The effect of SRT on nitrate formation during autotrophic nitrogen removal of anaerobically treated wastewater

2013 ◽  
Vol 68 (8) ◽  
pp. 1751-1756 ◽  
Author(s):  
Po-Heng Lee ◽  
Wonji Kwak ◽  
Jeaho Bae ◽  
Perry L. McCarty

Autotrophic nitrogen removal, coupling nitritation (ammonium to nitrite) with anaerobic ammonium oxidation (anammox), offers a promising nitrogen-removal alternative, especially for post-treatment of anaerobically-treated wastewater. However, previous reports suggest that less than 90% total nitrogen removal should be expected with this process alone because over 10% of the ammonium removed will be converted to nitrate. This is caused because nitrite conversion to nitrate is required for reduction of carbon dioxide to cell carbon. However, recent research results suggest that more limited nitrate formation of only a few per cent sometimes occurs. It was hypothesized such lower nitrate yields may result from use of long solids retention times (SRT) where net biological yields are low, and providing that the ratio of oxygen added to influent ammonium concentrations is maintained at or below 0.75 mol/mol. Overall reaction equations were developed for each process and combined to evaluate the potential effect of SRT on process stoichiometry. The results support the use of a long SRT to reduce net cell yield, which in turn results in a small percentage conversion to nitrate during ammonium removal and high total nitrogen removals in the range of 90 to 94%.

1992 ◽  
Vol 26 (3-4) ◽  
pp. 461-472 ◽  
Author(s):  
O. E. Albertson ◽  
P. Hendricks

A 1630 L/s activated sludge plant at Phoenix was limited to an average rate of 1050 L/s and operated, at 400-600 mg/L MLSS and 0.8-1.3 day solids retention time (SRT) due to bulking sludge and limited clarification capacity. Higher SRTs also produced uncontrolled Nocardia foaming and low dissolved oxygen due to partial nitrification. The City retained the services of a team of consultants to resolve these problems as well as to upgrade the plant to provide nitrification and total nitrogen removal. An anoxic selector design was implemented within the existing basin and the clarifiers were modified to improve inlet design and sludge transport. The modified advanced wastewater treatment (AWT) plant operating at 1450 L/s has averaged an effluent of 7.6 mg/L BOD5, 8.2 mg/L TSS, 1.3 mg/L NH4N, 4.1 mg/L NO3N and 2.9 mg/L TP. Oxygen transfer efficiency has increased about 80% in the nitrification-denitrification (NdeN) mode. The cost of modification/upgrading to AWT was approximately $730,000 and a 400 L/s increase in hydraulic capacity was realized. Upgrading costs were $5.63/m3 ($0.02/gal.)


RSC Advances ◽  
2015 ◽  
Vol 5 (73) ◽  
pp. 59326-59334 ◽  
Author(s):  
A. Chen ◽  
Y. Chen ◽  
C. Ding ◽  
H. Liang ◽  
B. Yang

The presence of 2 and 5 mg L−1of tetracycline decreased total nitrogen removal. Tetracycline induced EPS release and decreased its protective role on cells. Denitrifiers instead of nitrifiers were negatively affected by tetracycline.


2010 ◽  
Vol 61 (9) ◽  
pp. 2259-2266 ◽  
Author(s):  
Styliani Kantartzi ◽  
Paraschos Melidis ◽  
Alexander Aivasidis

In the present study, a laboratory scale system, consisting of a primary settling tank, a continuous stirred tank reactor and a clarifier were constructed and operated, using wastewater from the municipal wastewater treatment plant in Xanthi, Greece. The system operated under intermittent aeration in aerobic/anoxic conditions and feeding of the wastewater once in every cycle. The unit was inoculated with sludge, which originated from the recirculation stream of the local wastewater treatment plant. The wastewater was processed with hydraulic retention time (HRT) of 12 h, in which various experimental states were studied regarding the combination of aerobic and anoxic intervals. The wastewater was fed in limited time once in every cycle of aerobic/anoxic conditions at the beginning of the anoxic period. The two states that exhibited highest performance in nitrification and total nitrogen removal were, then, repeated with HRT of 10 h. The results show that, regarding the nitrification stage and the organic load removal, the intermittent system achieved optimum efficiency, with an overall removal of biological oxygen demand (BOD5) and ammonium nitrogen in the range of 93–96% and 91–95% respectively. As far as the total nitrogen removal is concerned, and if the stage of the denitrification is taken into account, the performance of the intermittent system surpassed other methods, as it is shown by the total Kjeldahl nitrogen (TKN) removal efficiency of 85–87%. These operating conditions suppressed the growth of filamentous organisms, a fact reflected at the SVI values, which were lower than 150 ml/g.


2007 ◽  
Vol 55 (8-9) ◽  
pp. 59-65 ◽  
Author(s):  
A. Onnis-Hayden ◽  
P.B. Pedros ◽  
J. Reade

An experimental study investigating the nitrogen removal efficiency from the recycle stream generated in the dewatering facility of the anaerobically digested sludge at the Deer Island wastewater treatment plant (WWTP) in Boston was conducted using a single submerged attached growth bioreactor (SAGB), designed for simultaneous nitrification and denitrification. The applied nitrogen loading to the reactor ranged from 0.7 to 2.27 kg-N/m3·d, and the corresponding total nitrogen (TN) removal rate ranged from 0.38 to 1.8 kg-N/m3·d. The observed nitrification rates varied from 0.42 kg-N/m3·d to 1.45 kg-N/m3·d with an ammonia load of 0.5 kg-N/m3·d and 1.8 kg-N/m3·d, respectively. An average nitrification efficiency of 91% was achieved throughout the experiment. Denitrification efficiency varied from 55%, obtained without any addition of carbon source, to 95% when methanol was added in order to obtain a methanol/nitrate ratio of about 3 kg methanol/kg NO3−-N.


2017 ◽  
Vol 2017 ◽  
pp. 1-8 ◽  
Author(s):  
Xiaoling Zhang ◽  
Fan Zhang ◽  
Yanhong Zhao ◽  
Zhengqun Li

The start-up and performance of the completely autotrophic nitrogen removal via nitrite (CANON) process were examined in a sequencing batch reactor (SBR) with intermittent aeration. Initially, partial nitrification was established, and then the DO concentration was lowered further, surplus water in the SBR with high nitrite was replaced with tap water, and continuous aeration mode was turned into intermittent aeration mode, while the removal of total nitrogen was still weak. However, the total nitrogen (TN) removal efficiency and nitrogen removal loading reached 83.07% and 0.422 kgN/(m3·d), respectively, 14 days after inoculating 0.15 g of CANON biofilm biomass into the SBR. The aggregates formed in SBR were the mixture of activated sludge and granular sludge; the volume ratio of floc and granular sludge was 7 : 3. DNA analysis showed that Planctomycetes-like anammox bacteria and Nitrosomonas-like aerobic ammonium oxidization bacteria were dominant bacteria in the reactor. The influence of aeration strategies on CANON process was investigated using batch tests. The result showed that the strategy of alternating aeration (1 h) and nonaeration (1 h) was optimum, which can obtain almost the same TN removal efficiency as continuous aeration while reducing the energy consumption, inhibiting the activity of NOB, and enhancing the activity of AAOB.


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