Integrated modelling of two xenobiotic organic compounds

2006 ◽  
Vol 54 (6-7) ◽  
pp. 213-221 ◽  
Author(s):  
E. Lindblom ◽  
K.V. Gernaey ◽  
M. Henze ◽  
P.S. Mikkelsen

This paper presents a dynamic mathematical model that describes the fate and transport of two selected xenobiotic organic compounds (XOCs) in a simplified representation of an integrated urban wastewater system. A simulation study, where the xenobiotics bisphenol A and pyrene are used as reference compounds, is carried out. Sorption and specific biological degradation processes are integrated with standardised water process models to model the fate of both compounds. Simulated mass flows of the two compounds during one dry weather day and one wet weather day are compared for realistic influent flow rate and concentration profiles. The wet weather day induces resuspension of stored sediments, which increases the pollutant load on the downstream system. The potential of the model to elucidate important phenomena related to origin and fate of the model compounds is demonstrated.

2014 ◽  
Vol 60 ◽  
pp. 64-74 ◽  
Author(s):  
Ulla E. Bollmann ◽  
Camilla Tang ◽  
Eva Eriksson ◽  
Karin Jönsson ◽  
Jes Vollertsen ◽  
...  

2006 ◽  
Vol 53 (11) ◽  
pp. 251-260 ◽  
Author(s):  
H. Tsuno ◽  
M. Kawamura ◽  
T. Oya

An expanded-bed anaerobic reactor with granular activated carbon (GAC) medium has been developed to treat wastewaters that contain a high concentration of inhibitory and/or refractory organic compounds as well as readily degradable organic compounds. The process is characterised by a combination of two removal mechanisms; adsorption on GAC and biological degradation by microorganisms grown on GAC. Applicability of the reactor to treatment of phenol, chloroacetaldehyde (CAA), pentachlorophenol (PCP) and tetrachloroethylene (PCE) was discussed based on experimental data. All chemicals focused on here were removed well and stably at a removal efficiency of more than 98% even during starting operation and shock load operation. Chemicals in influent that exceeded biological degradation capacity was initially adsorbed on GAC and then gradually degraded, and hence the adsorptive capacity of GAC was regenerated biologically. These results proved that a biological activated carbon anaerobic reactor was effective for treatment of wastewater containing hazardous chemicals, especially for strongly absorbable chemicals, as well as readily degradable organic compounds at high concentration.


2017 ◽  
Vol 7 (17) ◽  
pp. 3902-3919 ◽  
Author(s):  
Hussein A. Miran ◽  
Mohammednoor Altarawneh ◽  
Zhong-Tao Jiang ◽  
Hans Oskierski ◽  
Mansour Almatarneh ◽  
...  

Guided by recent experimental measurements, this study theoretically investigates the initial steps operating in the interactions of ceria surface CeO2(111) with three CVOC model compounds, namely chloroethene (CE), chloroethane (CA) and chlorobenzene (CB).


2014 ◽  
Vol 10 ◽  
pp. 2743-2750 ◽  
Author(s):  
Ludmilla Lumholdt ◽  
Sophie Fourmentin ◽  
Thorbjørn T Nielsen ◽  
Kim L Larsen

Polypropylene nonwovens were functionalised using a self-assembled, amphiphilic cyclodextrin coating and the potential for water purification by removal of pollutants was studied. As benzene is one of the problematic compounds in the Water Framework Directive, six volatile organic compounds (benzene and five benzene-based substances) were chosen as model compounds. The compounds were tested as a mixture in order to provide a more realistic situation since the wastewater will be a complex mixture containing multiple pollutants. The volatile organic compounds are known to form stable inclusion complexes with cyclodextrins. Six different amphiphilic cyclodextrin derivatives were synthesised in order to elucidate whether or not the uptake abilities of the coating depend on the structure of the derivative. Headspace gas chromatography was used for quantification of the uptake exploiting the volatile nature of benzene and its derivatives. The capacity was shown to increase beyond the expected stoichiometries of guest–host complexes with ratios of up to 16:1.


2014 ◽  
Vol 53 (9) ◽  
pp. 704-710 ◽  
Author(s):  
Elenilson G. Alves Filho ◽  
Luci Sartori ◽  
Lorena M. A. Silva ◽  
Bianca F. Silva ◽  
Pedro S. Fadini ◽  
...  

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