scholarly journals Improving biological phosphorus removal in membrane bioreactors – a pilot study

2013 ◽  
Vol 4 (1) ◽  
pp. 25-33 ◽  
Author(s):  
S. Smith ◽  
G. Kim ◽  
L. Doan ◽  
H. Roh

With increasing water reuse applications and possible stringent regulations of phosphorus content in secondary and tertiary effluent discharge in Florida, USA, alternative technologies beyond conventional treatment processes require implementation to achieve low phosphorus (P) and nitrogen (N) concentrations. A pilot scale membrane bioreactor (MBR) system, operated in Florida, adopted the University of Cape Town (UCT) biological process for the treatment of domestic wastewater. The system operated for 280 days at a wastewater treatment facility with total hydraulic retention time (HRT) of 7 h and sludge retention time (SRT) of 20 days. Operating conditions were controlled to maintain specific dissolved oxygen (DO) concentrations in the reactors, operate at suitable return activated sludge (RAS) rates and to waste from the appropriate reactor. This process favored biological phosphorus removal and achieved 94.1% removal efficiency. Additionally, chemical oxygen demand (COD) and N removal were achieved at 93.9% and 86.6%, respectively. Membrane operation and maintenance did not affect the biological P removal performance but enhanced the process given the different operating requirements compared to that required with the conventional UCT process alone. Conclusively, the result of the pilot study demonstrated improvement in biological phosphorus removal. The UCT-MBR process tested achieved average effluent nitrogen and phosphorus concentrations of 5 mg/L as N and 0.3 mg/L as P.

Author(s):  
Van Nu Thai Thien ◽  
Dang Viet Hung ◽  
Nguyen Thi Thanh Hoa

Anaerobic/Anoxic/Oxic – Membrane BioReactor (A2O-MBR) system was used to enhance simultaneous removal of nitrogen and phosphorus from brewery wastewater. The A2O unit containing microorganisms with short solids retention time (SRT) was employed mainly for removal of organic matter and phosphorus together with denitrification. The MBR containing microorganisms with long SRT was employed mainly for nitrification of NH4+-N and recirculation of NO3--N. The model of A2O-MBR system made from polyacrylic with the capacity of 49.5 liters was operated with hydraulic retention times decreased from 24, 18 to 12 hours corresponding to organic loading rates increased from 0.50, 0.75 to 1.00 kg COD/m3.day. The results showed that the model not only treated organic matter well but also nearly completely removed both nitrogen and phosphorus. For all three loading rates, chemical oxygen demand (COD) concentration decreased significantly in the anaerobic and anoxic compartments of the A2O unit, indicating that most of organic matter was utilized in the anaerobic and anoxic compartments for phosphorus release and denitrification, respectively. Nitrification in the MBR was almost perfectly completed, with average NH4 +-N removal efficiencies of over 98%. Denitrification in the anoxic compartment happened as much as possible. Demands for the development of PAOs, which were responsible for enhanced biological phosphorus removal (EBPR) processes, could be provided. For loading rate of 0.75 kg COD/m3.day, treatment efficiencies of COD, NH4+-N, total nitrogen (TN) and total phosphorus (TP) of the model were the highest as 95.4, 99.2, 86.7 and 84.6%, respectively. Output values of these parameters were within the limits of Vietnam National Technical Regulation on Industrial Wastewater (QCVN 40:2011/BTNMT), column A. The model of A2O-MBR system was capable of achieving effluents with very low nitrogen and phosphorus concentrations from brewery wastewater.  


2002 ◽  
Vol 45 (6) ◽  
pp. 137-144 ◽  
Author(s):  
M. Henze ◽  
H. Aspregren ◽  
J. la Cour Jansen ◽  
P.H. Nielsen ◽  
N. Lee

The paper deals with the effect of wastewater, plant design and operation in relation to biological nitrogen and phosphorus removal and the possibilities to model the processes. Two Bio-P pilot plants were operated for 2.5 years in parallel receiving identical wastewater. The plants had SRT of 4 and 21 days, the latter had nitrification and denitrification. The plant with 4 days SRT had much more variable biomass characteristics, than the one with the high SRT. The internal storage compounds, PHA, were affected significantly by the concentration of fatty acids or other easily degradable organics in the wastewater, and less by the plant lay-out. The phosphorus removal is mainly dependent on availability in the wastewater of fatty acids but also by the suspended solids in the effluent, which is higher in the plant with nitrification-denitrification, probably due to a higher SVI or denitrification in the settler. The addition of glucose to the influent seems to have an effect on the performance of the plants similar to that of acetic acid. In spite of great load variations over time to the pilot plants and the different operational modes, the study of population dynamics showed less significant variations with time which has importance in relation to modelling. The overall conclusion of the comparison between the two plants is that the biological phosphorus removal efficiency under practical operating conditions is affected by the SRT in the plant and the wastewater composition. Thus great care should be taken when extrapolating results from one type of plant to another. Indirectly the experiments confirm that results from lab-experiments with artificial wastewater are difficult to extrapolate through modelling to real life wastewater and conditions. The 2.5 years time series can be valuable in verification of models for Nitrogen and Enhanced Biological Phosphorus Removal.


