on the residual activated sludge.


2011 ◽  
Vol 6 (1) ◽  
Author(s):  
A. Iborra-Clar ◽  
J.A. Mendoza-Roca ◽  
A. Bes-Pií ◽  
J.J. Morenilla-Martínez ◽  
I. Bernácer-Bonora ◽  
...  

Rainfall diminution in the last years has entailed water scarcity in plenty of European regions, especially in Mediterranean areas. As a consequence, regional water authorities have enhanced wastewater reclamation and reuse. Thus, the implementation of tertiary treatments has become of paramount importance in the municipal wastewater treatment plants (WWTP) of Valencian Region (Spain). Conventional tertiary treatments consist of a physico-chemical treatment of the secondary effluent followed by sand filtration and UV radiation. However, the addition of coagulants and flocculants sometimes does not contribute significantly in the final water quality. In this work, results of 20-months operation of three WWTP in Valencian Region with different tertiary treatments (two without chemicals addition and another with chemicals addition) are discussed. Besides, experiments with a 2 m3/h pilot plant located in the WWTP Quart-Benager in Valencia were performed in order to evaluate with the same secondary effluent the effect of the chemicals addition on the final water quality. Results showed that the addition of chemicals did not improve the final water quality significantly. These results were observed both comparing the three full scale plants and in the pilot plant operation.


2003 ◽  
Vol 3 (5-6) ◽  
pp. 321-327 ◽  
Author(s):  
M. Gallenkemper ◽  
T. Wintgens ◽  
T. Melin

Endocrine disrupting compounds can affect the hormone system in organisms. A wide range of endocrine disrupters were found in sewage and effluents of municipal wastewater treatment plants. Toxicological evaluations indicate that conventional wastewater treatment plants are not able to remove these substances sufficiently before disposing effluent into the environment. Membrane technology, which is proving to be an effective barrier to these substances, is the subject of this research. Nanofiltration provides high quality permeates in water and wastewater treatment. Eleven different nanofiltration membranes were tested in the laboratory set-up. The observed retention for nonylphenol (NP) and bisphenol A (BPA) ranged between 70% and 100%. The contact angle is an indicator for the hydrophobicity of a membrane, whose influence on the permeability and retention of NP was evident. The retention of BPA was found to be inversely proportional to the membrane permeability.


1982 ◽  
Vol 14 (1-2) ◽  
pp. 121-133
Author(s):  
C Forsberg ◽  
B Hawerman ◽  
B Hultman

Experience from advanced municipal wastewater treatment plants and recovery of polluted waters are described for the last ten years in Sweden. Except in municipalities with large recipients, the urban population is served by treatment plants with combined biological and chemical treatment. Most of these plants are post-precipitation plants. Several modified operational modes have been developed in order to improve the removal efficiencies of pollutants and to reduce the costs. Results are presented on the recovery of specially investigated lakes with a lowered supply of total phosphorus and organic matter.


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