Author(s):  
Giedre Vaboliene ◽  
Algirdas Bronislovas Matuzevičius

Nitrogen and phosphorus removal is necessary to avoid eutrophication of water bodies when treated wastewater is outlet to slowly flowing water bodies or recycled as technological water. The “BioBalance” technology as the latest way of nitrogen and phosphorus removal was applied at Utena Wastewater Treatment Plant. Composition of wastewater has an impact on biological phosphorus removal, particularly the ratio of biochemical oxygen demand and total phosphorus (BOD7/Total-P) in wastewater after mechanical treatment. Nitrates in the anaerobic zone can have a negative effect on biological phosphorus removal. Consequently, it is necessary to evaluate the impact of the mentioned factors on biological nitrogen and phosphorus removal. Biological nitrogen and phosphorus removal was evaluated and compared by using the “BioBalance” technology for biological nitrogen and phosphorus removal and technology before reconstruction during this investigation. The correlation regressive analysis of the biochemical oxygen demand and total phosphorus (BOD7/Total‐P) after mechanical treatment and the total phosphorus concentration in the effluent was evaluated. The correlation regressive analysis of nitrates in an anaerobic zone on the aeration tank and the efficiency of phosphorus removal was also evaluated.


2006 ◽  
Vol 41 (1) ◽  
pp. 72-83 ◽  
Author(s):  
Zhe Zhang ◽  
Eric R. Hall

Abstract Parameter estimation and wastewater characterization are crucial for modelling of the membrane enhanced biological phosphorus removal (MEBPR) process. Prior to determining the values of a subset of kinetic and stoichiometric parameters used in ASM No. 2 (ASM2), the carbon, nitrogen and phosphorus fractions of influent wastewater at the University of British Columbia (UBC) pilot plant were characterized. It was found that the UBC wastewater contained fractions of volatile acids (SA), readily fermentable biodegradable COD (SF) and slowly biodegradable COD (XS) that fell within the ASM2 default value ranges. The contents of soluble inert COD (SI) and particulate inert COD (XI) were somewhat higher than ASM2 default values. Mixed liquor samples from pilot-scale MEBPR and conventional enhanced biological phosphorus removal (CEBPR) processes operated under parallel conditions, were then analyzed experimentally to assess the impact of operation in a membrane-assisted mode on the growth yield (YH), decay coefficient (bH) and maximum specific growth rate of heterotrophic biomass (µH). The resulting values for YH, bH and µH were slightly lower for the MEBPR train than for the CEBPR train, but the differences were not statistically significant. It is suggested that MEBPR simulation using ASM2 could be accomplished satisfactorily using parameter values determined for a conventional biological phosphorus removal process, if MEBPR parameter values are not available.


2013 ◽  
Vol 69 (8) ◽  
pp. 1612-1619 ◽  
Author(s):  
Paraschos Melidis ◽  
Anastasios G. Kapagiannidis ◽  
Spyridon Ntougias ◽  
Konstantina Davididou ◽  
Alexander Aivasidis

A novel enhanced biological phosphorus removal (EBPR) system, which combined the intermittent feeding design with an anaerobic selector, was examined using on-line oxidation reduction potential (ORP), nitrate and ammonium probes. Two experimental periods were investigated: the aerobic and anoxic phases were set at 40 and 20 minutes respectively for period I, and set at 30 and 30 minutes for period II. Chemical oxygen demand (COD), biochemical oxygen demand (BOD5) and P removal were measured as high as 87%, 96% and 93% respectively, while total Kjeldahl nitrogen (TKN) and NH4+ removal averaged 85% and 91%. Two specific denitrification rates (SDNRs), which corresponded to the consumption of the readily biodegradable and slowly biodegradable COD, were determined. SDNR-1 and SDNR-2 during period I were 0.235 and 0.059 g N g−1 volatile suspended solids (VSS) d−1 respectively, while the respective rates during period II were 0.105 and 0.042 g N g−1 VSS d−1. The specific nitrate formation and ammonium oxidizing rates were 0.076 and 0.064 g N g−1 VSS d−1 for period I and 0.065 and 0.081 g N g−1 VSS d−1 for period II respectively. The specific P release rates were 2.79 and 4.02 mg P g−1 VSS h−1 during period I and II, while the respective anoxic/aerobic uptake rates were 0.42 and 0.55 mg P g−1 VSS h−1. This is the first report on an EBPR scheme using the intermittent feeding strategy.


1983 ◽  
Vol 15 (3-4) ◽  
pp. 1-13 ◽  
Author(s):  
James L Barnard

This paper briefly summarizes the early work on phosphorus removal in activated sludge plants in the U.S.A. and observed that such removals only occurred in low SRT plants of the plug flow type and in the Phostrip plants, neither designed for full nitrification. The discovery of simultaneous nitrogen and phosphorus removal, as well as full-scale experiments are discussed. The Phoredox process was proposed utilizing internal recycling for the removal of nitrates and an anaerobic first stage in which the incoming feed is used to obtain the necessary anaerobic conditions, essential as a conditioning step for the uptake of phosphorus. Proposed mechanisms are discussed.


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